Search results for "engineering.material"
showing 10 items of 2352 documents
Unidirectional Spin Hall Magnetoresistance as a Tool for Probing the Interfacial Spin Polarization of Co2MnSi
2019
Materials with high spin polarization, such as Heusler compounds, are required for efficient spintronics. The authors propose an approach to probe the transport spin polarization at interfaces, using the recently discovered unidirectional spin Hall magnetoresistance. They show that insertion of thin Ag(001) layers clearly increases the interfacial spin polarization of the Heusler compound Co${}_{2}$MnSi, which is crucial for giant-magnetoresistance devices.
Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers
2017
Mesocrystals of a porous coordination polymer {Fe(pz)[Pt(CN)4]} (1) showing spin transition were prepared by the reverse micelle method, and the size-controlled mesocrystal 1 kept its porous property and magnetic bistability and exhibited higher guest-responsivity with switching the spin state in both solid and aqueous suspension states than the bulk 1.
Crystallization and microstructural development of nickel-containing aluminosilicate glasses with cordierite stoichiometry
2001
Abstract The crystallization behaviour of two glasses with chemical compositions MAl2O4/SiO2=1/2.5, being MNi and equimolar mixtures of Mg and Ni, was investigated. Glasses were prepared by cooling samples melted at 1650 °C. During thermal treatment over the range of temperature up to 1200 °C both glasses were first crystallized to form a β-quartz solid solution, then transformed to α-cordierite or spinel depending on the amount of nickel. The temperatures of both the crystallization of β-quartz solid solution and its further transformation were also dependent on the nominal amount of nickel. Lower temperatures were found for glasses with a large amount of nickel. UV–Vis diffuse reflectanc…
Temperature dependence of oxidation behavior and coercivity evolution in fine-grained spinel ferrites
2000
Abstract The present paper reviews for a series of fine-grained MxCoyFe(3−x−y)O4 spinel ferrites (M=Mn, Mo, Cu, V) which oxidize into mixed-valence defect ferrites, a systematic study of the correlation between the oxidation temperature and the variation of coercivity. An increase of the coercivity is observed as often as the oxidation reactions Fe2+→Fe3+ and Mn+→M(n+m)+ (1⩽m⩽3) occur. This enhancement of coercivity has been explained by stresses generated during each specific oxidation reaction. The well-known property of cobalt to strongly magnify the magnetostrictive effects has been used to support this interpretation.
Influence of iron non-stoichiometry on spinel zinc ferrite gas sensing properties
2012
Abstract It is demonstrated for the first time that the gas sensing properties of a spinel ferrite complex metal oxide semiconductor can be improved by controlling iron stoichiometry. Conductivity and sensitivity was analyzed for ZnFe2+zO4± spinel type ferrite with z from −0.01 to 0.15. By increasing iron content from z = −0.01 to z = 0.1, sensitivity increases up to 3 times but for samples with z > 0.1 sensitivity drops. It was observed from impedance spectroscopy measurements that resistance decreases with an increase of the iron content. Complex impedance spectra reveal two phases with different resistance attributed to depletion layer (Rd) and bulk (Rb). With increasing iron content inc…
Effect of thermal treatment on the structural evolution of 3:2 and 2:1 mullite monophasic gels
2005
Abstract Single phase mullite gels with composition 3Al2O3 · 2SiO2 (3:2) and 2Al2O3 · SiO2 (2:1) were prepared by the semialkoxide method using aluminum nitrate nonahydrate and tetraethylorthosilicate as reagents. The influence of the thermal processing conditions on the reaction sequence was investigated. Both 3:2 and 2:1 mullite gels formed orthorhombic mullite under fast heating (40 °C/min) at 900 °C. Slow heatings delayed the formation of mullite in both gel compositions but no formation of spinel was detected between 1000 °C and 1100 °C. The slow transformation of pentacoordinated aluminum to octahedral and tetrahedral arrangements probably depends on the larger size and extent of the …
Cobalt aluminate spinel-mullite composites synthesized by sol-gel method
1997
Abstract CoAl 2 O 4 spinel-mullite composites were prepared by double substitution of Al by Ti and Ni in stoichiometric 3:2 mullite. Gels with compositions 3(Al 2 − 2 x Co x Ti x O 3 )·2SiO 2 (x = 0.025, 0.05 and 0.2) and 3(Al 2 − 2 x M x O 3 )·2SiO 2 (x = 0.05; M = Co 2+ or Ti 4+ ) were synthesized by sol-gel techniques. The structure of the gels was investigated by infra-red spectroscopy. Heating gels at 750 °C produced an amorphous silicoaluminate network. The reaction sequence was investigated by differential thermal analysis, X-ray diffraction and ultraviolet-visible spectroscopy. All samples crystallized at temperatures lower than 1000 °C from the amorphous state. Al-Si spinel and/or …
Theoretical and experimental developments in quantum spin liquid in geometrically frustrated magnets: a review
2019
The exotic substances have exotic properties. One class of such substances is geometrically frustrated magnets, where correlated spins reside in the sites of triangular or kagome lattice. In some cases, such magnet would not have long-range magnetic order. Rather, its spins tend to form kind of pairs, called valence bonds. At $$T \rightarrow 0$$ these highly entangled quantum objects condense in the form of a liquid, called quantum spin liquid (QSL). The observation of a gapless QSL in actual materials is of fundamental significance both theoretically and technologically, as it could open a path to creation of topologically protected states for quantum information processing and computation…
Influence of nanoscale order–disorder transitions on the magnetic properties of Heusler compounds for spintronics
2017
Modifications in nanoscale chemical order are used to tune the magnetic properties, namely T-C, of Co2FeSixAl1-x (0 < x < 1). High-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) with Z-contrast reveals nanoscale regions of L2(1) order within a B2 matrix in the off-stoichiometry samples. Perhaps surprisingly, the latter, more chemically disordered structure, exhibits a higher T-C. Upon annealing, the off-stoichiometry samples become more homogeneous with the fraction of L2(1) order decreasing. The short-range order was also investigated using X-ray absorption fine structure (XAFS) measurements at the Co and Fe K edges. Since the local atomic environments of C…
Half-metallic compensated ferrimagnetism with a tunable compensation point over a wide temperature range in the Mn-Fe-V-Al Heusler system
2017
The cubic Heusler compound Mn1.5FeV0.5Al with the L21 Heusler structure is the first fully compensated half-metallic ferrimagnet with 24 valence electrons. The ferrimagnetic state can be tuned by changing the composition such that the compensation point appears at finite temperatures ranging from 0 K up to 226 K, while retaining half-metallicity in the system. In this paper, the structural, magnetic and transport properties of the Mn-Fe-V-Al system are discussed. Magnetic reversal and a change of sign of the anomalous Hall effect were observed at the compensation point, which gives rise to a sublattice spin-crossing. These materials present new possibilities for potential spintronic devices…