Search results for "calor"

Protein and glycerol contents affect physico-chemical properties of soy protein isolate-based edible films

2010

Abstract This study was conducted to determine the effect of both soy protein and glycerol contents on physico-chemical properties of soy protein isolate-based edible (SPI) films. The aim of this study was to better understand the influence of SPI and GLY contents on the behavior of the physico-chemical properties of soy protein isolate-based films. Films were casted from heated (70 °C for 20 min) alkaline (pH 10) aqueous solutions of SPI at 6, 7, 8, and 9 (w/w %), glycerol (50%, w/w, of SPI) and SPI at 7 (w/w %), glycerol (40, 60, 70 %, w/w of SPI). Water vapor permeability (WVP), was measured at 25 °C and for four different relative humidities (30–100%, 30–84%, 30–75%, 30–53%). Surface pr…

A contribution to the study of staling of white bread: effect of water and hydrocolloid

1996

Abstract Staling of white bread at ambient temperature was studied using differential scanning calorimetry and dynamic mechanical thermal analysis. During storage, sample hydration varied slightly, from 0 to 0.4% per day, depending on packaging conditions. An increase in rigidity was observed, which was attributed both to starch retrogradation and to changes in the organization of the amorphous part of crumb. The glass transition temperature of crumb was not significantly modified by these structural changes. Hydrocolloids did not affect the overall shape of the viscoelastic behavior of crumb in the temperature range from −40°C to 80°C, and had a limited influence on the kinetics of starch …

Chiral hemicucurbit[8]uril as an anion receptor: selectivity to size, shape and charge distribution

2017

A novel eight-membered macrocycle of the hemicucurbit[n]uril family, chiral (all-R)-cyclohexanohemicucurbit[8]uril (cycHC[8]) binds anions in a purely protic solvent with remarkable selectivity. The cycHC[8] portals open and close to fully encapsulate anions in a 1 : 1 ratio, resembling a molecular Pac-Man™. Comprehensive gas, solution and solid phase studies prove that the binding is governed by the size, shape and charge distribution of the bound anion. Gas phase studies show an order of SbF6− ≈ PF6− > ReO4− > ClO4− > SCN− > BF4− > HSO4− > CF3SO3− for anion complexation strength. An extensive crystallographic study reveals the preferred orientations of the anions within the octahedral cav…

Oligoamide Foldamers as Helical Chloride Receptors-the Influence of Electron-Withdrawing Substituents on Anion-Binding Interactions.

2019

The anion-binding properties of three closely related oligoamide foldamers were studied using NMR spectroscopy, isothermal titration calorimetry and mass spectrometry, as well as DFT calculations. The 1 H NMR spectra of the foldamers in [D6 ]acetone solution revealed partial preorganization by intramolecular hydrogen bonding, which creates a suitable cavity for anion binding. The limited size of the cavity, however, enabled efficient binding by the inner amide protons only for the chloride anion resulting in the formation of a thermodynamically stable 1:1 complex. All 1:1 chloride complexes displayed a significant favourable contribution of the entropy term. Most likely, this is due to the …

2016 Antiaging Medicine

2016

• The factors best demonstrated to delay aging are fruit and vegetables, exercise, not smoking, drinking one or two glasses of alcohol daily, and fish consumption. • Vitamin D replacement, in persons with low 25[OH] vitamin D levels, decreases hip fractures, improves muscle strength, enhances function, and decreases mortality. • Antiaging medicine has been hijacked by charlatans who promote unproven or dangerous remedies to a naïve aging public. • Too often animal studies that produce longevity are directly ap-plied to humans before appropriate clinical trials have been carried out. • There is no evidence that hormones or megadoses of vitamins prolong life. • Numerous products of varying qu…

Appréciation d'un aliment nouveau et contrôle de la prise énergétique chez l'enfant : Impact de l'apprentissage

2013

In a context of high rate of obesity, understanding early formation of child eating behaviour, in qualitative and quantitative terms, is crucial. This work shows that new vegetable acceptance is positively associated with the introduction of variety since the beginning of the complementary feeding, and would be more difficult in 2 year old children. Moreover, the liking of a new food (vegetable or beverage) increases after familiarisation by repeated exposure. A transitional association between the new food and calories induces more stable liking than repeated exposure. However, a high energy density could limit intake of the new food by learned satiation. This result supports an ability of…

Latest results from CUPID-0

2022

International audience; CUPID-0 is a pilot experiment in scintillating cryogenic calorimetry for the search of neutrino-less double beta decay. 26 ZnSe crystals were operated continuously in the first project phase (March 2017 - December 2018), demonstrating unprecedented low levels of background in the region of interest at the Q-value of $^{82}\rm{Se}$. From this successful experience comes a demonstration of full alpha to beta/gamma background separation, the most stringent limits on the $^{82}\rm{Se}$ neutrino-less double beta decay, as well as the most precise measurement of the $^{82}$Se half-life. After a detector upgrade, CUPID-0 began its second and last phase (June 2019 - February…

Lien entre fonctionnement de la dyade mère-nourrisson au cours du repas et capacités d'ajustement énergétique autour de 11 mois

2018

Urate as effector for crustacean hemocyanins.

2004

Real time analysis of Escherichia coli biofilms using calorimetry

2008

Abstract Microbial communities grow more stably when they are associated to surfaces or organized in aggregates. This advantage of biofilms is technically exploited for the degradation of xenobiotics or in biocatalysis, where the fixed biomass has the added advantage of easier separation of excreted products. Whereas the biothermodynamic analysis of growth and product formation of suspended cells is developing fast, there are only few reports on the calorimetric analysis and biothermodynamic interpretation of biofilm evolution. Experiments illustrate the ability of calorimetry to monitor the physiological state of biofilms in real time. Sessile cells of Escherichia coli DH5α DSM 6897 were s…