Search results for "diffusion"

showing 10 items of 1615 documents

Prediction of Maxwell – Stefan diffusion coefficients in polymer – multicomponent fluid systems

2014

Abstract Calculations of mass fluxes in multicomponent fluids based on the system of generalized Maxwell–Stefan equations (GMSE) is preferably used because Maxwell–Stefan (M–S) diffusion coefficients are symmetrical and have a clear physical meaning, as they reflect the binary friction forces between compounds in the system. For the calculation of the mass transport of a multicomponent fluid in the polymer basing on GMSE, it is necessary to have M–S diffusion coefficients. This paper proposes a method that allows their calculation using widely available self-diffusion coefficients and binary diffusion coefficients for infinitely diluted mixtures. The proposed method was compared with the me…

Activity coefficientMolar concentrationChemistryDiffusionThermodynamicsFiltration and SeparationMole fractionBiochemistrychemistry.chemical_compoundMaxwell–Stefan diffusionVinyl acetateGeneral Materials ScienceDiffusion; Multicomponent; Polymer; Free volume; Maxwell–StefanPhysical and Theoretical ChemistryTernary operationMass fractionJournal of Membrane Science
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Die bestimmung von sedimentationskoeffizient, diffusions-koeffizient und molekulargewicht von α-amylasen nach der methode des aktivitätstransportes

1965

Abstract Sedimentation and diffusion coefficients determined by optical methods on pure (crystallized) enzymes are compared with those obtained by activity measurements on the unpurified enzymes. On performing the experiments under suitable conditions, results of the two methods are in good agreement. The calculation of the molecular weights of the unpurified enzymes is somewhat uncertain because the partial specific volume in most cases is not accurately known.

Activity measurementsChromatographyMolecular massPartial specific volumeChemistryDiffusionPolymer chemistryBiochemistry Genetics and Molecular Biology (miscellaneous)Biochimica et Biophysica Acta (BBA) - Biophysics including Photosynthesis
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Virtual reality system for planning minimally invasive neurosurgery

2008

Object The authors report on their experience with a 3D virtual reality system for planning minimally invasive neurosurgical procedures. Methods Between October 2002 and April 2006, the authors used the Dextroscope (Volume Interactions, Ltd.) to plan neurosurgical procedures in 106 patients, including 100 with intracranial and 6 with spinal lesions. The planning was performed 1 to 3 days preoperatively, and in 12 cases, 3D prints of the planning procedure were taken into the operating room. A questionnaire was completed by the neurosurgeon after the planning procedure. Results After a short period of acclimatization, the system proved easy to operate and is currently used routinely for pre…

AdenomaAdultMaleHemangioma Cavernous Central Nervous Systemmedicine.medical_specialtySurgical strategyClinical Neurology610 Medicine & healthPlan (drawing)Virtual realitySurgical planningNeurosurgical ProceduresPatient Care PlanningUser-Computer Interface10180 Clinic for NeurosurgeryImaging Three-DimensionalImage Processing Computer-AssistedmedicineHumansMinimally Invasive Surgical ProceduresComputer SimulationMedical physicsAgedBrain Neoplasmsbusiness.industryAngiographyIntracranial AneurysmTechnical noteGeneral MedicineMiddle AgedMagnetic Resonance Imaging2746 SurgerySurgeryDextroscopeDiffusion Magnetic Resonance Imaging2728 Neurology (clinical)Surgery Computer-AssistedIntracranial lesionsFemaleSurgeryNeurosurgeryMeningiomaTomography X-Ray ComputedbusinessMagnetic Resonance AngiographyJournal of Neurosurgery
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Study and Modelling of the Vacuum Swing Adsorption (VSA) Process Employed in the Production of Oxygen

1999

An isothermal and non-equilibrium mathematical model was provided for the multi-component adsorption process. In addition, the software was developed for the VSA-based production of oxygen with the use of a CaX zeolite molecular sieve. The mathematical model and computer software were verified on the basis of experimental data. The study employed a test stand comprising two adsorption columns. The adsorption pressure P A = 150 and 135 kPa and desorption pressure P D = 20 kPa were adopted in the experiments. The tests produced oxygen with the purity of 90–94% O 2 (vol), at an efficiency of 55–73% and productivity of 570–850 kg O 2 per ton per day. The calculation results showed good consiste…

