Search results for "dimethyl sulfoxide"

showing 10 items of 200 documents

Cranioplasty with autologous bone flaps cryopreserved with Dimethylsulphoxide : does tissue processing matter

2021

Este artículo se encuentra disponible en la siguiente URL: https://www.sciencedirect.com/science/article/abs/pii/S1878875021001625?via%3Dihub En este artículo de investigación también participan: Dolores Ocete, Lucas Aranda, Ana Melero, Antonio J. Guillot, Nuria Yagüe y Carlos Botella. Este es el pre-print del siguiente artículo: Mirabet, V., García, D., Roca, A., Quiroz, A. R., Antón, J., Rodríguez-Cadarso, M., Ocete, D., Aranda, L., Melero, A., Guillot, A. J., Yagüe, N., Guillén, I. & Botella, C. (2021). Cranioplasty with autologous bone flaps cryopreserved with Dimethylsulphoxide: does tissue processing matter. World Neurosurgery, vol. 149 (may.), pp. e582?e591, que se ha publicado de fo…

MaleTime Factorsmedicine.medical_treatmentBrain EdemaSurgical Flaps0302 clinical medicineCryoprotective AgentsPostoperative ComplicationsHuesos - Crioconservación.Brain Injuries TraumaticAutograftsAutologous bone flapMiddle AgedCranioplastyResorptionAnti-Bacterial AgentsStrokeCryopreservacion of organs tissues etc.030220 oncology & carcinogenesisTissue bankVancomycinDecompressive craniectomyFemalemedicine.drugCrioconservación de órganos tejidos etc.Adultmedicine.medical_specialtyDecompressive CraniectomyAdolescentDecompressive craniectomyCráneo - Cirugía.CranioplastySkull - Surgery.03 medical and health sciencesYoung AdultmedicineHumansSurgical Wound InfectionDimethyl SulfoxideBones - Cryopreservacion.Bone ResorptionCryopreservationbusiness.industryBone storageSkullPostoperative complicationBone processingPlastic Surgery Proceduresmedicine.diseaseSurgeryHydrocephalusSurgeryNeurology (clinical)businessComplication030217 neurology & neurosurgery
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Antiepileptic effect of dimethyl sulfoxide in a rat model of temporal lobe epilepsy.

2012

Dimethyl sulfoxide (DMSO) is an amphipathic molecule widely used to solubilize water-insoluble compounds. In many studies it was reported that DMSO is capable of affecting several biological processes, thus resulting in a potential cause for the misinterpretation of experimental data. Recent papers showed that DMSO modified the brain bioelectric activity in animal models of epilepsy. In an in vivo model of temporal lobe epilepsy in the rat, we examined the effects of different doses (10%, 50% and 100%) of DMSO on the maximal dentate activation (MDA). The results show that DMSO induced a dose-dependent significant reduction of the electrically induced paroxysmal activity.

MaleTreatment outcomeRat modelAction PotentialsPharmacologySettore BIO/09 - FisiologiaTemporal lobeEpilepsychemistry.chemical_compoundIn vivomedicineAnimalsHumansDimethyl SulfoxideRats WistarTemporal lobe epilepsyDose-Response Relationship DrugChemistryDimethyl sulfoxideGeneral Neurosciencemedicine.diseaseRatsDose–response relationshipDisease Models AnimalMaximal dentate activationTreatment OutcomeBiochemistryCerebellar NucleiEpilepsy Temporal LobeSolubilizationAnticonvulsantsNeuroscience letters
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Delayed and incomplete treatment may result in dural fistula development in children with Vein of Galen malformation

2017

The association of dural arteriovenous fistulas (DAVF) in children with Vein of Galen malformation (VGM) has recently been reported for the first time. In a larger series of cases treated with transarterial NBCA embolization, 30% had DAVF. We wanted to analyze the development of DAVF in our cohort of children with VGM and to evaluate whether their occurrence depends on different treatment timing and embolic materials. We analyzed 43 VGM cases treated with a combined transarterial and transvenous approach between 2003 and 2016. In our early series until 2011, we used coils solely in 21 children. Since 2012, 22 children were treated with the combination of coils and Onyx. In the early series…

Malemedicine.medical_specialtyFistulamedicine.medical_treatment030218 nuclear medicine & medical imaging03 medical and health sciences0302 clinical medicineDural arteriovenous fistulasmedicineHumansTransvenous approachDimethyl SulfoxideEmbolizationVeinTreatment timingProximal occlusionCentral Nervous System Vascular Malformationsbusiness.industryAngiography Digital SubtractionInfantmedicine.diseaseEmbolization TherapeuticCerebral AngiographySurgeryTreatment Outcomemedicine.anatomical_structureChild PreschoolVein of Galen MalformationsFemalePolyvinylsRadiologybusinessAV ShuntsMagnetic Resonance Angiography030217 neurology & neurosurgeryInterventional Neuroradiology
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Naphthalimide imidazolium-based supramolecular hydrogels as bioimaging and theranostic soft materials

