Search results for "dispersion"
showing 10 items of 1101 documents
Ab initio studies on the lattice thermal conductivity of silicon clathrate frameworks II and VIII
2016
The lattice thermal conductivities of silicon clathrate frameworks II and VIII are investigated by using ab initio lattice dynamics and iterative solution of the linearized Boltzmann transport equation(BTE) for phonons. Within the temperature range 100-350 K, the clathrate structures II and VIII were found to have lower lattice thermal conductivity values than silicon diamond structure (d-Si) by factors of 1/2 and 1/5, respectively. The main reason for the lower lattice thermal conductivity of the clathrate structure II in comparison to d-Si was found to be the harmonic phonon spectra, while in the case of the clathrate structure VIII, the difference is mainly due to the harmonic phonon spe…
Effects of partial self-ordering of Si dots formed by chemical vapor deposition on the threshold voltage window distribution of Si nanocrystal memori…
2006
We study the role that the denuded zone around Si nanocrystals obtained by chemical vapor deposition plays on the fluctuations of the dot surface coverage. In fact, the capture mechanism of the silicon adatoms in the proximity of existing dots restricts the number of possible nucleation sites, the final dot size, and the dot position, thus driving the process toward partial self-order. We numerically evaluate the relative dispersion of surface coverage for several gate areas and compare the results to the fully random case. The coverage dispersion is related to the fluctuations from bit to bit of the threshold voltage window (Δ Vth) distribution of nanocrystal memories. The evaluations, com…
Supercontinuum generation in silicon waveguides based on optical wave-breaking
2014
We theoretically find the third order dispersion that optimizes the spectral broadening induced by optical wave-breaking. It produces supercontinuum spectra spanning beyond 2=3 of an octave in a silicon waveguide pumping at 1550 nm.
Tunable radical scavenging activity of carbon nanotubes through sonication
2016
Abstract Carbon nanotubes (CNTs) having controlled radical scavenging activity have been achieved tuning the content of their lattice defects induced by an ultra-sound (us) treatment. The reactivity of CNTs, subjected to ultra-sonication for different time intervals, toward 1,1-diphenyl-2-pycryl (DPPH) and hydroxyl (•OH) radicals has been estimated and related to defect concentration, evaluated through Raman spectrometry. The radical scavenging efficiency of ultra-sound treated CNTs (us-CNTs) increases with increasing the content of the structural defects, suggesting that the defect resulting from us treatment can be capitalized to obtain an amplified and controlled radical scavenging activ…
ZnO nanoparticles embedded in UVM-7-like mesoporous silica materials: Synthesis and characterization
2009
Abstract ZnO nanodomains embedded in bimodal mesoporous silica (UVM-7) materials with high Zn content (4≤Si/Zn≤30) have been synthesized by an one-pot surfactant-assisted procedure from a hydro alcoholic medium using a cationic surfactant (CTMABr=cetyltrimethylammonium bromide) as structural directing agent, and starting from molecular atrane complexes of Zn and Si as hydrolytic inorganic precursors. This chemical procedure allows optimizing the dispersion of the ZnO particles in the silica walls. The bimodal mesoporous nature of the final high surface area nano-sized materials is confirmed by XRD, TEM, and N2 adsorption–desorption isotherms. The small intra-particle mesopore system is due …
Topological electronic structure and Weyl points in nonsymmorphic hexagonal materials
2020
Using topological band theory analysis we show that the nonsymmorphic symmetry operations in hexagonal lattices enforce Weyl points at the screw-invariant high-symmetry lines of the band structure. The corepresentation theory and connectivity group theory show that Weyl points are generated by band crossings in accordion-like and hourglass-like dispersion relations. These Weyl points are stable against weak perturbations and are protected by the screw rotation symmetry. Based on first-principles calculations we found a complete agreement between the topological predicted energy dispersion relations and real hexagonal materials. Topological charge (chirality) and Berry curvature calculations…
Octave-spanning coherent supercontinuum generation in a step-index tellurite fiber and towards few-cycle pulse compression at 2 μ m
2021
Abstract We experimentally demonstrate 140-THz bandwidth (at −20 dB) supercontinuum generation in a 10 cm-long all-normal dispersion step-index tellurite fiber pumped by a turn-key femtosecond fiber laser emitting at 2 . 11 μ m at a repetition rate of 19 MHz. The soliton self-frequency shifted thulium-doped fiber mode-locked laser emits initial transform-limited pulses, with 85-fs pulse duration, that are subsequently quasi-linearly chirped (over more than 50 THz) during the above nJ-level nonlinear propagation. Moreover, we numerically demonstrate the possible pulse compression down to 12 fs by means of additional linear propagation in a standard step-index fluoride fiber with anomalous di…
Relaxation of photogenerated carriers in P3HT:PCBM organic blends.
2009
Relaxing in the sunlight. Long time-transient decays of photogenerated carriers in P3HT:PCBM blends for organic solar cells are interpreted in terms of the relaxation of hole carriers in a broad density of states. The after-pulse time-resolved microwave conductivity (TRMC) decays observed in P3HT:PCBM blends display a dependence on time close to t−β, independent of excitation intensity, in the 10 ns–1 μs range. This is explained in terms of the relaxation of carriers in a Gaussian density of states (DOS). The model is based on a demarcation level that moves with time by thermal release and retrapping of initially trapped carriers. The model shows that when the disorder is large the after-pu…
Dynamic control of the operation regimes of a mode-locked fiber laser based on intracavity polarizing fibers: experimental and theoretical validation.
2012
[EN] An intracavity polarizing fiber is proposed to control the emission regime of a passively mode-locked fiber laser. Stable operation in self-starting high and low dispersion soliton mode-locking and 100 GHz multiwavelength regimes is demonstrated through numerical simulations and experimental validation. Mode-locking stability is ensured by a saturable absorber in the ring cavity. The effective selection of operation regime is dynamically carried out by controlling the intracavity polarization state.
One-Dimensional Hypersonic Phononic Crystals
2010
We report experimental observation of a normal incidence phononic band gap in one-dimensional periodic (SiO(2)/poly(methyl methacrylate)) multilayer film at gigahertz frequencies using Brillouin spectroscopy. The band gap to midgap ratio of 0.30 occurs for elastic wave propagation along the periodicity direction, whereas for inplane propagation the system displays an effective medium behavior. The phononic properties are well captured by numerical simulations. The porosity in the silica layers presents a structural scaffold for the introduction of secondary active media for potential coupling between phonons and other excitations, such as photons and electrons.