Search results for "dye"
showing 10 items of 577 documents
On the synthesis of functionalized porphyrins and porphyrin conjugates via β-aminoporphyrins
2016
International audience; The synthesis of functionalized porphyrins and their conjugates from meso-tetraarylporphyrins through the acylation and the oxidation of beta-aminoporphyrins was investigated. 2,3-Dioxochlorins were prepared by the oxidation of a variety of beta-aminoporphyrins and subsequently used in a condensation reaction with functionalized aromatic aldehydes and ammonium acetate to form beta-functionalized porphyrins bearing a fused imidazole ring. Under optimized experimental conditions both reactions tolerate various functional groups and afford the products in an appropriate overall yield. The mildness and usefulness of this methodology are illustrated by several examples in…
2-[4-(Dimethylamino)phenyl]-3,3-difluoro-3H-naphtho[1,2-e][1,3,2]oxazaborinin-2-ium-3-uide
2017
In the title compound, C19H17BF2N2O, a twist about the N—C single bond is observed, making the cross conjugation not as efficient as in the case of a planar structure. The borone complex has tetrahedral geometry. In the crystal, molecules are conected by weak C—H...F hydrogen bonds.
Crystal structure of 4-{2-[4-(dimethylamino)phenyl]diazen-1-yl}-1-methylpyridinium iodide
2015
The molecular geometry of the ionic title compound, C14H17N4+·I−or DAZOP+·I−, is essentially featureless. Regarding the crystal structure, in addition to the obvious cation–anion Coulombic interactions, the packing is mostly directed by non-covalent interactions involving both ring systems, as well as the iodide anion. It consists of cationic molecules aligned along [101] and disposed in an antiparallel fashion while linked into π-bonded dimeric entities by a stacking contact involving symmetry-related phenyl rings, with a centroid–centroid distance of 3.468 (3) Å and a slippage of 0.951 Å. The dimers are, in addition, sustained by a number of C—H...I and I...π (I...centroid = 3.876 Å) inte…
Indigon sinisestä kokenillin punaiseen : tekstiilivärjäyksessä käytettyjen luonnonväriaineiden tuonti Suomeen (1791–1856)
2022
Tutkimme ulkomaisten luonnonväriaineiden tuontia Suomeen 1790-luvun alusta 1850-luvun puoliväliin. Ajankohtaa voidaan luonnehtia murroskaudeksi väriaineiden käytön historiassa. Selvitämme mitä väriaineita Suomeen tuotiin, millaisia määriä, minneniitä tuotiin sekä mistä satamista väriainelastit olivat lähtöisin. Lähdeaineistomme perustan muodostavat Tanskan Juutinrauman tullitilit, joista on koostettu suomalaisia satamia koskeva tietokanta (FIN-STRO: 1560/1791–1856). Lähdepohjaa on täydennetty muulla tilastoaineistolla sekä laadullisella materiaalilla, kuten värjäysoppailla ja Kansalliskirjaston digitaalisella sanomalehtiarkistolla. Tutkimme erityisesti sinistä, punaista ja keltaista väriä t…
Dye molecules on titatium dioxide surface: cluster and periodic surface models
2008
Analiza etykiet produktów żywnościowych dostępnych w obrocie handlowym w Polsce pod kątem obecności barwników
2016
Barwniki spożywcze są nieodzownym elementem produkcji. Ich zawartość w artykułach żywnościowych jest ściśle limitowana obostrzeniami prawnymi. Ograniczenia zawartości poszczególnych barwników lub nawet zakaz ich stosowania w niekutych krajach związany jest z potencjalnym zagrożeniem dla zdrowia konsumenta. Celem przeprowadzonych badań była ocena występowania barwników w różnych kategoriach produktów spożywczych dostępnych w obrocie handlowym na terenie Opolszczyzny, w oparciu o składy podane na opakowaniach. Materiał badawczy stanowiło 197 produktów spożywczych różnych marek przyporządkowanych do 8 kategorii. Analizę składu artykułów spożywczych dokonano w oparciu o informacje zawarte przez…
MAHONIA AQUIFOLIUM AS A PROMISING RAW MATERIAL FOR THE FOOD INDUSTRY
2017
The development of the food industry leads to the expansion of the range of processed raw materials. Mahonia aquifolium today can be attributed to the non-traditional agricultural plants. However, the analysis of the chemical composition of the fruits showed that they contain significant amount of carbohydrates, vitamin C, various minerals, which recommend it for a wider use in the diet. Also due to the presence in the fruits of Mahonia aquifolium anthocyanins can extend of the use as raw material for natural anthocyanin dyes obtaining.
Assessing dye-tracer technique for rill flow velocity measurements
2018
Abstract Rill erosion is considered one of the most important processes affecting soil because of the large amount of soil loss. The rill network acts as sediment source and is able to transport both rill flow-detached particles and those delivered from the interrill areas. Small flow depth in a rill and steep slope values of its bed affect significantly flow hydraulics. When rill flow velocity is measured using a dye-tracing method, the mean velocity is calculated by multiplying the measured surface velocity of the leading edge of the tracer plume by a correction factor. The main uncertainty of the dye-tracing technique stands in the relationship between mean and surface flow velocity. In …
Performance Analyses of Innovative Glassblocks for BIPV
2014
The paper illustrates the results of the performance analyses conducted on an innovative glassblock integrated with 3rd generation dye-sensitized solar cells, designed for enabling the construction of translucent and sustainable building envelopes. The analyses encompass the simulation of both thermal and optical performance referring to different configurations of the PV-integrated glassblock, showing the results obtained by using two different software tools: Comsol Multiphysics and WINDOW. The configurations may differ, for example, because of the position of the module inside the glassblock, the type of dye-sensitized solar module used (composition, transparency, design), and glassblock…
Investigation of photoluminescence and amplified spontaneous emission properties of cyanoacetic acid derivative (KTB) in PVK amorphous thin films
2018
This work was supported by European Regional Development Fund within the Project No. 1.1.1.1/16/A/046 and A.Riekstins SIA “Mikrotīkls” donation, administered by University of Latvia Foundation.