Search results for "WASTE"
showing 10 items of 2580 documents
Membrane distillation: solar and waste heat driven demonstration plants for desalination
2011
Potential applications of Salinity Gradient Power-Heat Engines for recovering low-temperature waste heat in cogeneration plants
2021
Abstract Salinity Gradient Power-Heat Engine is an innovative technology able to convert very low-temperature heat into electricity. Energy and economic benefits could be achieved by integrating this technology into cogeneration plants, where the exploitation of waste heat available during the operation could increase the revenues arising from “High-Efficiency” labels. For the first time, this paper proposes two potential applications in this field, and three illustrative case studies are purposely investigated. In the first case study, a salinity gradient-heat engine converts the waste heat available from a cogeneration plant serving an industrial process. In the second case study, a salin…
Design of a novel membrane-integrated waste acid recovery process from pickling solution
2019
Abstract Hydrochloric acid pickling is a common practice in steel manufacturing industry. During the process, acid is consumed to dissolve surface oxides and metals ions are accumulated in the solution, which becomes less effective with time. In addition, the costly and risky waste acid disposal is another issue affecting the hot-dip galvanizing industry. In this work, a novel sustainable waste acid recovery process from pickling solutions based on circular approach is proposed to tackle these issues. The innovative system allows (i) the continuous regeneration of pickling solutions to enhance process rate and performance and (ii) minimise the highly expensive and environmentally risky wast…
Water-organic systems in closed-loop reverse electrodialysis for lower regeneration requirements
2016
Salinity Gradient Power (SGP) is an emerging opportunity to produce sustainable energy. Among the different SGP technologies, Reverse ElectroDialysis (RED) looks very promising. In a RED system the salinity gradient between two different solutions is used to directly produce electricity. Closed-loop RED is an innovative process, combining a RED unit with a regeneration system. If low grade waste-heat is used for the regeneration stage, in which the initial concentrations of the solutions exiting the RED unit are restored, the closed-loop can be seen as a RED-heat-engine able to convert thermal energy into electricity. The aim of this work is to perform a preliminary analysis of a regenerati…
Long-run operation of a reverse electrodialysis system fed with wastewater solutions
2016
In the framework of Salinity Gradient Power technologies, Reverse ElectroDialysis (RED) is one of the most promising. In RED, two solutions of different salt concentration are fed into a series of alternate compartments, the one fed by the low salinity solution, the other by the high salinity solution. Compartments are separated by anion and cation exchange membranes alternatively piled to form a stack. Selective ion transport from the concentrate compartment to the dilute one across the membranes allows to generate an ionic current, which is eventually converted into electric current by means of suitable electrode compartments closing the stack. Several options for the feed solutions are p…
REVERSE ELECTRODIALYSIS HEAT ENGINE: Low-grade Waste Heat into Electricity
Our society is undergoing a progressive change about the life style and habits. The world population is continuously increasing with 7.6 billion of human beings in 2018, resulting in an increasingly demand of resources in terms of food, water and energy. The exploitation of the planet resources since the first Industrial Revolution, results today in an unsustainable condition, which requires fundamental changes. In particular, in the energy sector the adoption of fossil fuels as the main energy source for human beings’ activities resulted in a strong impact on our planet, leading to climate changes and environmental pollution. Nowadays these aspects have induced society to a substantial cha…
Performance of a RED system with ammonium hydrogen carbonate solutions
2016
The use of closed-loop salinity gradient power (SGP) technologies has been recently presented as a viable option to generate power using low-grade heat, by coupling a SGP unit with a thermally-driven regeneration process in a closed loop where artificial solutions can be adopted for the conversion of heat into power. Among these, the closed-loop reverse electrodialysis (RED) process presents a number of advantages such as the direct production of electricity, the extreme flexibility in operating conditions and the recently demonstrated large potentials for industrial scale-up. Ammonium hydrogen carbonate (NH4HCO3) is a salt suitable for such closed-loop RED process thanks to its particular …
Reverse electrodialysis with NH4HCO3-water systems for heat-to-power conversion
2017
Abstract A Reverse ElectroDialysis Heat Engine (REDHE) system operating with “thermolytic” ammonium hydrogen-carbonate (NH4HCO3) aqueous solutions as working fluids is studied. The engine is constituted by (i) a RED unit to produce electric power by mixing the solutions at different salinity and (ii) a thermally-driven regeneration unit including a stripping and an absorption column to restore the initial salinity gradient thus closing the cycle. In the present work only the RED unit and the stripping column are taken into account. In particular, a simplified integrated process model for the whole cycle was developed: it consists of (i) a lumped parameter model for the RED unit validated wi…
Development of a pilot plant for the recovery of magnesium hydroxide from waste brines
Waste brines from various industrial processes, mainly from saltworks, are an important source of minerals, such as magnesium, table salt and potable water.
Diffusion dialysis for the treatment of H2SO4-CuSO4 solutions from electroplating plants: Ions membrane transport characterization and modelling
2021
Diffusion dialysis (DD) is proposed to separate and recover mineral acids and transition metals from electroplating industry process waters promoting a circular approach of resources recovery. In this work, a DD module with two anionic membranes (Fumasep FAD and Neosepta AFN) are used for the separation of H2SO4 from Cu2+ containing solutions. The membrane performances with sole H2SO4 solutions (0.2–2 M) and sole CuSO4 solutions (0.8–1.1 M Cu2+) and with mixtures of H2SO4 (0.6 M) and CuSO4 (0.2–1.1 M Cu2+) as feed are studied. H2SO4 recovery efficiency decreases as the concentration of acid increases. For H2SO4 solutions, the water drag flux from the retentate to the diffusate prevails agai…