Search results for "dame"
showing 10 items of 1466 documents
Photocatalytic and Catalytic Oxidation of 2-Propanol over Au/TiO2-CeO2 Catalysts
2016
Photocatalytic and catalytic oxidation of 2-propanol (representative VOC’s compound) were compared over mixed (Au)TiO2-CeO2-based catalysts. The role of support in Au catalyzed oxidation reaction under photo and dark conditions was studied. In the photocatalytic oxidation CeO2 had a negative effect on the performance towards the alcohol conversion of both TiO2-CeO2 and Au/TiO2-CeO2 catalysts, being Au/TiO2 the most active system. On the contrary mixed TiO2-CeO2 and Au/TiO2- CeO2 samples showed a higher catalytic oxidation efficiency for 2-propanol conversion compared to the single oxides.
Superparamagnetic recoverable flowerlike Fe3O4@Bi2O3 core–shell with g-C3N4 sheet nanocomposite: synthesis, characterization, mechanism and kinetic s…
2019
In the present research study, a simple method was developed for the synthesis of three-dimensional flowerlike Fe3O4@Bi2O3 core–shell with g-C3N4 sheet nanocomposites. The X-ray diffraction, Fourier transform infrared spectroscopy, scanning electronic microscopy, transmission electron microscope, vibrating sample magnetometer, dynamic laser scattering analyzer and UV–Vis diffuse reflection spectroscopy were employed for the characterization of structure, purity and morphology of the resultant samples. The degradation of indigo carmine as a model of organic dye pollutant is applied for photo-catalytic activity. The parameters which are affecting the efficiency of various parameters, such as;…
Structural Tuning and Conformational Stability of Aromatic Oligoamide Foldamers
2017
A series of aromatic oligoamide foldamers with two or three pyridine-2,6-dicarboxamide units as their main folding motifs and varying aromatic building blocks as linkers have been synthetized to study the effects of the structural variation on the folding properties and conformational stability. Crystallographic studies showed that in the solid state the central linker unit either elongates the helices and more open S-shaped conformations, compresses the helices to more compact conformations or acts as a rigid spacer separating the pyridine-2,6-dicarboxamide units, which for their part add the predictability of the conformational properties. Multidimensional NMR studies showed that, even in…
Formation of dibutyl carbonate and butylcarbamate via CO2 insertion in titanium(IV) butoxide and reaction with n-butylamine
2016
Abstract The species resulting from insertion of 12CO2 and 13CO2 into titanium(IV) butoxide is for the first time fully characterized by means of infrared and nuclear magnetic resonance spectroscopy. Results show formation of Ti-monobutylcarbonate, that easily undergoes nucleophilic attack by an aliphatic amine. The hydrolysis of the resulting species produces butylcarbamate and dibutylcarbonate as the only main products. Characterization results of the carbonate-like adduct, along with its reactivity with amine molecules open the route to new ways of CO2 utilization as building block for valuable organic compounds.
One-Pot, Clean Synthesis of Vanillic Acid from Ferulic Acid
2016
Ferulic acid dissolved in water is selectively oxidized to vanillic acid in high yield (≈60 %) under remarkably mild and green conditions, namely at room temperature with air as primary oxidant, over a catalytic amount of nanostructured Bi2WO6. The process is general and opens the route to the selective oxidation of natural substances into derivatives of significant applicative relevance.
Reactions in the presence of irradiated semiconductors: Are they simply photocatalytic?
2018
A generally accepted classification distinguishes semiconductor photocatalysis in type A and type B. The first class comprehends reactions where the primary redox products (radical anions and cations) further evolve giving rise to the final reduced and oxidized species. Type B reactions occur when the primary redox products undergo intermolecular bond formation to addition products. Recently, some photocatalytic reactions have been reported wherein the photocatalytically produced compounds are not the final products. In fact, they react in the solution bulk or catalytically on the surface of the semiconductor with other species thus producing the target compounds. These reactions, hereby re…
Study of a sample of faint Be stars in the exofield of CoRoT
2013
International audience; Context. Be stars are probably the most rapid rotators among stars in the main sequence (MS) and, as such, are excellent candidates to study the incidence of the rotation on the characteristics of their non-radial pulsations, as well as on their internal structure. Pulsations are also thought to be possible mechanisms that help the mass ejection needed to build up the circumstellar disks of Be stars.Aims. The purpose of this paper is to identify a number of faint Be stars observed with the CoRoT satellite and to determine their fundamental parameters, which will enable us to study their pulsation properties as a function of the location in the HR diagram and to searc…
Models and data analysis tools for the Solar Orbiter mission
2020
All authors: Rouillard, A. P.; Pinto, R. F.; Vourlidas, A.; De Groof, A.; Thompson, W. T.; Bemporad, A.; Dolei, S.; Indurain, M.; Buchlin, E.; Sasso, C.; Spadaro, D.; Dalmasse, K.; Hirzberger, J.; Zouganelis, I.; Strugarek, A.; Brun, A. S.; Alexandre, M.; Berghmans, D.; Raouafi, N. E.; Wiegelmann, T.; Pagano, P.; Arge, C. N.; Nieves-Chinchilla, T.; Lavarra, M.; Poirier, N.; Amari, T.; Aran, A.; Andretta, V.; Antonucci, E.; Anastasiadis, A.; Auchère, F.; Bellot Rubio, L.; Nicula, B.; Bonnin, X.; Bouchemit, M.; Budnik, E.; Caminade, S.; Cecconi, B.; Carlyle, J.; Cernuda, I.; Davila, J. M.; Etesi, L.; Espinosa Lara, F.; Fedorov, A.; Fineschi, S.; Fludra, A.; Génot, V.; Georgoulis, M. K.; Gilbe…
Deimatism: a neglected component of antipredator defence
2017
Deimatic or ‘startle’ displays cause a receiver to recoil reflexively in response to a sudden change in sensory input. Deimatism is sometimes implicitly treated as a form of aposematism (unprofitability associated with a signal). However, the fundamental difference is, in order to provide protection, deimatism does not require a predator to have any learned or innate aversion. Instead, deimatism can confer a survival advantage by exploiting existing neural mechanisms in a way that releases a reflexive response in the predator. We discuss the differences among deimatism, aposematism, and forms of mimicry, and their ecological and evolutionary implications. We highlight outstanding questions …
Bioethics and neuroethics
2019
Neuroethics officially appeared at the start of the 21st century due to the progress made by the neurosciences, as an applied ethics related to bioethics, but also as an independent discipline in its own right. As an applied ethics, it tackles issues bordering on bioethics. As independent neuroethics, it deals with established philosophical problems from a neuroscientific standpoint in the broader sense. It involves two central questions: the design of a framework in which to select, interpret and integrate data from neuroscience on morality and outlining the appropriate method or methods for this new branch of knowledge. In both cases, most neuroethicists curiously claim to take a naturali…