2020

1,8-Naphthalimide-based imidazolium salts differing for the alkyl chain length and the nature of the anion were synthesized and characterized to obtain fluorescent probes for bioimaging applications. First, their self-assembly behavior and gelling ability were investigated in water and water/dimethyl sulfoxide binary mixtures. Only salts having longer alkyl chains were able to give supramolecular hydrogels, whose properties were investigated by using a combined approach of fluorescence, resonance light scattering, and rheology measurements. Morphological information was obtained by scanning electron microscopy. In addition, conductive properties of organic salts in solution and gel state we…

Materials scienceCell SurvivalMacromolecular SubstancesSurface PropertiesScanning electron microscopeimidazolium salts010402 general chemistry01 natural sciencesTheranostic Nanomedicinechemistry.chemical_compoundbioimaging; fluorescence; imidazolium salts; naphthalimide; supramolecular hydrogelsCell Line TumorPhase (matter)HumansGeneral Materials ScienceParticle SizeSettore BIO/06 - Anatomia Comparata E CitologiabioimagingAlkylFluorescent Dyeschemistry.chemical_classificationMolecular Structure010405 organic chemistryDimethyl sulfoxideOptical ImagingImidazolesHydrogelsBiological activitySettore CHIM/06 - Chimica OrganicaResonance (chemistry)Combinatorial chemistryFluorescencenaphthalimide0104 chemical sciencesNaphthalimideschemistrySelf-healing hydrogelssupramolecular hydrogelsfluorescence
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Pulsed electric field (PEF) recovery of biomolecules from Chlorella: Extract efficiency, nutrient relative value, and algae morphology analysis

2023

This study investigated the effects of pulsed electric field (PEF) (3 kV/cm, 44 pulses, 99 kJ/kg), solvent (H2O or 50 % DMSO) and time (0, 10, 20, 30, 60, 90, 120 and 180 min) on the extraction of Chlorella antioxidant biomolecules and minerals. The results showed that PEF treatment increased the biomolecules recovery. For the extraction time of 120 min, more proteins and polyphenols were obtained using water, while more chlorophyll a and b, and carotenoids were obtained using 50 % DMSO as the extraction solvent. The extracts mineral concentration (PEF vs control) were analysed including Mg, P, Ca, Fe and Zn, and the Relative Nutrient Values results indicated that Chlorella H2O-extracts cou…

MineralsChlorophyll AChlorellaNutrientsGeneral MedicinePulsed electric fields (PEF)AntioxidantsAnalytical ChemistryAlguesSolventsMicroalgaeAlgues d'aigua dolçaDimethyl SulfoxideNutritive ValueMicrostructureFood ScienceFood Chemistry
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Syntheses, crystal structures, and oxidative DNA cleavage of some Cu(II) complexes of 5-amino-3-pyridin-2-yl-1,2,4-triazole

2004

Three new monomeric Cu(II) complexes of 5-amino-3-pyridin-2-yl-1,2,4-triazole (Hapt), [Cu(Hapt)(H(2)O)(2)(SO(4))] (1), [Cu(Hapt)(2)(H(2)O)(NO(3))](NO(3)) (2), and [Cu(Hapt)(2)(NCS-N)](NCS).H(2)O (3), have been prepared and characterized by single crystal X-ray diffraction. One distorted [CuN(2)O(2)+O(')] square-pyramidal (1), one distorted [CuN(3)O+N(')+O(')] octahedral (2), and one distorted [CuN(4)+N(')] intermediate between square-pyramidal and trigonal-bipyramidal (3) coordination configuration were found and are suggested to be due to the chelating nature of the ligand, which interacts with Cu(II) through the N4(triazole) and N(pyridine) atoms. Spectral properties of these chelates are…

Models MolecularDeoxyribonucleasesMolecular StructureStereochemistryDimethyl sulfoxideLigandSpectrum AnalysisMolecular Sequence Data124-TriazoleDNAFree Radical ScavengersCrystal structureTriazolesCrystallography X-RayBiochemistryMedicinal chemistryInorganic Chemistrychemistry.chemical_compoundMonomerchemistryOctahedronSodium azideChelationOxidation-ReductionCopperJournal of Inorganic Biochemistry
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CCDC 1555250: Experimental Crystal Structure Determination

