Search results for "cellar"
showing 10 items of 230 documents
Heat capacities of butanol and pentanol in aqueous dodecyltrimethylammonium bromide solutions
1987
Heat capacities of the ternary systems water-dodecyltrimethylammonium bromide (DTAB)-butanol and water-DTAB-pentanol were measured at 25°C. The standard partial molar heat capacities of pentanol in micellar solutions show a maximum at about 0.35 mol-kg−1 DTAB that has been attributed to a micellar structural transition. This maximum tends to vanish by increasing the alcohol concentration and by decreasing the alcohol alkyl chain length; in the case of butanol it was not detected. The behavior of the standard partial molar heat capacities of alcohols in micellar solutions in the region above the cmc and below the structural transition was explained using a previously reported mass-action mod…
Determination of albendazole and ivermectin residues in cattle and poultry-derived samples from India by micellar liquid chromatography
2021
We have developed a method, based on micellar liquid chromatography, to determine albendazole and ivermectin in dairy products and biological waste from bovine, as well as edible tissues from poultry. Anthelmitics were resolved in less than 10 min using a C18 column and a mobile phase of 0.15 mol/L sodium dodecyl sulfate – 6% 1-pentanol at buffered at pH 7 with a 0.01 M phosphate salt, running under isocratic mode at 1 mL/min. Detection was by absorbance at 292 nm. Method was successfully validated following official validation guidelines, in terms of: selectivity, sensitivity, calibration range (0.0125−0.5 mg/kg to 25−50 mg/kg), linearity (r2 > 9990), trueness (86.3–105.6%), precision (<12…
Micellar and lyotropic behavior of three isomeric bola-amphiphiles with pyridinium groups
2010
The micellar and lyotropic phase behavior of three isomeric bola-amphiphiles 1, 2 and 3 based on para-, meta- and ortho-phenylene derivatives with hydrophilic pyridinium headgroups was investigated. The micellar behavior was characterized by surface-tension and conductivity measurements: while the para-substituted amphiphile 1 and the ortho isomer 3 aggregated to micelles, the meta-substituted amphiphile 2 exhibited stepwise, but discontinous self-association. This is explained by the mass-action and phase-separation model. The existence of “premicellar” aggregates and the discontinous aggregation of 2 is evidenced in addition by a difference-spectro-photometric measurement. The low surface…
Un secteur d'habitat du haut Moyen Âge (VIIe-XIIe siècle) et son espace funéraire à Pfulgriesheim, Rue du Levant (Bas-Rhin)
2022
The preventive archaeological excavations conducted by Inrap under the direction of Édith Peytremann in 2010, in the commune of Pfulgriesheim in the Kochersberg region, led to the discovery of a settlement sector occupied from the middle of the 7th century to the end of the 11th century. The singularity of the site lies in the absence of any pole constructions and the subdivision of the sector, from the 10th century onwards, by building on cellars associated with excavated huts, pits, and silos. The dynamics tend to show a retraction of the latter from the beginning of the 8th century to the middle of the 10th century, while it is marked by the presence of a funerary complex arranged along …
VERIFICA DI IPOTESI E PROCEDURE NELLA STIMA EMPIRICA DELLA PERDITA DI SUOLO PARCELLARE IN UN AMBIENTE MEDITERRANEO
2015
La stima dell’erosione idrica mediante approcci empirici ha interesse sia scientifico sia applicativo. Nella presente indagine è stata condotta una verifica di ipotesi e procedure adottate nella USLE e in modelli basati sullo schema USLE per la stima della perdita di suolo da parcelle di suolo nudo nell’area sperimentale di Sparacia, in Sicilia. La perdita di suolo per unità di superficie del singolo evento erosivo, Ae, non è significativamente dipendente dalla lunghezza parcellare, λ, in quanto all’aumentare di λ si riduce il deflusso ma cresce la concentrazione dei sedimenti. I valori di Ae sono crescenti con la pendenza parcellare, s, in quanto il coefficiente di deflusso non varia appre…
Study of lecithin reverse micelles by FT-IR spectroscopy
2007
FT-IR spectra of water/lecithin/deuterated cyclohexane microemulsions as a function of water/lecithin molar ratio R (R=[water]/[lecithin]) at various lecithin volume fractions (φ) have been recorded. After elimination of the spectral contributions due to the deuterated cyclohexane and normalization, the band parameters of the CO and PO4 vibrational modes due to lecithin have been found dependent only upon R. This behaviour has been interpreted in terms of a progressive structural modification of the water/lecithin interface superimposed to the progressive hydration of CO and PO4 groups. Moreover, no correlation between the CO and PO4 band parameters and the formation of gel-like micellar so…
Small-angle neutron scattering from lecithin reverse micelles
1996
Abstract We report new results of small-angle neutron scattering from cyclohexane- d 12 /lecithin/water micellar solutions, performed as a function of the water content, w 0 , the temperature, T and the dispersed-phase volume fraction, ф. The data from dilute samples can be interpreted in terms of the existence of giant cylindrical reverse micelles, in good agreement with the current idea of an unlimited micellar growth with ф. In contrast, the appearance of a sharp interference maximum at high concentrations ( ф > 0.15 ) suggests that the current hypothesis of a gel structure interpreted as a random network of entangled micelles can be assumed to be incorrect, and that there must be some c…
Stone winepress and cellars in the Iberian territory of Kelin (Utiel-Requena) (6th-2nd centuries BC)
2013
Los primeros indicios sobre cultivo de la vid en la comarca de Requena-Utiel son unas semillas carbonizadas de la ciudad ibérica de Kelin (Caudete de las Fuentes, València) del siglo VII a.C. No obstante, la expansión de su cultivo corresponde a los siglos V-III a.C. como se infiere del gran número de semillas carbonizadas, lagares de piedra, bodegas y ánforas, algunas con marcas pre y postcocción. En la actualidad, se conocen unos diez lagares de piedra de distinta capacidad, situados entre el valle del Cabriel y las ramblas de la Alcantarilla y Los Morenos. Todos ellos se encuentran asociados a materiales arqueológicos que permiten datarlos como ibéricos y, en uno de ellos se ha excavado …
Hydrophobin (HFBI): a potential fusion partner for one-step purification of recombinant proteins from insect cells
2008
Hydrophobins play an important role in binding and assembly of fungal surface structures as well as in medium-air interactions. These, hydrophobic properties provide interesting possibilities when purification of macromolecules is concerned. In aqueous micellar two-phase systems, based on surfactants, the water soluble hydrophobins are concentrated inside micellar structures and, thus, distributed to defined aqueous phases. This, one-step purification is attractive particularly when large-scale production of recombinant proteins is concerned. In the present study the hydrophobin HFBI of Trichoderma reesei was expressed as an N-terminal fusion with chicken avidin in baculovirus infected inse…
Spectroscopic and Structural Investigation of the Confinement of D and L Dimethyl Tartrate in Lecithin Reverse Micelles
2009
The confinement of D and L dimethyl tartrate in lecithin reverse micelles dispersed in cyclohexane has been investigated by FT-IR, polarimetry, electronic and vibrational circular dichroism (ECD and VCD), 1H NMR, and small-angle X-ray scattering (SAXS). Measurements have been performed at room temperature as a function of the solubilizate-to-surfactant molar ratio (R) at fixed lecithin concentration. The analysis of experimental data indicates that the dimethyl tartrate molecules are solubilized within reverse micelles in proximity to the surfactant head groups in the same way for the D and L forms. The encapsulation of dimethyl tatrate within lecithin reverse micelles involves changes in i…