Search results for "engineering.material"
showing 10 items of 2352 documents
Study of Coating/Work Material Interaction in Turning with Chip Forming Inserts
1997
This paper presents some interesting and novel results of an experimental study on the influence of the coating structure on the behaviour of the tribo-contact between the tool and the chip. The experiments involved TiC, TiC/TiN and TiC/Al2O3/TiN — coated flat-faced and grooved inserts in conjunction with a medium carbon steel and an austenitic stainless steel. Extensive experimental studies involving the cutting force and the tool-chip interface temperature were carried out. Two new parameters were introduced in order to compare both the mechanical and thermal loadings of the tool-chip contact for the two shapes of the rake face. Some optimal coating structures for high speed machining of …
Anodic growth of passive layers on steel rebars in an alkaline medium simulating the concrete pores
2006
Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) techniques have been used to study passive layers anodically grown on steel rebars in an aqueous alkaline solution simulating the electrolyte of the concrete pores. Nyquist diagrams recorded by EIS at the different stabilization potentials show a diffusional tail at low frequencies. The analysis of the impedance measurements has been made by means of an equivalent circuit with a Warburg component and within the framework of the point defect model (PDM) theory. It is observed that the calculated concentration of vacancies is a function of the potential in accordance with the theoretical prediction of the PDM.
Thermal Characterization of the Chip-Tool Interface When Using Coated Turning Inserts
2000
Abstract This paper reports some results of extensive experimental investigations of the thermal interactions between the coating/substrate and the moving surface of the chip. Semi-orthogonal cutting when bar turning a medium carbon steel and an austenitic stainless steel was carried out. Both flat-faced and grooved inserts coated with TiC, TiC/TiN, and TiC/Al 2 O 3 /TiN were tested. A standard K-type thermocouple embedded in the workpiece was used to convert measured efm's to the interfacial temperatures. In addition, the chiprake contact length and the area of contact were determined by using computer processing of scanned contact images. The minimum steady-state temperature at the interf…
Pd supported on magnetic carbon coated halloysite as hydrogenation catalyst: Study of the contribution of carbon layer and magnetization to the catal…
2019
Abstract In this article, a magnetic carbon-coated halloysite nanoclay (Hal) was prepared through introduction of hydrothermally carbonized glucose (Glu) on Hal followed by the immobilization of magnetic nanoparticles (MNPs) and incorporation of resorcinol-formaldehyde polymeric shell (RF) and carbonization. The resulting composite was then successfully applied for the immobilization of Pd nanoparticles to afford Pd@Hal@Glu-Fe-C that could efficiently promote hydrogenation of nitroarenes in the aqueous media at low temperature. The catalyst exhibited high selectivity toward nitro group. Moreover, it was highly recyclable with low MNPs and Pd leaching. To elucidate the contribution of each c…
PEM electrolyzer characterization with carbon-based hardware and material sets
2021
Abstract The research and development of proton exchange membrane water electrolysis (PEMWE) is an upcoming and growing area due to a rising interest in hydrogen as an energy carrier. Operating conditions are harsher than in a fuel cell system, particularly because the potentials required for the oxygen evolution reaction are significantly higher. In commercial water electrolysis systems, this is compensated by typically using titanium material sets that are often protected against oxidation through coating processes. Such material choices make small scale research hardware and porous transport layers expensive and difficult to source. In this work, we show that the stability of traditional…
Multifunctional Carrier Based on Halloysite/Laponite Hybrid Hydrogel for Kartogenin Delivery
2018
[Image: see text] A novel carrier system based on halloysite nanotubes (HNT), for the potential intraarticular delivery of kartogenin (KGN) by means laponite (Lap) hydrogel (HNT/KGN/Lap), is developed. The drug was first loaded into HNT, and the hybrid composite obtained was used as filler for laponite hydrogel. Both the filler and the hydrogel were thoroughly investigated by several techniques and the hydrogel morphology was imaged by transmission electron microscopy. Furthermore, the gelating ability of laponite in the presence of the filler and the rheological properties of the hybrid hydrogel were also investigated. The kinetic release of kartogenin from HNT and HNT/Lap hybrid hydrogel …
Electrochemical Characterization of Archaeological Tin-Opacified Lead-Alkali Glazes and Their Corrosion Processes
2005
The electrochemical response of weathered and unweathered archaeological tin-opacified glazes attached to paraffin-impregnated graphite electrodes is described. Upon comparison with the square wave voltammetric response of SnO2, PbO and PbO2, Sn- and Pb-centered reduction processes can be characterized. Reduction of Sn(IV) involves the stepwise formation of solid Sn(II) and Sn metal, successively, at potentials of −0.08 and −0.55 V vs. AgCl/Ag. Reduction of network-modifier Pb(II) in glazes occurs at −0.5 V and is accompanied by the reduction of network-forming Pb(IV) at potentials ranging from +0.65 to +0.20 V, confirming the presence of such centers in glazes. Voltammetric data suggest th…
Atomic layer deposition of Ti-Nb-O thin films onto electrospun fibers for fibrous and tubular catalyst support structures
2018
Here, the authors report on the preparation of core-shell carbon-ceramic fibrous as well as ceramic tubular catalyst supports utilizing electrospinning and atomic layer deposition (ALD). In this paper, ALD of Ti-Nb-O thin films using TiCl4, Nb(OEt)5, and H2O as precursors is demonstrated. According to the time-of-flight-elastic recoil detection analysis and Rutherford backscattering spectrometry, carbon and hydrogen impurities were relatively low, but depend on the pulsing ratio of the precursors. Optimized ALD process was used for coating of sacrificial electrospun polyvinyl alcohol (PVA) template fibers to yield tubular Ti-Nb-O structures after thermal or solution based PVA removal. Anoth…
Induced Modification of Flexural Toughness of Natural Hydraulic Lime Based Mortars by Addition of Giant Reed Fibers
2020
Abstract Nowadays, there is a growing need to reduce the environmental impact generated by the use of inorganic materials for building applications. The aim of this work is to investigate the bio-lime based mortar flexural toughness improvement due to the addition of common reed fibers (Arundo donax L.) in order to evaluate their possible application as ductile eco-compatible prefabricated bricks or laying and joint mortars for masonry. Different sets of specimens were tested by varying the fiber weight content and the fiber length. Moreover, chemical treatments with Linseed Oil and Polyethylene glycol (PEG) were performed to improve the physical and mechanical properties of the fibers as w…
Performance of Multilayered Particles: Influence of a Thin Cushioning Layer
2005
Nowadays, oral dosage forms with controlled release kinetics have known an increasing interest. The polymer coating of drug-loaded particles is one of the most common methods used for controlling drug delivery. Such multilayered particles could be either filled into capsules or compressed into tablets for their oral administration. However, many studies have noticed that coating films are damaged during the compression process, leading to significant changes in drug release profiles. The aims of this study were to investigate the effects of a thin cushioning layer [made of HydroxyPropylMethyl Cellulose (HPMC)] applied on coated theophylline particles upon particle characteristics, tablet pr…