AdsorptionChromatographyChemistryGeneral Chemical EngineeringDiffusionDesorptionAnalytical chemistrySorptionGeneral ChemistryVacuum swing adsorptionMolecular sieveZeoliteIsothermal processChemical Engineering Research and Design
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Sorption Kinetics of Xenon on MFI-Type Zeolite Molecular Sieves

1990

Kinetic uptake data for xenon adsorbed onto large and uniform silicalite-I crystals are presented over a temperature range of 121 K to 296 K. — Adsorption isotherms and corrected diffusion coefficients derived from the uptake curves are given. The heat of adsorption and activation energy of diffusion were estimated from the plots of reciprocal temperature against the logarithm of equilibrium pressure and corrected diffusion coefficients, respectively. — While the corrected diffusion coefficient is independent of coverage for the higher temperatures, it decreases significantly at the lower temperatures investigated (<170 K) when the limiting adsorption capacity has been reached. — Comparing …

AdsorptionXenonChemistryGeneral Chemical EngineeringDiffusionPhysical chemistryNoble gaschemistry.chemical_elementThermodynamicsSorptionActivation energyAtmospheric temperature rangeOrder of magnitudeBerichte der Bunsengesellschaft für physikalische Chemie
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Whole-body MRI, FDG-PET/CT, and bone marrow biopsy, for the assessment of bone marrow involvement in patients with newly diagnosed lymphoma.

2016

To compare whole-body MRI (WB-MRI) with diffusion-weighted imaging (DWI), FDG-PET/CT, and bone marrow biopsy (BMB), for the evaluation of bone marrow involvement (BMI) in patients with newly diagnosed lymphoma.This retrospective study was approved by our Institutional Review Board. Two independent radiologists and one nuclear medicine specialist reviewed all WB-MRI and FDG-PET/CT scans prospectively performed on 104 patients with newly diagnosed lymphoma (53 males; 47 Hodgkin; mean age: 44 years; range, 15-86 years) between 2013 and 2015. The delay between imaging scans and BMBs was up to 10 days. The diagnostic accuracy of WB-MRI (1.5 Tesla MR scanner, with T1w, T2w-STIR, and DWI sequences…

AdultAged 80 and overMaleAdolescentLymphomaBiopsyReproducibility of ResultsstagingMiddle AgedMagnetic Resonance ImagingYoung Adultbone marrow biopsyDiffusion Magnetic Resonance ImagingBone MarrowFluorodeoxyglucose F18Positron Emission Tomography Computed TomographyHumansFemaleWhole Body Imagingpositron emission tomography-computerized tomographyRadiopharmaceuticalsAgedRetrospective StudiesJournal of magnetic resonance imaging : JMRI
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PET Studies of Net Blood—Brain Clearance of FDOPA to Human Brain: Age-Dependent Decline of [18F]Fluorodopamine Storage Capacity

2005

Conventional methods for the graphical analysis of 6-[18F]fluorodopa (FDOPA)/positron emission tomography (PET) recordings ( Kappin) may be prone to negative bias because of oversubtraction of the precursor pool in the region of interest, and because of diffusion of decarboxylated FDOPA metabolites from the brain. These effects may reduce the sensitivity of FDOPA/PET for the detection of age-related changes in dopamine innervations. To test for these biasing effects, we have used a constrained compartmental analysis to calculate the brain concentrations of the plasma metabolite 3- O-methyl-FDOPA (OMFD) during 120 mins of FDOPA circulation in healthy young, healthy elderly, and Parkinson's …

AdultAgingFluorine Radioisotopesmedicine.medical_specialtyMetaboliteDiffusionCentral nervous system diseasechemistry.chemical_compoundDopamineInternal medicinemedicineHumans18F-fluorodopamineFluorodopamedicine.diagnostic_testbusiness.industryPutamenBrainHuman brainMiddle Agedmedicine.diseaseDihydroxyphenylalanineEndocrinologymedicine.anatomical_structureNeurologychemistryPositron emission tomographyPositron-Emission TomographyNeurology (clinical)Cardiology and Cardiovascular MedicineNuclear medicinebusinessmedicine.drugJournal of Cerebral Blood Flow &amp; Metabolism
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Aberrant Subnetwork and Hub Dysconnectivity in Adult Bipolar Disorder: A Multicenter Graph Theory Analysis

