Search results for "aragonite"
showing 10 items of 90 documents
Geochemistry and mineralogy of travertine deposits of the SW flank of Mt. Etna (Italy): Relationships with past volcanic and degassing activity
2007
Abstract Travertine deposits outcropping in the lower SW flank of Mt. Etna were studied for their mapping, as well as for their chemical, mineralogical and isotopic compositions. These deposits are dated to about 24 to 5 ka in the Adrano area, located at the western limit of the study area. In this area travertines show high Mg contents and are composed mostly of dolomite, thus apparently ruling out any primary deposition in favour of a diagenetic origin. Travertines outcropping near Paterno, in the east part of the study area, should be younger than 18 ka. Those located to the SSW of Paterno (Paterno–Diga) show high Sr contents and aragonite as dominant mineralogical phase, thus suggesting…
Deep-water stromatolites andFrutexites Maslov from the early and Middle Jurassic of S-Germany and Austria
1993
Despite extensive discussions during the last 20 years stromatolites are still used by many geologists as unequivocal indicators of very shallow-water conditions. We investigated four stratigraphic units from the Lower and Middle Jurassic of southern Germany (Posidonien-Schiefer, Amaltheen-Ton) and of the Northern Calcareous Alps (Adneter Kalk, Klauskalk), which were formerly interpreted as shallow marine sediments by some authors due to the occurrence of stromatolites. Our interpretations of the macro-, micro- and ultrafacies of these sediments are not compatible with shallow-water settings. We therefore propose a deep-marine, aphotic origin of these stromatolites. Former interpretations o…
Nonenzymatic Transformation of Amorphous CaCO3 into Calcium Phosphate Mineral after Exposure to Sodium Phosphate in Vitro: Implications for in Vivo H…
2015
Studies indicate that mammalian bone formation is initiated at calcium carbonate bioseeds, a process that is driven enzymatically by carbonic anhydrase (CA). We show that amorphous calcium carbonate (ACC) and bicarbonate (HCO3 (-) ) cause induction of expression of the CA in human osteogenic SaOS-2 cells. The mineral deposits formed on the surface of the cells are rich in C, Ca and P. FTIR analysis revealed that ACC, vaterite, and aragonite, after exposure to phosphate, undergo transformation into calcium phosphate. This exchange was not seen for calcite. The changes to ACC, vaterite, and aragonite depended on the concentration of phosphate. The rate of incorporation of phosphate into ACC, …
Integrated annual calcium carbonate production of planktic calcifiers in the North Pacific from the R/V Kilo Moana cruise KM1712
2022
This dataset compiles the estimates of annual CaCO3 production, including the upper and lower limits of the estimates, for the 4 planktic calcifying groups considered in the study, the pteropods (mg/m²/yr), the heteropods (mg/m²/yr), the foraminifers (mg/m²/yr) and the coccolithophores (mg/m²/yr). The estimates derived from the living standing stocks of these 4 groups of organisms collected in the North Pacific between Hawaii and the Gulf of Alaska during the R/V Kilo Moana cruise KM1712 in August 2017. R code was used to calculate the integrated annual CaCO3 production for the different organisms, including the upper and lower limits (Gray, 2022).
Characterization and origin of permeability-porosity heterogeneity in shallow-marine carbonates: from core scale to 3D reservoir dimension (Middle Ju…
2014
21 pages; International audience; Nuclear magnetic resonance (NMR), stable isotope geochemistry of micro-sampled cores, NMR well-logs and 3D modeling are used to investigate the carbonate permeability-porosity heterogeneity along 230 m-thick limestones of the Paris Basin. Despite the global low porosity and permeability of the limestones, two aquifers units with porosity greater than 15% were identified. These two aquifers are very different in terms of pore through radii and NMR signal. The first one (A1: Aquifer 1) is a 7 m-thick mudstone unit, dominated by extended microporosity with pore throat radii of 0.25 μm to 0.3 μm. The second one (A2: Aquifer 2) is a 15 m-thick oolitic grainstone…
Paleoenvironmental evolution of the Pliocene Villarroya Lake, northern Spain. A multidisciplinary approach
2002
The Pliocene Villarroya basin fill consists of lacustrine and alluvial deposits over 100 m thick. The lacustrine deposits, up to 30 m thick, comprise three sequences. The two lower sequences consist of profundal, laminated deposits formed by mostly terrigenous facies that are overlain by charophytic carbonates and varves. The uppermost, third sequence made up of massive bioturbated mudstones corresponds to a very shallow lacustrine-palustrine environment. Bulk mineralogy comprises carbonates, clay minerals, quartz and feldspars. The carbonates are: exogenic, biogenic calcite and biogenic aragonite. Biogenic calcite constitutes ostracod shells and charophyte stem encrustations, whereas arago…
Calcification is not the Achilles' heel of cold-water corals in an acidifying ocean
2015
Ocean acidification is thought to be a major threat to coral reefs: laboratory evidence and CO2 seep research has shown adverse effects on many coral species, although a few are resilient. There are concerns that cold-water corals are even more vulnerable as they live in areas where aragonite saturation (?ara) is lower than in the tropics and is falling rapidly due to CO2 emissions. Here, we provide laboratory evidence that net (gross calcification minus dissolution) and gross calcification rates of three common cold-water corals, Caryophyllia smithii, Dendrophyllia cornigera, and Desmophyllum dianthus, are not affected by pCO2 levels expected for 2100 (pCO2 1058 ?atm, ?ara 1.29), and nor a…
Functional consequences of prey acclimation to ocean acidification for the prey and its predator
2016
Ocean acidification is the suite of chemical changes to the carbonate system of seawater as a consequence of anthropogenic carbon dioxide (CO2) emissions. Despite a growing body of evidences demonstrating the negative effects of ocean acidification on marine species, the consequences at the ecosystem level are still unclear. One factor limiting our ability to upscale from species to ecosystem is the poor mechanistic understanding of the functional consequences of the observed effects on organisms. This is particularly true in the context of species interactions. The aim of this work was to investigate the functional consequence of the exposure of a prey (the mussel Brachidontes pharaonis) t…
Discovery of Ca oxalate crystals associated with fungi in moss travertines (Bryoherms, freshwater heterogeneous stromatolites)
1995
Buffered decalcification of live moss and liverwort (Hepaticae) travertines resulted in the release of a large number of organisms (bacteria, cyanobacteria, fungi, eukaryotic algae, and small animals), which constitute an “organic mat”; (also called an algal mat or biofilm). This mat is calcified and commonly has laminations, allowing moss travertines to be considered as stromatolitic structures. After decalcification of 300 samples of travertines (using dilute acetic acid), only 9 released Ca oxalate crystals in the form of needle bundles, spherulites, and tetragonal bipyramidal prisms. These crystalline forms are identical to those found in some phanerophytes and soils. Mycelian filaments…
Calcification is not the Achilles'heel of cold-water corals in an acidifying ocean
2015
Ocean acidification is thought to be a major threat to coral reefs: laboratory evidence and CO2 seep research has shown adverse effects on many coral species, although a few are resilient. There are concerns that cold-water corals are even more vulnerable as they live in areas where aragonite saturation (Omega ara) is lower than in the tropics and is falling rapidly due to CO2 emissions. Here, we provide laboratory evidence that net (gross calcification minus dissolution) and gross calcification rates of three common cold-water corals, Caryophyllia smithii, Dendrophyllia cornigera, and Desmophyllum dianthus, are not affected by pCO2 levels expected for 2100 (pCO2 1058 µatm, Omega ara 1.29),…