Search results for "brine."
showing 10 items of 89 documents
A brine evaporative cooler/concentrator for autonomous thermal desalination units
2011
In recent years growing attention has been paid to the problem of brine disposal due to the raising awareness of significant environmental issues related to the use of desalination processes for fresh water production. This is particularly relevant when desalination units are located in remote sites, characterised by major complexity in the construction and management of intake and outfall structures. In the present work a novel device, named brine evaporative cooler/concentrator (BECC, patent pending), has been developed for coupling with small-scale thermal desalination plants in order to reduce the problem of brine disposal. Such device fulfils two different functions: i) cooling of the …
Analysis of Operational Parameters in Acid and Base Production Using an Electrodialysis with Bipolar Membranes Pilot Plant
2023
In agreement with the Water Framework Directive, Circular Economy and European Union (EU) Green Deal packages, the EU-funded WATER-MINING project aims to validate next-generation water resource solutions at the pre-commercial demonstration scale in order to provide water management and recovery of valuable materials from alternative sources. In the framework of the WATER-MINING project, desalination brines from the Lampedusa (Italy) seawater reverse osmosis (SWRO) plant will be used to produce freshwater and recover valuable salts by integrating different technologies. In particular, electrodialysis with bipolar membranes (EDBM) will be used to produce chemicals (NaOH and HCl). A novel EDBM…
Valorisation of SWRO brines in a remote island through a circular approach: Techno-economic analysis and perspectives
2022
Nowadays, small remote islands rely heavily on desalination technologies to overcome freshwater scarcity. Unfortunately, these technologies are accompanied by the production of brines which can affect the receiving water bodies i.e., the aquatic ecosystem. Yet, it is extremely appealing how such brines constitute an abundant source of valuable raw materials (such as magnesium). In this work, a novel hybrid system is introduced to capture the value of seawater reverse osmosis (SWRO) brines produced in the minor Sicilian island of Pantelleria. The “Minimal Liquid Discharge” (MLD) process consists of: (i) Nanofiltration NF (separation of bivalent from monovalent ions), (ii) Mg Reactive Crystal…
Valorization of seawater desalination brines through the integration of Eutectic Freeze Crystallization and Electrodialysis with Bipolar Membranes in…
2021
European policy encourages the adoption of sustainable systems that promote the efficient use and recovery of resources. Accordingly, this study proposes integrating two innovative technologies, including Eutectic Freeze Crystallization (EFC) and Electrodialysis with Bipolar Membranes (EDBM), for treating seawater desalination brines. Two experimental campaigns were conducted to assess the viability of this novel treatment chain. Using two lab-test rig units, the effect of various operating conditions on the outputs and general performance of both EFC and EDBM was evaluated. Firstly, results showed that EFC could manage seawater brines to (i) obtain pure sodium sulphate, and fresh water in …
Combined membrane and thermal desalination processes for the treatment of ion exchange resins spent brine
2019
Abstract The disposal of industrial wastewater effluents represents a critical environmental issue. This work focuses on the treatment of the spent brine produced by the regeneration of ion exchange resins employed for water softening. For the first time, a comprehensive techno-economic assessment and an analysis of the energy requirements of the treatment chain are carried out, via the simulation of ad hoc implemented models. The chain is composed of nanofiltration, double-stage crystallization and multi-effect distillation. The valuable product is the brine produced by the multi-effect distillation, which can be re-used for the regeneration. Therefore, the treatment chain’s economic feasi…
Techno-economic assessment of multi-effect distillation process for the treatment and recycling of ion exchange resin spent brines
2019
Abstract A treatment chain including nanofiltration, crystallization and multi-effect distillation (MED) is for the first time proposed for the treatment of an effluent produced during the regeneration of Ion Exchange resins employed for water softening. The goal is to recover the minerals and to restore the regenerant solution to be reused in the next regeneration cycle. MED is the most crucial unit of the treatment chain from an economic point of view. A techno-economic analysis on the MED unit was performed and a novel performance indicator, named Levelized Brine Cost, was introduced as a measure of the economic feasibility of the process. Different scenarios were analysed, assuming diff…
Valorization of surface-water RO brines via Assisted-Reverse Electrodialysis for minerals recovery: Performance analysis and scale-up perspectives
2022
Reverse osmosis (RO) processes have been recently identified as mostly capable of quantitative removal of salts and contaminants from saline and surface waters, though posing the problem of a concentrated brine to be disposed of and a produced permeate too low in minerals, thus requiring a sometimes expensive remineralization step. In the present paper, Assisted-Reverse Electrodialysis (A-RED) has been proposed for the remineralization of surface-water RO permeate by recovering minerals from its brine. A purposely developed and validated model has been adopted to carry out a parametric analysis for design and optimization of an industrial-scale plant. The techno-economic analysis underlined…
Performance of the first reverse electrodialysis pilot plant for power production from saline waters and concentrated brines
2016
Abstract This work reports experimental data collected for the first time on a full-scale RED pilot plant operated with natural streams in a real environment. The plant – located in the South of Italy – represents the final accomplishment of the REAPower project ( www.reapower.eu ). A RED unit equipped with almost 50 m2 of IEMs (125 cell pairs, 44x44 cm2) was tested, using both artificial and natural feed solutions, these latter corresponding to brackish water (≈0.03 M NaClequivalent) and saturated brine (4–5 M NaClequivalent). A power output up to around 40 W (i.e. 1.6 W/m2 of cell pair) was reached using natural solutions, while an increase of 60% was observed when testing the system with…
Towards 1 kW power production in a reverse electrodialysis pilot plant with saline waters and concentrated brines
2017
Abstract Reverse electrodialysis (RED) is a promising technology to extract energy from salinity gradients, especially in the areas where concentrated brine and saline waters are available as feed streams. A first pilot-scale plant was recently built in Trapani (Italy), and tested with real brackish water and brine from saltworks. The present work focuses on the scale-up of the pilot plant, reaching more than 400 m 2 of total membrane area installed and representing the largest operating RED plant so far reported in the literature. With a nominal power capacity of 1 kW, the pilot plant reached almost 700 W of power capacity using artificial brine and brackish water, while a 50% decrease in …
Feasibility of Producing Electricity, Hydrogen, and Chlorine via Reverse Electrodialysis
2022
Reverse electrodialysis (RED) is a technology to generate electricity from two streams with different salinities. While RED systems have been conventionally used for electricity generation, recent works explored combining RED for production of valuable gases. This work investigates the feasibility of producing hydrogen and chlorine in addition to electricity in an RED stack and identifies potential levers for improvement. A simplified one-dimensional model is adopted to assess the technical and economic feasibility of the process. We notice a strong disparity in typical current densities of RED fed with seawater and river water and that in typical water (or chlor-alkali) electrolysis. This …