Search results for "bioplastic"
showing 10 items of 20 documents
Bioplastic recovery from wastewater: A new protocol for polyhydroxyalkanoates (PHA) extraction from mixed microbial cultures
2019
Abstract A new protocol for polyhydroxyalkanoates (PHA) extraction from mixed microbial cultures (MMCs) is proposed. PHA-accumulating capacity of the MMC was selected in a sequencing batch reactor (SBR) fed with a synthetic effluent emulating a fermented oil mill wastewater (OMW). The highest recovery yield and purity (74 ± 8% and 100 ± 5%, respectively) was obtained when using NH4-Laurate for which operating conditions of the extraction process such as temperature, concentration and contact time were optimized. Best conditions for PHA extraction from MMC turned to be: i) a pre-treatment with NaClO at 85 °C with 1 h of contact time, followed by ii) a treatment with lauric acid in a ratio ac…
Thermoplastic starch and green tea blends with LLDPE films for active packaging of meat and oil-based products
2019
International audience; Thermoplastic starch (TPS) is an alternative biomaterial that can be used to produce bioplastics to replace petroleum-based food packaging. Active films were developed from acetylated cassava TPS and green tea using the blown extrusion process. Green tea (GT) and TPS from native starch (NS) and acetylated starch (AS) with different degrees of substitution (DS) were extruded with linear low-density polyethylene (LLDPE) at LLDPE/TPS-GT ratios of 70/30 and 60/40 prior to blown-film extrusion. Results indicated that a higher DS of AS enhanced melt flow index which altered processability and subsequently impacted film microstructures and physical and barrier properties. N…
QSPR Prediction of Retention Times of Methylxanthines and Cotinine by Bioplastic Evolution
2018
High-performance liquid-chromatographic retention times of methylxanthines and cotinine in human plasma and urine are modelled by structure–property relationships. Bioplastic evolution is an evolutionary perspective conjugating the effect of acquired characters, and relations that emerge among the principles of evolutionary indeterminacy, morphological determination and natural selection. It is applied to design co-ordination index, which is used to characterize retentions of methylxanthines, etc. Parameters used to calculate co-ordination index are formation enthalpy, molecular weight and surface area. Morphological and co-ordination indices provide strong correlations. Effect of different…
Green Composites Based on PLA and Agricultural or Marine Waste Prepared by FDM
2021
Three dimensional-printability of green composites is recently growing in importance and interest, especially in the view of feasibility to valorize agricultural and marine waste to attain green fillers capable of reducing bioplastic costs, without compromising their processability and performance from an environmental and mechanical standpoint. In this work, two lignocellulosic fillers, obtained from Opuntia ficus indica and Posidonia oceanica, were added to PLA and processed by FDM. Among the 3D printed biocomposites investigated, slight differences could be found in terms of PLA molecular weight and filler aspect ratio. It was shown that it is possible to replace up to 20% of bioplastic …
Beyond Biodegradability of Poly(lactic acid): Physical and Chemical Stability in Humid Environments
2017
International audience; Poly(lactic acid) (PLA) is the most traded biodegradable and biobased material. It is largely used as ecofriendly substitute of conventional plastics. Nevertheless, one of the main limiting factors is its water sensitivity. PLA reacts with water and is hydrolyzed during time, which determines its performance. Limited information related to the hydrolysis mechanism driven by water in vapor state is available in scientific literature. Literature is mainly focused on the effects of water in liquid state. This lack of information is of significant importance, since PLA interacts with water in both phases. This work was aimed to give a full depiction of the chemical and p…
Effects of halloysite content on the thermo-mechanical performances of composite bioplastics
2020
Abstract The aim of this study is the design and preparation of Mater-Bi/halloysite nanocomposite materials that could be employed as bioplastics alternative to the petroleum derived products. The biocomposite materials at variable halloysite content (from 0 to 30 wt%) were prepared by using the solvent casting method. We investigated the mechanical behaviour and the thermal properties of the prepared nanocomposites in order to estimate their suitability as biocompatible packaging materials. The thermo-mechanical characteristics were correlated to the nanocomposites' morphologies, which were studied by Scanning Electron Microscopy (SEM). As a general result, the physico-chemical performance…
An overview of nanoparticles role in the improvement of barrier properties of bioplastics for food packaging applications
2017
Abstract Plastics are the most demanding materials for the food packaging industry due to economical and practical reasons such as their low cost, lightness, easy to handle in integrated production lines, and their higher resistance than other materials. Besides containment and information, the packaging should protect foodstuffs from not only contamination but also the loss of food quality. Despite the many advantages, their inherent permeability is perhaps the foremost drawback that could lead to the loss of some food components and, also, to the transference of gases or moisture from the surrounding to the food. Thus, the barrier properties and the wettability are of fundamental importan…
Bioplastics: A new analytical challenge
2022
Even though petroleum-based plastics are advantageous in complying with the performance requirements in many applications, these are related, throughout their life cycle, to several environmental problems, including greenhouse gas emissions and persistence in marine and terrestrial environments. Therefore, the preservation of natural resources and climate change is considered worldwide, the main reason for which is necessary to reduce consumption and dependence on fossil-based materials. Biopolymers (PLA, PHAs, etc.) are examples of plastics whose use is grown exponentially over the years because of the improvements of their physical and mechanical properties using additives of various natu…
Influence of photo-oxidation on the performance and soil degradation of oxo- and biodegradable polymer-based items for agricultural applications
2021
Abstract The examination of the aging behavior of polymers, blends, composites, items, etc. under different environmental conditions is a priority issue for assessing the possible applications and establishing the lifetime. In agriculture, plastic items (mulch films, irrigation tubes, etc.) are widely used and subjected to solar UV exposure that can induce photo-oxidation on macromolecular chains. Therefore, weathering under outdoor conditions and accelerated degradation tests are performed for simulating aging processes during the lifetime of materials and select appropriate stabilizers to be used. In the last decades, oxo- and biodegradable polymers have been investigated and used in agri…
The Unintended Side Effects of Bioplastics: Carbon, Land, and Water Footprints
2020
(One Earth 3, 45–53, July 24, 2020) In the originally published version of this article, the authors inadvertently used global volumes of bioplastics in plastic packaging instead of European volumes for Figure 1C. After noticing this, the authors recalculated European bioplastic packaging consumption, and as such, Figure 1 and its legend have been corrected in the online article (as shown below) to reflect all data sources used for estimating European bioplastic volumes in Figure 1C. In the Experimental Procedures, the Data and Code Availability section has been updated, and the section “Estimation of European Bioplastic Volumes” has been added. Additionally, reference 69 is new, and two in…