2017

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

N2-{2-[(benzenecarbonyl)amino]phenyl}-N6-{2-[(2-{[6-({2-[(benzenecarbonyl)amino]phenyl}carbamoyl)pyridine-2-carbonyl]amino}benzene-1-carbonyl)amino]phenyl}pyridine-26-dicarboxamide perdeuterodimethyl sulfoxide solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Induction of micronuclei in V79 Chinese hamster cells by tetrachlorohydroquinone, a metabolite of pentachlorophenol

1992

Tetrachlorohydroquinone, a metabolite of the fungicide pentachlorophenol, induced significant dose-related increases in micronuclei in V79 Chinese hamster cells without exogenous metabolic activation. The lowest observed effective dose was 10 microM, where the relative survival was about 62%. At the highest dose tested, 20 microM, the relative survival was about 8% and the frequency of cells with micronuclei was about 6 times the solvent control frequency. The induction of micronuclei by tetrachlorohydroquinone was significantly inhibited by the hydroxyl radical scavenger dimethyl sulfoxide at 5% (v/v).

PentachlorophenolMetaboliteHamsterToxicologycomplex mixturesChinese hamsterchemistry.chemical_compoundCricetulusCricetinaeGeneticsAnimalsDimethyl SulfoxideCells CulturedMicronuclei Chromosome-DefectiveCarcinogenMicronucleus TestsbiologyDimethyl sulfoxidebiology.organism_classificationMolecular biologyEffective dose (pharmacology)HydroquinonesPentachlorophenolchemistryBiochemistryMicronucleus testDNA DamageMutation Research/Genetic Toxicology
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Enhancing Sensitivity of Microflow-Based Bottom-Up Proteomics through Postcolumn Solvent Addition.

2019

The introduction of more sensitive mass spectrometers allows researchers to adapt front-end liquid chromatography (LC) to individual needs for the analysis of complex proteomes. Where absolute sensitivity is not paramount, it is advantageous to switch from a highly sensitive nanoflow-LC setup, the de facto standard platform in mass-spectrometry (MS)-based discovery proteomics, to a more robust, high-throughput-compatible microflow or conventional-flow setup. To enhance the microflow-LC-MS electrospray process of complex proteomic samples, we tested the effects of different solvents, including 2-propanol, methanol, and acetonitrile, pure or as mixture with dimethyl sulfoxide, which were adde…

ProteomicsElectrospraySpectrometry Mass Electrospray IonizationChromatographyChemistryDimethyl sulfoxideElectrospray ionization010401 analytical chemistry010402 general chemistryMass spectrometry01 natural sciences0104 chemical sciencesAnalytical ChemistrySolventchemistry.chemical_compoundSolventsHumansNanotechnologyDimethyl SulfoxideBottom-up proteomicsMethanolAcetonitrilePeptidesChromatography High Pressure LiquidHeLa CellsAnalytical chemistry
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The contribution of hydrogen peroxide to the radiosensitizing effect of gold nanoparticles

2019

Abstract Plasmid DNA in aerated aqueous solution is used as a probe to determine whose of the reactive oxygen species (ROS) generated after absorption of ultra-soft X-rays (USX) take part in biomolecule damage in the presence and in absence of Gold Nano-Particles (GNP) and specific scavengers. Citrate-coated GNPs with core sizes of 6, 10 and 25 nm are synthetized and characterized, especially in terms of plasmon band shift, ζ-potential and hydrodynamic radii (respectively 9, 21 and 30 nm). We confirm the radiosensitizing effect of GNP and show that the SSB number per plasmid increases when, for a same mass of gold element, the core size of the gold nanoparticles decreases. Hydroxyl radicals…

Radiation-Sensitizing AgentsFormatesRadicalMetal Nanoparticles02 engineering and technologyPhotochemistry01 natural sciencesCitric AcidMetalchemistry.chemical_compoundColloid and Surface ChemistryPyruvic Acid0103 physical sciences[CHIM]Chemical SciencesMoleculeDimethyl SulfoxideDNA Breaks Single-StrandedParticle SizeTromethaminePhysical and Theoretical ChemistryHydrogen peroxideComputingMilieux_MISCELLANEOUSchemistry.chemical_classificationReactive oxygen speciesQuenching (fluorescence)Aqueous solution010304 chemical physicsHydroxyl RadicalX-RaysFree Radical ScavengersHydrogen PeroxideSurfaces and InterfacesGeneral Medicine021001 nanoscience & nanotechnologySolutionschemistryColloidal goldvisual_artvisual_art.visual_art_mediumGold0210 nano-technologyPlasmidsBiotechnologyColloids and Surfaces B: Biointerfaces
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