Search results for "approximation"
showing 10 items of 818 documents
Calculations of the atomic and electronic structure for SrTiO3 perovskite thin films
2001
The results of calculations of SrTiO3 (100) surface relaxation and rumpling with two different terminations (SrO and TiO2) are presented and discussed. We have used the ab initio Hartree–Fock (HF) method with electron correlation corrections and the density functional theory (DFT) with different exchange–correlation functionals, including hybrid exchange techniques. All methods agree well on surface energies and on atomic displacements, as well as on the considerable increase of covalency effects near the surface. More detailed experiments on surface rumpling and relaxation are necessary for further testing of theoretical predictions.
Two-LO-Phonon Resonant Raman Scattering in II-VI Semiconductors
1996
Recently, absolute values of socond-order Raman scattering efficiency have been measured around the E 0 and E 0 + Δ 0 critical points of several II-VI semiconductor compounds. The measurements were perfomed in the z(x,x)z backscattering configuration on (001) (ZnSe and ZnTe) and (110) (CdTe) surfaces. They show strong incoming and outgoing resonances around the baud gap and larger scattering efficiencies as compaered to III-V compounds. A theoretical model which includes excitons as intermediate states in the Raman process is shown to give a very good quantitative agreement between theory and experiment. Only a small discrepancy exists, while III-V compounds the discrepancies were close to …
Partial self-consistency and analyticity in many-body perturbation theory: Particle number conservation and a generalized sum rule
2016
We consider a general class of approximations which guarantees the conservation of particle number in many-body perturbation theory. To do this we extend the concept of $\Phi$-derivability for the self-energy $\Sigma$ to a larger class of diagrammatic terms in which only some of the Green's function lines contain the fully dressed Green's function $G$. We call the corresponding approximations for $\Sigma$ partially $\Phi$-derivable. A special subclass of such approximations, which are gauge-invariant, is obtained by dressing loops in the diagrammatic expansion of $\Phi$ consistently with $G$. These approximations are number conserving but do not have to fulfill other conservation laws, such…
Exception-Tolerant Hierarchical Knowledge Bases for Forward Model Learning
2021
This article provides an overview of the recently proposed forward model approximation framework for learning games of the general video game artificial intelligence (GVGAI) framework. In contrast to other general game-playing algorithms, the proposed agent model does not need a full description of the game but can learn the game's rules by observing game state transitions. Based on hierarchical knowledge bases, the forward model can be learned and revised during game-play, improving the accuracy of the agent's state predictions over time. This allows the application of simulation-based search algorithms and belief revision techniques to previously unknown settings. We show that the propose…
A new approximation procedure for fractals
2003
AbstractThis paper is based upon Hutchinson's theory of generating fractals as fixed points of a finite set of contractions, when considering this finite set of contractions as a contractive set-valued map.We approximate the fractal using some preselected parameters and we obtain formulae describing the “distance” between the “exact fractal” and the “approximate fractal” in terms of the preselected parameters. Some examples and also computation programs are given, showing how our procedure works.
Invariant approximation results in cone metric spaces
2011
Some sufficient conditions for the existence of fixed point of mappings satisfying generalized weak contractive conditions is obtained. A fixed point theorem for nonexpansive mappings is also obtained. As an application, some invariant approximation results are derived in cone metric spaces.
Resonance of minimizers forn-level quantum systems with an arbitrary cost
2004
We consider an optimal control problem describing a laser-induced population transfer on a n-level quantum system. For a convex cost depending only on the moduli of controls ( i.e. the lasers intensities), we prove that there always exists a minimizer in resonance. This permits to justify some strategies used in experimental physics. It is also quite important because it permits to reduce remarkably the complexity of the problem (and extend some of our previous results for n=2 and n=3): instead of looking for minimizers on the sphere one is reduced to look just for minimizers on the sphere . Moreover, for the reduced problem, we investigate on the question of existence of strict abnormal mi…
Convergence of Markovian Stochastic Approximation with discontinuous dynamics
2016
This paper is devoted to the convergence analysis of stochastic approximation algorithms of the form $\theta_{n+1} = \theta_n + \gamma_{n+1} H_{\theta_n}({X_{n+1}})$, where ${\left\{ {\theta}_n, n \in {\mathbb{N}} \right\}}$ is an ${\mathbb{R}}^d$-valued sequence, ${\left\{ {\gamma}_n, n \in {\mathbb{N}} \right\}}$ is a deterministic stepsize sequence, and ${\left\{ {X}_n, n \in {\mathbb{N}} \right\}}$ is a controlled Markov chain. We study the convergence under weak assumptions on smoothness-in-$\theta$ of the function $\theta \mapsto H_{\theta}({x})$. It is usually assumed that this function is continuous for any $x$; in this work, we relax this condition. Our results are illustrated by c…
Fronts propagating with signal dependent speed in limited diffusion and related Hamilton-Jacobi formulations
2021
We consider a class of limited diffusion equations and explore the formation of diffusion fronts as the result of a combination of diffusive and hyperbolic transport. We analyze a new class of Hamilton-Jacobi equations arising from the convective part of general Fokker-Planck equations ruled by a non-negative diffusion coefficient that depends on the unknown and on the gradient of the unknown. We explore the main features of the solution of the Hamilton-Jacobi equations that contain shocks and propose a suitable numerical scheme that approximates the solution in a consistent way with respect to the solution of the associated Fokker-Planck equation. We analyze three model problems covering d…
Plasmon de surface de particules métalliques toroïdales
2006
This thesis deals with the optical properties of small metal torii. A method of resolution of the equation of Laplace in toroidal coordinates is introduced and the radiative properties of the metal toric nanoparticules are studied within the electrostatic framework. The study on the eigenmodes spatial distribution suggests that metal nanotorus can carry a non-zero magnetic dipole moment at optical frequencies. Analytical expressions for the extinction and scattering cross sections of the torus are also found and compared with numerical simulations and experimental results obtained with collaborations. The sensitivity of the plasmon frequency to the refraction index of the external medium an…