Search results for "bentonite"
showing 10 items of 45 documents
The first 40Ar-39Ar date from Oxfordian ammonite-calibrated volcanic layers (bentonites) as a tie-point for the Late Jurassic.
2013
AbstractEight volcanic ash layers, linked to large explosive events caused by subduction-related volcanism from the Vardar Ocean back-arc, interbedded with marine limestones and cherts, have been identified in the Rosso Ammonitico Veronese Formation (northeastern Italy). The thickest ash layer, attributed to the Gregoryceras transversarium ammonite Biozone (Oxfordian Stage), yields a precise and reliable 40Ar–39Ar date of 156.1 ± 0.89 Ma, which is in better agreement with GTS2004 boundaries than with the current GTS2012. This first biostratigraphically well-constrained Oxfordian date is proposed as a new radiometric tie-point to improve the Geologic Time Scale for the Late Jurassic, where a…
Evidence of aerial volcanic activity during the Valanginian along the northern Tethys margin.
2009
7 pages; International audience; Stratigraphic measurement and sampling on three sections (Vergol, La Charce, and Montclus) through Valanginian deposits from the Vocontian Basin (southeastern France) reveals the occurrence of centimetre thick ochre-coloured layers, which can be correlated from one section to another. At least twelve of these are identified in sediments dated from the Pertransiens to Furcillata ammonite Zones. These horizons appear similar to previously described Oxfordian and Aptian bentonites, also from the Vocontian Basin. Clay-mineralogical and geochemical data are similar in the Valanginian ochre horizons and their enclosing marls except in one of these that shows a cla…
Diagenesis of clay minerals and K-bentonites in Late Permian/Early Triassic sediments of the Sichuan Basin (Chaotian section, Central China).
2014
10 pages; International audience; Detailed clay mineralogical analyses were carried out on Late Permian/Early Triassic carbonate sediments exposed on the Chaotian section (Sichuan Basin, Central China). The clay assemblages are dominantly composed of illite in platform carbonates and clay seams, and illite-smectite mixed-layers (I/S) in tuff layers (K-bentonites) intercalated in the carbonate succession. Detrital and authigenic volcanogenic clay minerals have been partially replaced through illitisation processes during burial, raising questions about diagenetic effects. The precise determination of I/S occurring in K-bentonites shows that the sediments reached a temperature of about 180 °C…
How to Deal with Uninvited Guests in Wine: Copper and Copper-containing Oxidases
2020
Copper is one of the most frequently occurring heavy metals in must and wine. It is introduced by pesticides, brass fittings, and as copper sulphate for treatment of reductive off-flavors. At higher concentrations, copper has harmful effects on the wine. It contributes to the oxidation of wine ingredients, browning reactions, cloudiness, inhibition of microorganisms, and wine fermentation. Last but not least, there is also a danger to the consumer. At present, some physicochemical methods exist to reduce the copper content in must and wine, but they all have their shortcomings. A possible solution is the biosorption of metals by yeasts or lactobacilli. Copper can also reach must and wine in…
Water retention and swelling behaviour of granular bentonites for application in Geosynthetic Clay Liner (GCL) systems
2016
Geosynthetic Clay Liner (GCL) systems are used as efficient hydraulic barriers in landfills for the disposal of hazardous municipal wastes. Along with geotextiles, bentonite materials are chosen as one of the primary components of GCLs due to their high retention, adsorption, and swelling capacities. GCLs are manufactured using bentonites at a high total suction and hydrated through the uptake of liquid from the subsoil and the confined material as soon as they are installed. Bentonites may exhibit considerable volume change upon wetting. Depending on the confinement stress, the void ratio may significantly increase with a decrease in suction, particularly at higher degrees of saturation. T…
RGD-mimic polyamidoamine-montmorillonite composites with tunable stiffness as scaffolds for bone tissue-engineering applications
2017
This paper reports on the development of montmorillonite (MMT)-reinforced hydrogels, based on a peptidomimetic polyamidoamine carrying guanidine pendants (AGMA1), as substrates for the osteo-induction of osteoblast precursor cells. AGMA1 hydrogels of various degrees of crosslinking responded favourably to MMT reinforcement, giving rise to composite hydrogels with shear storage modulus G', when fully swollen in water, up to 200 kPa, i.e. 20 times higher than the virgin hydrogels and of the same order or higher than other hydrogel-based composites proposed for orthopaedic applications. This significant improvement was ascribed to the effective interpenetration between the polymer matrix and t…
Natural Compounds as Sustainable Additives for Biopolymers
2020
In the last few decades, the interest towards natural compounds, coming from a natural source and biodegradable, for biopolymers is always increasing because of a public request for the formulation of safe, eco-friendly, and sustainable materials. The main classes of natural compounds for biopolymers are: (i) naturally occurring fillers (nFil), such as nano-/micro- sized layered alumino-silicate: halloysite, bentonite, montmorillonite, hydroxyapatite, calcium carbonate, etc.; (ii) naturally occurring fibers (nFib), such as wood and vegetable fibers; (iii) naturally occurring antioxidant molecules (nAO), such as phenols, polyphenols, vitamins, and carotenoids. However, in this short review, …
Aqueous nonionic copolymer-functionalized laponite clay. A thermodynamic and spectrophotometric study to characterize its behavior toward an organic …
2006
The affinity of functionalized Laponite clay toward an organic material in the aqueous phase was explored. Functionalization was performed by using triblock copolymers based on ethylene oxide (EO) and propylene oxide (PO) units that are EO(11)PO(16)EO(11) (L35) and PO(8)EO(23)PO(8) (10R5). Phenol (PhOH) was chosen as organic compound, which represents a contaminant prototype. To this purpose, densities and enthalpies of mixing as well as PhOH UV-absorption spectra were determined. The enthalpy and the spectrophotometry revealed PhOH-Laponite interactions whereas the volume did not. It emerged that the area occupied by PhOH on the Laponite surface is equal to that computed from the partial m…
Mineralogical variability of Callovo-Oxfordian clays from the Paris Basin and the Subalpine Basin.
2006
High-resolution clay mineralogical data at the Middle/Upper Jurassic boundary from the French Subalpine Basin, the Jura Mountains and the Paris Basin (ANDRA boreholes) from Callovo-Oxfordian clayey deposits allow spatial and temporal terrigenous flux evolution to be considered over a period of 6 to 7 Myr. Recorded diachronisms of major mineralogical changes and complex clays distribution at the Paris Basin scale result to combined palaeogeographic/eustatic variations and climate input. In the French Subalpine Basin, mineralogical homogeneity confirms the burial diagenesis influence, but other terrigenous supplies must be involved in contrast to the Paris Basin domains. Volcanogenic clays (b…
Preparation and characterization of organofunctionalized bentonite clay bearing aminophosphonic groups in heavy metal uptake
2019
Abstract Bentonite (Bnt) with covalently immobilized N-propylaminodi(methylenephosphonic) groups (Bnt-ADPA) was obtained through a two-step synthesis including aminosilanization and phosphorylation of resulting aminobentonite through Moedritzer-Irani reaction. The grafting of an aminosilane layer in the interplanar space of the bentonite was investigated by XRD, and the presence of N and P-containing groups was confirmed by FTIR, 31P and 29Si MAS NMR. The immobilization of the organic functional groups increased the interplanar distance in bentonite matrix at 52% that essentially improved filtration properties compared to raw bentonite. The number of surface acid groups was evaluated to 0.8…