Search results for "composites"
showing 10 items of 1905 documents
TOWARD A DESIGN METHOD FOR METAL-COMPOSITE CO-CURED JOINT BASED ON THE G-SIFs
2013
Abstract In this work, a systematic study of the singular stress field in the zone where the interface intersects the free edge surfaces of bonded metal-composite co-cured joints, has been performed. The obtained theoretical, numerical and experimental results have permitted to detect the relationships between the joint configuration and the singular stress field, as well as to implement a new design method based on the so called generalised stress intensity factors. Such a proposed method allows the user to predict the static strength of a generic metal-composite co-cured joint, vs. the main influence parameters as the elastic modulus of the coupled materials, the overlap length, the taper…
A Study on the Propagation of Plane Stress Waves across the Thickness of a Plate by the Method of Analytic Continuation in Time
2004
The interaction of plane tension/compression waves propagating within a plate perpendicularly to its surface is considered. The analytic solution is obtained by a modified method of characteristics for the one-dimensional wave equation used in problems on an impact of a rigid body on the surface of a plate. The displacements, velocities, and stresses in the plate are determined by the edge disturbance caused by the initial velocity and the stationary force field of masses of the striker and the plate. The method of analytic continuation in time put forward allows a stress analysis for an arbitrary time interval by using finite expressions. Contrary to a stress analysis in the frequency doma…
Role of organo-modifier and metal impurities of commercial nanoclays in the photo-and thermo-oxidation of polyamide 11 nanocomposites
2020
The photo-oxidative degradation processes of bio-based PA11 nanocomposites containing montmorillonite (MMT) and the organo-modified Cloisite®
NO2-controlled cargo delivery from gated silica mesoporous nanoparticles
2017
[EN] Cargo delivery from mesoporous silica nanoparticles loaded with sulforhodamine B and capped with a difluoroboron-dipyrromethene (BODIPY) derivative was triggered by a NO2-induced oxidative process.
Coordination polymers undergoing spin crossover and reversible ligand exchange in the solid
2006
Here we report the synthesis and characterisation of a polymer made up of a system of parallel 2-D grids of Fe(II) ions linked by [Au(CN)2]– bridges and its transformation into a new system of three interpenetrated 3-D coordination open frameworks with the NbO topology. Reversibility of this crystal-to-crystal transformation is evidenced by X-ray crystallographic data and from their spin crossover properties. Real Cabezos, Jose Antonio, Jose.A.Real@uv.es
A family of higher-order single layer plate models meeting Cz0-requirements for arbitrary laminates
2019
Abstract In the framework of displacement-based equivalent single layer (ESL) plate theories for laminates, this paper presents a generic and automatic method to extend a basis higher-order shear deformation theory (polynomial, trigonometric, hyperbolic…) to a multilayer C z 0 higher-order shear deformation theory. The key idea is to enhance the description of the cross-sectional warping: the odd high-order C z 1 function of the basis model is replaced by one odd and one even high-order function and including the characteristic zig-zag behaviour by means of piecewise linear functions. In order to account for arbitrary lamination schemes, four such piecewise continuous functions are consider…
Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H2O)2](C(CN)3)4…
2002
A new polynuclear copper(II) complex [Cu7(OH)6Cl2- (pn)6(H2O)2](C(CN)3)4Cl2 with hydroxo-bridging ligands has been prepared; the centrosymmetric cluster cation can be described as two Cu4O3Cl distorted cubane units sharing one copper cation. Clemente Juan, Juan Modesto, Juan.M.Clemente@uv.es ; Gomez Garcia, Carlos Jose, Carlos.Gomez@uv.es ; Coronado Miralles, Eugenio, Eugenio.Coronado@uv.es
Olive mill wastewaters decontamination based on organo-nano-clay composites
2019
Abstract Green composites for environmental applications were successfully prepared by intercalation of the biosurfactant Quillaja saponin onto montmorillonite mineral clay on varying pH and surfactant/clay ratio. Equilibrium adsorption isotherms were constructed and the system was characterized by performing TGA and XRD analyses. The efficiency of the surfactant-modified clay in the removal of the organic content present in olive mill wastewaters (OMW) was evaluated by means of spectrophotometric measurements. The interest for this cogent issue comes from the consideration that, despite their high pollutant content, OMW can be considered as a potential resource of several organic compounds…
Hygrothermal effect on moisture kinetics and mechanical properties of hemp/polypropylene composite: Experimental and numerical studies
2015
The exposition of thermoplastic composites reinforced with natural fibers to moisture and heat is likely to lower their mechanical properties and restrain their use in the design of parts. The present work is focussed on investigating the effects of hygrothermal aging on the mechanical behaviour of injected polypropylene reinforced with short hemp fibers. Moreover, the kinetic of isothermal moisture absorption has been studied for four immersion temperatures. The experimental results show that the time taken to reach saturation decreases significantly with increase in immersion temperature. These tests also reveal that moisture absorption in this type of materials does not follow Fick's law…
Structure and Mechanical Properties of Melt Intercalated Po1lypropylene–Organomontmorillonite Nanocomposites
2010
The preparation and properties of polymer nanocomposites, obtained by melt-compounding of polypropylene (PP) and organomontmorillonite (OMMT) modified by different alkyl ammonium salts, are described. A copolymer of maleic anhydride and PP was used as a compatibilizing additive. Nanocomposites with OMMT content of 1, 5 and 10 wt% were prepared and tested. The influence of OMMT content on the tensile stress–strain curves, elastic modulus, yield and tensile strength, and ultimate elongation of the nanocomposites is determined. The results of measuring the microhardness and impact strength of polymer nanocomposites are presented. Long-term creep tests were performed to predict the long-term de…