Search results for "coordination complex"
showing 10 items of 381 documents
A fluorinated 2D magnetic coordination polymer
2021
Herein we show the versatility of coordination chemistry to design and expand a family of 2D materials by incorporating F groups at the surface of the layers. Through the use of a prefuntionalized organic linker with F groups, it is possible to achieve a layered magnetic material based on Fe(ii) centers that are chemically stable in open air, contrary to the known 2D inorganic magnetic materials. The high quality of the single crystals and their robustness allow to fabricate 2D molecular materials by micromechanical exfoliation, preserving the crystalline nature of these layers together with the desired functionalization.
Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted [FeIII(aca…
2015
The syntheses, structures and magnetic properties of the coordination compounds of formula [FeIII(acac2-trien)][MnIICrIII(Cl2 An)3]·(CH3CN)2 (1), [FeIII(acac2-trien)][MnIICrIII(Br2An)3]·(CH3CN)2 (2) and [GaIII(acac2-trien)][MnIICrIII(Br2An)3]·(CH3CN)2 (3) are reported. They exhibit a 2D anionic network formed by Mn(II) and Cr(III) ions linked through anilate ligands, while the [FeIII(acac2-trien)]+ or [GaIII(acac2-trien)]+ charge-compensating cations are placed inside the hexagonal channels of the 2D network, instead of being inserted in the interlamellar spacing. Thus, these crystals are formed by hybrid layers assembled through van der Waals interactions. The magnetic properties indicate …
A Self-Assembled 2D Molecule-Based Magnet: The Honeycomb Layered Material {Co3Cl4(H2O)2[Co(Hbbiz)3]2}
2003
Research in the area of molecule-based magnets is rapidly expanding, owing, in part, to numerous breakthroughs in the past decade.[1] The preparation of solid-state architectures of varying dimensionalities from specifically tailored paramagnetic building blocks has proven to be very successful, and also clearly multidisciplinary. Materials science and supramolecular chemistry efforts have joined forces with classical organic and inorganic chemistry in the design of solid-state materials whose magnetic properties rival, and sometimes even exceed, those of classic inorganic solids.[2] The moleculebased strategy allows for the preparation of unusual materials that cannot otherwise be obtained…
Red-light-emitting electrochemical cell using a polypyridyl iridium(III) polymer.
2009
A deep-red phosphorescent ionic iridium(III) complex is prepared and incorporated into a polymer. Both the complex (1) and the polymer (2) were used as the single active material in solid-state light-emitting electrochemical cells (LECs). The devices built up using 1 and 2 emit in the deep-red region of the visible spectrum with CIE coordinates x = 0.710; y = 0.283 and x = 0.691; y = 0.289, respectively, making them one of the deepest-red emitting LECs reported. It is the first example of a polymeric LEC incorporating an ionic iridium complex, which exhibits increased stabilities compared with the device based on the small molecular weight complex.
Magnetic molecular nanostructures: Design of magnetic molecular materials as monolayers, multilayers and thin films
2007
In this paper we summarize the importance and versatility of the molecular approach in the design and development of novel magnetic molecular materials. These materials processing, in order to obtain controlled molecular structures at the nanoscale, will also be remarked.
Molecular spintronics: the role of coordination chemistry.
2016
Welcome to this themed issue of Dalton Transactions entitled ‘Molecular spintronics: the role of coordination chemistry’.
Dynamic magnetic MOFs.
2012
In this review we combine the use of coordination chemistry with the concepts of molecular magnetism to design magnetic Metal–Organic Frameworks (MOFs) in which the crystalline network undergoes a dynamic change upon application of an external stimulus. The various approaches so far developed to prepare these kinds of chemically or physically responsive MOFs with tunable magnetic properties are presented.
Experimental and Theoretical Study of Dynamic Structural Transformations between Sensing Copper(II)-Uracil Antiferromagnetic and Metamagnetic Coordin…
2020
This paper describes the synthesis and characterization of several Copper(II)-uracil-1-propionic acid (UPrOH) coordination compounds, including the theoretical and experimental study of their cryst...
Oxamato-based coordination polymers: recent advances in multifunctional magnetic materials
2014
The design and synthesis of novel examples of multifunctional magnetic materials based on the so-called coordination polymers (CPs) have become very attractive for chemists and physicists due to their potential applications in nanoscience and nanotechnology. However, their preparation is still an experimental challenge, which requires a deep knowledge of coordination chemistry and large skills in organic chemistry. The recent advances in this field using a molecular-programmed approach based on rational self-assembly methods which fully exploit the versatility of the coordination chemistry of the barely explored and evergreen family of N-substituted aromatic oligo(oxamato) ligands are prese…
Ligand design for multidimensional magnetic materials: a metallosupramolecular perspective.
2008
The aim and scope of this review is to show the general validity of the ‘complex-as-ligand’ approach for the rational design of metallosupramolecular assemblies of increasing structural and magnetic complexity. This is illustrated herein on the basis of our recent studies on oxamato complexes with transition metal ions looking for the limits of the research avenue opened by Kahn's pioneering research twenty years ago. The use as building blocks of mono-, di- and trinuclear metal complexes with a novel family of aromatic polyoxamato ligands allowed us to move further in the coordination chemistry-based approach to high-nuclearity coordination compounds and high-dimensionality coordination po…