2021

Abstract Neuroimaging evidence implicates structural network-level abnormalities in bipolar disorder (BD); however, there remain conflicting results in the current literature hampered by sample size limitations and clinical heterogeneity. Here, we set out to perform a multisite graph theory analysis to assess the extent of neuroanatomical dysconnectivity in a large representative study of individuals with BD. This cross-sectional multicenter international study assessed structural and diffusion-weighted magnetic resonance imaging data obtained from 109 subjects with BD type 1 and 103 psychiatrically healthy volunteers. Whole-brain metrics, permutation-based statistics, and connectivity of h…

AdultBipolar DisorderBipolar illnessCognitive NeuroscienceBrainHuman brainmedicine.diseaseMagnetic Resonance ImagingCellular and Molecular NeuroscienceCross-Sectional StudiesDiffusion Magnetic Resonance Imagingmedicine.anatomical_structureMoodNeuroimagingHealthy volunteersmedicineHumansOriginal ArticleBipolar disorderGraph theory analysisPsychologySubnetworkNeuroscienceCerebral Cortex
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Reduced interhemispheric structural connectivity between anterior cingulate cortices in borderline personality disorder

2008

Functional and structural alterations of the anterior cingulate cortex (ACC), a key region for emotional and cognitive processing, are associated with borderline personality disorder (BPD). However, the interhemispheric structural connectivity between the left and right ACC and between other prefrontal regions in this condition is unknown. We acquired diffusion-tensor imaging data from 20 healthy women and 19 women with BPD and comorbid attention-deficit hyperactivity disorder (ADHD). Interhemispheric structural connectivity between both sides of the ACC, dorsolateral prefrontal cortices and medial orbitofrontal cortices was assessed by a novel probabilistic diffusion tensor-based fiber tra…

AdultCingulate cortexDorsumAdolescentCentral nervous systemNeuroscience (miscellaneous)610 Medicine & health10056 Clinic for Clinical and Social Psychiatry Zurich West (former)Corpus callosumGyrus Cingulibehavioral disciplines and activitiesFunctional LateralityCorpus CallosumYoung Adult2738 Psychiatry and Mental HealthBorderline Personality DisorderNeural Pathwaysmental disordersImage Processing Computer-AssistedmedicineHumans2741 Radiology Nuclear Medicine and ImagingRadiology Nuclear Medicine and imagingBorderline personality disorderAnterior cingulate cortexBrain MappingCognitionMiddle Agedmedicine.diseasePsychiatry and Mental healthDiffusion Magnetic Resonance Imagingmedicine.anatomical_structurenervous system2801 Neuroscience (miscellaneous)Case-Control StudiesFemalePsychologyNeuroscienceDiffusion MRI
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Soluble-protein and antigenic heterogeneity in axenic Blastocystis hominis isolates: pathogenic implications.

1999

The protein profile and the antigenic cross-reactivity of 18 axenic isolates of Blastocystis hominis obtained from symptomatic patients with chronic diarrhea (14 isolates) showing no evidence of parasitic etiology and from patients with acute diarrhea attributable in 2 cases to Salmonella spp. were analyzed. Sodium dodecyl sulfate-polyacrylamide gel electrophoresis of soluble proteins showed the existence of a common profile composed of 31 bands, with molecular weights ranging between 24 and >200 kDa, and minor differences in the proteins of 149, 118, 106, 50, 48, 47, and 30 kDa. These differences allowed us to classify the strains into three related patterns (I–III). In an indirect immunof…

AdultDiarrheaSalmonellaImmunodiffusionProtozoan ProteinsAntigens ProtozoanHIV InfectionsBlastocystis InfectionsBiologyLoboseaCross Reactionsmedicine.disease_causeMicrobiologyAntigenmedicineAnimalsHumansBlastocystis hominisAxenicGel electrophoresisBlastocystisGeneral VeterinaryGeneral Medicinebiology.organism_classificationVirologyMolecular WeightDiarrheaInfectious DiseasesInsect ScienceAcute DiseaseChronic DiseaseSalmonella InfectionsProtozoaParasitologyElectrophoresis Polyacrylamide Gelmedicine.symptomParasitology research
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