Search results for "Viscosity."

Online measurement of floc size, viscosity, and consistency of cellulose microfibril suspensions with optical coherence tomography

2021

AbstractIn this study, cellulose microfibril (CMF) suspensions were imaged during pipe flow at consistencies of 0.4%, 1.0%, and 1.6% with optical coherence tomography (OCT) to obtain images of the structure and the local velocity of the suspension. The viscosities obtained by combining pressure loss measurement with the OCT velocity data showed typical shear thinning behavior and were in excellent agreement with viscosities obtained with ultrasound velocity profiling. The structural OCT images were used to calculate the radial and the axial floc sizes of the suspension. A fit of power law to the geometrical floc size–shear stress data gave the same power law index for all consistencies, sug…

Shear-Thinning in Oligomer Melts—Molecular Origins and Applications

2021

We investigate the molecular origin of shear-thinning in melts of flexible, semiflexible and rigid oligomers with coarse-grained simulations of a sheared melt. Entanglements, alignment, stretching and tumbling modes or suppression of the latter all contribute to understanding how macroscopic flow properties emerge from the molecular level. In particular, we identify the rise and decline of entanglements with increasing chain stiffness as the major cause for the non-monotonic behaviour of the viscosity in equilibrium and at low shear rates, even for rather small oligomeric systems. At higher shear rates, chains align and disentangle, contributing to shear-thinning. By performing simulations …

Artificial neural network based particle size prediction of polymeric nanoparticles.

2017

Particle size of nanoparticles and the respective polydispersity are key factors influencing their biopharmaceutical behavior in a large variety of therapeutic applications. Predicting these attributes would skip many preliminary studies usually required to optimize formulations. The aim was to build a mathematical model capable of predicting the particle size of polymeric nanoparticles produced by a pharmaceutical polymer of choice. Polymer properties controlling the particle size were identified as molecular weight, hydrophobicity and surface activity, and were quantified by measuring polymer viscosity, contact angle and interfacial tension, respectively. A model was built using artificia…

Process parameters of microsphere preparation based on propylene carbonate emulsion-precursors.

2020

This study aimed for a detailed understanding of the impact of different process parameters involved during celecoxib-loaded microsphere preparation based on propylene carbonate emulsion-precursors.Microspheres were prepared by a modified emulsification-solvent extraction method. Performed investigations included polymer solubility and viscosity, microsphere size, morphology and stability, propylene carbonate content as well as celecoxib solid state, content and release.Rough-walled round microspheres with sizes between 21 µm and 122 µm and an internal sponge-like structure filled with residual propylene carbonate (content between 1.9 ± 0.1% and 6.7 ± 0.5% w/w) were obtained. Encapsulation …

Non-ideal mixing behavior in dibutyl phosphate-propylamine binary liquids: Dielectric and nuclear magnetic resonance investigations

2021

Abstract Owing to the amphiphilic nature of their constituent molecules, binary mixtures of pure liquid surfactants are usually characterized by enhanced nano-segregation and thus can exhibit interesting transport properties and complex macroscopic behavior. In this ambit it was recently shown by Turco Liveri et al. (J. Mol. Liq. 263 (2018) 274–281) at room temperature that mixtures of short aliphatic chains compounds, such as dibutyl phosphate (DBP) and n-propylamine (PA) liquids, due to their ability to allow for phosphate-to-amine proton transfer, display ionic liquid–like behavior with composition-dependent enhanced conductivity, viscosity, and magnetically-induced birefringence. To und…

Improved Testing Setup for Real-Time Monitoring of PMBs During Manufacturing and Rotational Viscosity Measurements

2021

Polymer modified binders (PMBs) are a practical solution to design asphaltmixtures with superior performance. Although these polymers often improve bitumen properties to some extent, their final performance are linked to the accurate control of the properties during manufacturing and storage. However, some of the common procedures used to characterise neat bitumen are not suitable with these binders making their characterisation challenging. This study presents a novel laboratory procedure to produce SBS-MB through a real-time monitoring of the rotational viscosity, as well as an attempt to understand the suitability of current testing geometries to measure viscosity of such a complex bitum…

Shear Thinning: Determination of Zero‐Shear Viscosities from Measurements in the Non‐Newtonian Region

2020

Solvent hydrodynamics speed up crystal nucleation in suspensions of hard spheres

2014

We present a computer simulation study on the crystal nucleation process in suspensions of hard spheres, fully taking into account the solvent hydrodynamics. If the dynamics of collodial crystallization were purely diffusive, the crystal nucleation rate densities would drop as the inverse of the solvent viscosity. However, we observe that the nucleation rate densities do not scale in this way, but are enhanced at high viscosities. This effect might explain the large discrepancy between the nuclation rate densities obtained by simulation and experiment that have reported in the literature so far.

TeO2 liquid phase: Viscosity measurements and evaluation of the thermal conductivity from crystal growth experiments

2008

Current applications of paratellurite TeO{sub 2} in optics and nuclear physics require improving the yield and optical quality of synthesized single crystals. Modelling of the growth process is a useful tool for such purpose, however, involving the knowledge of several thermodynamic parameters of both solid and liquid phase of the compound. This work describes the determination of two main unknown ones, namely dynamic viscosity {eta} and thermal conductivity {lambda}{sub l} of the liquid phase. Measurements of {eta} are performed by means of a specifically designed apparatus; over a 40 K temperature interval above the melting point we find a mean value of 0.028 Pa.s. This data is used in co…

Fibre break processes in unidirectional composites

2014

International audience; A model to predict the effects of the accumulation of fibre breakages in unidirectional carbon fibre composites has been developed that takes into account several physical phenomena controlling fibre failure, including the stochastic nature of fibre strength, stress transfer between fibres due to the shear of the matrix, interfacial debonding and viscosity of the matrix. The damage processes leading up to failure are discussed and quantified, first in terms of fibre breaks for the case of monotonically increasing tensile loading, then for sustained loading and finally the implications for more complex loads and structures are discussed. It is clearly shown that the f…