Search results for "chalcogenides"

Raman Spectra of ZrS2 and ZrSe2 from Bulk to Atomically Thin Layers

2016

In the race towards two-dimensional electronic and optoelectronic devices, semiconducting transition metal dichalcogenides (TMDCs) from group VIB have been intensively studied in recent years due to the indirect to direct band-gap transition from bulk to the monolayer. However, new materials still need to be explored. For example, semiconducting TMDCs from group IVB have been predicted to have larger mobilities than their counterparts from group VIB in the monolayer limit. In this work we report the mechanical exfoliation of ZrX2 (X = S, Se) from bulk down to the monolayer and we study the dimensionality dependence of the Raman spectra in ambient conditions. We observe Raman signal from bul…

Mismatch strain versus dangling bonds: formation of "coin-roll nanowires" by stacking nanosheets.

2010

Theoretical study of cascade laser in erbium-doped chalcogenide glass fibers

2010

International audience; A theoretical investigation of an innovative cascade laser source is performed. The main goal of the work is the design of a continuous-wave (CW) photonic crystal fiber (PCF) laser, based on an erbium-doped chalcogenide glass. Due to the comparable lifetimes of the 4I13/2, 4I11/2 and 4I9/2 erbium energy levels, the simultaneous emissions at the wavelengths close to 2.7 μm and 4.5 μm are obtained with a pump wavelength close to 806 nm (direct pumping into the level 4I9/2). This scheme could be useful to develop high efficiency, high beam-quality and compact Near-IR and Mid-IR oscillators with single-mode output for applications not only in surgery but also in spectros…

High-pressure synthesis of boron-rich chalcogenides B12S and B12Se

2022

The authors thank Drs. I. Dovgaliuk and T. Chauveau for assistance with Rietveld analysis; and Drs. V. Bushlya and A. Jamali for help with EDX/SEM measurements. This work was financially supported by the European Union's Horizon 2020 Research and Innovation Program under Flintstone2020 project (grant agreement No 689279).

ZnS Ultrathin interfacial layers for optimizing carrier management in Sb2S3-based photovoltaics

2021

Antimony chalcogenides represent a family of materials of low toxicity and relative abundance, with a high potential for future sustainable solar energy conversion technology. However, solar cells based on antimony chalcogenides present open-circuit voltage losses that limit their efficiencies. These losses are attributed to several recombination mechanisms, with interfacial recombination being considered as one of the dominant processes. In this work, we exploit atomic layer deposition (ALD) to grow a series of ultrathin ZnS interfacial layers at the TiO2/Sb2S3 interface to mitigate interfacial recombination and to increase the carrier lifetime. ALD allows for very accurate control over th…

chalcogenide materials for nonlinear integreted optics in mid-infrared

2019

Elaboration and characterization of new compositions of chalcogenide materials exhibiting nonlinear effects for integrated optic applications and fabrication of low-loss waveguides.

Strong absorption and ultrafast localisation in NaBiS2 nanocrystals with slow charge-carrier recombination.

2022

Funder: AiF Project, no: ZIM-KK5085302DF0

Application of 2D Non-Graphene Materials and 2D Oxide Nanostructures for Biosensing Technology

2016

The discovery of graphene and its unique properties has inspired researchers to try to invent other two-dimensional (2D) materials. After considerable research effort, a distinct "beyond graphene" domain has been established, comprising the library of non-graphene 2D materials. It is significant that some 2D non-graphene materials possess solid advantages over their predecessor, such as having a direct band gap, and therefore are highly promising for a number of applications. These applications are not limited to nano- and opto-electronics, but have a strong potential in biosensing technologies, as one example. However, since most of the 2D non-graphene materials have been newly discovered,…

Design of Er3+-doped chalcogenide glass laser for MID-IR application

2009

Abstract The feasibility of a photonic crystal fiber laser (PCF laser), made of a novel Er 3+ -doped chalcogenide glass and operating at the wavelength λ s  = 4.5 μm is investigated. The design is performed on the basis of spectroscopic and optical parameters measured on a fabricated Er 3+ -doped Ga 5 Ge 20 Sb 10 S 65 chalcogenide bulk sample. The simulations have been performed by employing a home made numerical code that solves the multilevel rate equations and the power propagation equations via a Runge-Kutta iterative method. The numerical results indicate that a laser exhibiting slope efficiency close to the maximum theoretical one and a wide tunability in the wavelengths range where t…

Reversible self-assembly of metal chalcogenide/metal oxide nanostructures based on Pearson hardness.

2010

Nanotechnology has reached a stage of development where not individual nanoparticles but rather systems of greater complexity are the focus of concern. These complex structures incorporate two or more types of materials, an example of which is the formation of metal–semiconductor hybrids, which effectively combine the properties of both materials. The assembly of multicomponent nanoparticles from constituents with different optical, electrical, magnetic, and chemical properties can lead to novel functionalities that are independent of the individual components and may be tailored to fit a specific application. These applications include such far-reaching challenges as solar energy conversio…