Search results for "VIBRATION"
showing 10 items of 823 documents
Helium and Argon Line Broadening in the nu2 Band of CH4
2004
Abstract The spectra of the gaseous mixtures CH 4 –He and CH 4 –Ar were obtained in the spectral region 1400–1750 cm −1 with a resolution up to 0.003 cm −1 . Helium and argon pressure broadenings for the vibration–rotation lines of the ν 2 band of CH 4 have been estimated at room temperature for some lines in the P , Q , and R branches. These values were also calculated using the theoretical approach developed by Robert and Bonamy, extended to the case of tetrahedral molecules. The helium data have been found to be in a satisfactory agreement whereas a divergence of calculated and measured broadening coefficients has been evidenced in the case of argon. Simulations of the ν 2 band shapes of…
On the coupling dynamics between thermally stressed beams and granular chains
2015
The in-situ measurement of thermal stress in slender beams, or long continuous welded rails, may prevent structural anomalies. With this aim, we investigated the coupling dynamics between a beam and the highly nonlinear solitary waves propagating along a straight granular chain in contact with the beam. We hypothesized that these waves can be used to measure the stress of thermally loaded structures, or to infer the neutral temperature, i.e., the temperature at which this stress is null. We studied numerically and experimentally the mechanical interaction of one and two straight chains of spherical particles in contact with a prismatic beam that is subjected to heat. The results show that c…
On the role of atomic thermal vibrations in binary-alloy thermodynamics
2001
An ab initio approach is advanced for the thermodynamical properties investigations of disordered binary alloys. Configurational and vibrational degrees of freedom are considered on the microscopic level in the grand partition sum calculations. Summing over the vibrational and configurational states of an alloy is performed within the reference system approach and the collective variables method, respectively. An equation defining the alloy free energy is obtained. The role of the atomic thermal vibrations in the binary-alloy thermodynamics and their relationship with the configurational effects are discussed. Conditions when the configurational and vibrational effects can be treated separa…
XRD and micro Raman characterization of epitaxial Bi-2201, Bi-2212 and Bi-2223 thin films
1997
Copyright (c) 1997 Elsevier Science B.V. All rights reserved. Micro Raman characterization is performed on high quality thin films of Bi 2 Sr 2 CuO 6+x (2201), Bi 2 Sr 2 CaCu 2 O 8+x (2212), Bi 2 Sr 2 Ca 2 Cu 3 O 10+x (2223) made by dc-sputtering. Single crystal X-ray measurements reveal the full epitaxy of the films, which allows for polarized Raman spectra to be obtained.
Optical and Vibrational Spectra of CsCl-Enriched GeS2-Ga2S3 Glasses
2016
Optical and FTIR spectroscopy was employed to study the properties of 80GeS2-20Ga2S3-CsCl chalcohalide glasses with CsCl additives in a temperature range of 77–293 K. It is shown that CsCl content results in the shift of fundamental absorption edge in the visible region. Vibrational bands in FTIR spectra of (80GeS2-20Ga2S3)100 − х (СsCl) x (x = 5, 10, and 15) are identified near 2500 cm−1, 3700 cm−1,, around 1580 cm−1, and a feature at 1100 cm−1. Low energy shifts of vibrational frequencies in glasses with a higher amount of CsCl can be caused by possible thermal expansion of the lattice and nanovoid agglomeration formed by CsCl additives in the inner structure of the Ge-Ga-S glass.
Nonlocal model for a magneto-electro-elastic nanoplate
2013
A mathematical model based on nonlocal third-order shear deformation plate theory has been developed to evaluate the mechanical and electromagnetic behavior of magneto-electro-elastic nanoplates. Two types of magneto-electro-elastic composites have been considered, all of them combination of Barium Titanate sheets, that represents the piezoelectric phase, and Cobalt Ferrite, that is the piezomagnetic component. Setting magneto-electric boundary conditions on each laminate, it has been possible to extrapolate and to analyze free vibrations frequencies for all considered plates, allowing to do objective assessments on what factors influence laminate modes and, especially, how these vary in th…
Energy Based Characterization of Fatigue Behaviour of Cyclically Unstable Materials
2009
The paper presents a definition of a new energy based parameter which allows to better describe fatigue proprieties of materials, especially cyclically unstable materials in comparison with the Lagoda-Macha parameter. The proposed parameter distinguishes positive and negative work of external force and depends on the sign of the stresses in paths of strain in materials. It is used in laboratory tests for control of a fatigue process on hydraulic stand. A close-loop control system has been equipped with computer program based on MATLAB/Simulink module.
Acoustic vibrations of anisotropic nanoparticles
2009
Acoustic vibrations of nanoparticles made of materials with anisotropic elasticity and nanoparticles with non-spherical shapes are theoretically investigated using a homogeneous continuum model. Cubic, hexagonal and tetragonal symmetries of the elasticity are discussed, as are spheroidal, cuboctahedral and truncated cuboctahedral shapes. Tools are described to classify the different vibrations and for example help identify the modes having a significant low-frequency Raman scattering cross-section. Continuous evolutions of the modes starting from those of an isotropic sphere coupled with the determination of the irreducible representation of the branches permit some qualitative statements t…
Phonon Dispersion of Wurtzite CdSe: The Bond Charge Model
2000
The phonon dispersion of wurtzite CdSe is presented along the main directions of the Brillouin zone. The study has been performed by using a bond charge model for wurtzite-type semiconductors with only six adjustable parameters. The results are compared against neutron scattering data and ab initio calculations. The phonon eigenvectors corresponding to the vibrational modes at the Γ-point are in very good agreement with the ab initio calculations.