Search results for "density polyethylene"
showing 10 items of 140 documents
Effect of nano zinc oxide as UV stabilizer on the weathering performance of wood-polyethylene composite
2016
Abstract In this study, the effect of using nano-sized zinc oxide (ZnO) particles on the enhancement if the degradation resistance of wood-high density polyethylene (HDPE) composite was investigated through artificial weathering. Samples with different amounts of ZnO mixing ratio (0, 1, 2, and 4 wt%) were manufactured using an internal mixer followed by compression molding. The prepared samples were then exposed to the artificial weathering process in a QUV weatherometer. The weathering behavior of samples was characterized using tensile strength, contact angle analysis, colorimetry, ATR-FTIR spectroscopy and FE-SEM. The results indicated that the amount of surfaces crack, tensile strength …
Amorphous hydrogenated carbon (a-C:H) depositions on polyoxymethylene: Substrate influence on the characteristics of the developing coatings
2016
Abstract After oxygen plasma treatment polyoxymethylene (POM) material was exposed to acetylene plasma to progressively deposit two different types of amorphous hydrogenated carbon (a-C:H) films. Radio frequency plasma-enhanced chemical vapor deposition (RF-PECVD) was used to generate both plasma processes. The surface morphology of the coated samples has been investigated by atomic force microscopy (AFM) and their chemical composition by Diffusive Reflectance Infrared Fourier Transform (DRIFT) and Raman spectroscopy. Results revealed the absence of a solid interlayer formation between the a-C:H films and POM. The in sequence exposure of oxygen and acetylene plasma on POM substrate prevents…
“Compatibilization” through Elongational Flow Processing of LDPE/PA6 Blends
2018
Polyamide/polyolefin blends have gained attention from the academia and the industry for several years. However, in order to optimize their properties, some drawbacks such as chemical incompatibility must be adequately overcome. This can be done by adding suitable compatibilizers. On the other hand, it is less known that suitable processing techniques may also lead to significant results. In a previous work on a low-density polyethylene/polyamide 6 (LDPE/PA6) blend, we found that the orientation due to elongational flow processing conditions could lead to an unexpected brittle&ndash
Evolution of the sp2 content and revealed multilayer growth of amorphous hydrogenated carbon (a-C:H) films on selected thermoplastic materials
2017
Amorphous hydrogenated carbon (a-C:H) films were gradually deposited on high-density polyethylene (HDPE), polyethylene terephthalate (PET) and polyoxymethylene (POM) via an indirect (f-type) and a direct (r-type) plasma-enhanced chemical vapor deposition (PECVD) process with acetylene plasma. The surface morphologies of the thicker r-depositions on the three different thermoplastics have been analyzed by atomic force microscopy (AFM) at varying micrometer scales. Absorbance spectroscopy has been used to characterize the optical properties of all coatings. Intrinsic stress release phenomena are revealed on thicker layers through the detection of characteristic surface corrugations. Based on …
Influence of calcium‐based fillers and vegetable oil on the processability and yield behavior of polyolefins
1997
The mixing of different polyolefins, several calcium-based fillers, and a type of vegetable oil was investigated. The effect of viscosity and type of polyolefin on Young's modulus, yield stress, and elongation at yield has been determined. Tensile and machine torque properties have been studied for both mixing at 180°C and at 250°C as a function of the content of several types of calcium carbonate or calcium hydroxide filler. The influence of the addition of a sunflower oil as a lubricant has also been characterized. SEM micrographs indicate some problems of the formation of agglomerates and the influence of particle size on matrix morphology and filler/matrix adhesion. Physical and chemica…
Modified arabinoxylan-based films. Part B. Grafting of omega-3 fatty acids by oxygen plasma and electron beam irradiation.
2003
Arabinoxylans (AXs) are byproducts of the cereal milling industry. To obtain high-value products, AXs have been used as a film-forming agent. Hence, AX-based films are poor water vapor barriers. The objectives of this study were to graft omega-3 (omega3) fatty acids onto AX polymeric chains by using two new technologies: cold plasma and electron beam (EB) irradiation. Results show that the surface hydrophobicity of the modified films is higher than that of a waxy coating or a low-density polyethylene (LDPE) film. In addition, FTIR spectroscopy analysis reveals vibration bands attributed to new chemical functions. Finally, a decrease in water vapor permeability (WVP) is obtained for the film…
A quantitative electron-microscopic study of a linear polyethylene fraction crystallized at different temperatures
1981
Replica and thin-section electron microscopy was performed on a linear polyethylene fraction (Mw = 1.89 × 105, Mn = 1.79 × 10 5) which was either isothermally crystallized or quenched at difference temperatures. The results are numerically analyzed in such a manner so as to give the distribution of the total long spacing and of the crystallite and amorphous thicknesses. The quantitative information about the maximum and minimum values for these parameters at each crystallization temperature yields important clues as to possible molecular processes involved. Qualitative information regarding general morphology, molecular tilt with respect to the lamellar surface, and possible crystallographi…
A quantitative electron microscopic study of the crystallite structure of molecular weight fractions of linear polyethylene
1984
Utilizing thin-section techniques, transmission electron microscope studies were performed on a series of bulk-crystalized fractions of linear polyethylene covering the range M = 5 × 103−6 × 106. The crystallization conditions were varied from long-time isothermal to rapid quenching. Quantitative analysis could be carried out on such samples crystallized under controlled conditions. The crystallite thickness distributions and long periods are presented in terms of histograms. From these data the degree of crystallinity can be calculated and was found to compare favorably with that from other methods. The amorphous thickness increases significantly with molecular weight for all modes of crys…
Shear characterization of CaCO3-filled linear low density polyethylene
1988
Shear properties of CaCO3-filled linear low density polyethylene have been determined over a wide range of filler loading. The viscosity rises with the filler loading especially at low shear rates and a yield value appears for CaCO3-contents larger than 5%. The decrease of the die-swell ratios of the filled samples indicates a reduction of the melt elasticity.
Laboratory and in-situ tests for estimating improvements in asphalt concrete with the addition of an LDPE and EVA polymeric compound
2019
Abstract Pavement deformation is a critical issue in the design of pavement structures and the related mixture. Asphalt concretes may be very sensitive to this problem, in compliance with the viscoelastic behaviour of the adopted bitumen. To improve the material performance, many attempts have been made to introduce in the mixture other materials as “modifiers” or “additives” for increasing the permanent deformation resistance and the elastic modulus of the material. Among the different possible materials, polymers determined significant improvements in the road pavement performance. In this paper, the authors tested the adoption of a specifically engineered polymeric compound, in order to …