Search results for "engineering.material"
showing 10 items of 2352 documents
Orbital mapping of carbon thin films by XANES-spectromicroscopy
2000
Abstract A laterally resolved micro-XANES study (X-ray absorption near edge structure) of amorphous carbon, hydrogen terminated CVD-diamond (100) and highly oriented pyrolytic graphite (HOPG) is presented. The results were obtained by means of a photoemission electron microscope. Using this technique the well-known spectral features of carbon in its different chemical states (sp 2 , sp 3 ) could be recorded. The sp 2 /sp 3 content of the films was extracted from the spectra. Images, taken at X-ray energies corresponding to maxima (π*, C–H*) of the unoccupied density of states in these spectra, map the lateral distribution of the different orbitals at the sample surface. This study revealed …
A Methodology to Deduce the Microstructural Spatial Deformation of Polycrystalline Structures: Application to the Alloy 600
2009
Studying the corrosion of the alloy 600, under water pressure, is of high importance to understand the ageing process of pressurized water reactors. Today, the impact of the oxide growth on the mechanical properties of nickel alloys is a challenge. The surface analysis and the quantification of the local deformation are key factors to deduce the surface damage of the substrate produced by corrosion. Here, we introduce a new methodology to determine the deformation distribution of the alloy 600 by using polycrystalline samples. The method is based on nanopads disposed on the surface samples, which allow a mapping, at the microscopic scale, of the spatial deformation. We applied to the sample…
Trap spectroscopy and tunnelling luminescence in feldspars
1998
Abstract Comparative studies of tunnel luminescence, thermally stimulated luminescence (TSL), and trap energy spectra by the fractional glow technique (FGT) have been made both with sanidine and microcline feldspars. After X-irradiation at LNT these feldspars show intense tunnelling afterglow. As the temperature is raised, several TSL glow peaks may be observed, starting at 135 K. An intense peak at 250 K is common to all four investigated microclines. In samples of sanidine, tunnelling afterglow overcomes TSL up to 250–260 K. With sanidine and microcline samples, the distributions of trap activation energies vs temperature obtained by the FGT are continuous and quasi-linear. Maxima in the …
Controlled release of tyrosol and ferulic acid encapsulated in chitosan–gelatin films after electron beam irradiation
2016
Abstract This work deals with the study of the release kinetics of antioxidants (ferulic acid and tyrosol) incorporated into chitosan–gelatin edible films after irradiation processes. The aim was to determine the influence of electron beam irradiation (at 60 kGy) on the retention of antioxidants in the film, their release in water (pH=7) at 25 °C, in relation with the barrier and mechanical properties of biopolymer films. The film preparation process coupled to the irradiation induced a loss of about 20% of tyrosol but did not affect the ferulic acid content. However, 27% of the ferulic acid remained entrapped in the biopolymer network during the release experiments whereas all tyrosol was …
Activity of laccase on unbleached and bleached thermomechanical pulp
2003
The introduction of value-added properties to pulp fibres is an attractive proposition. One interesting option is targeted modification of fibre surfaces by enzymatic activation. In this work, the activity of laccase on pulp and pulp fractions from thermomechanical pulp (TMP) and peroxide bleached TMP was studied on the basis of consumption of the co-substrate oxygen in the reaction and by studying the formation of radicals in the pulp material as analysed by electron paramagnetic resonance spectroscopy (EPR). Laccases obtained from Trametes hirsuta and Myceliophthora thermophila were used in the study. Laccases were found to be active on pulp material of unbleached TMP, whereas only fines …
Crosslinking of poly(vinylpyrrolidone) activated by electrogenerated hydroxyl radicals: a first step towards a simple and cheap synthetic route of na…
2016
A facile electrosynthesis route for the preparation of polymer nanogels based on the in situ production of hydroxyl radicals is reported for the first time. Electro-Fenton process with continuous H2O2 electrogeneration and Fe2+ regeneration performs better than electro-oxidation with a boron-doped diamond or dimensionally stable anode for promoting crosslinking of poly(vinylpyrrolidone). Keywords: Electrogenerated hydroxyl radicals, BDD, DSA, Electro-Fenton, Polymer modification, Nanogel
Ultrapotassic volcanism from the waning stage of the Neotethyan subduction: a key study from the Izmir-Ankara-Erzincan suture belt, central northern …
2016
Upper Cretaceous volcano-sedimentary successions in the Central Pontides of Turkey, related to the closure of the Tethys Ocean, include a variety of alkaline ultrapotassic igneous rocks that have been classified as leucititic, lamprophyric and trachytic based on their mineral paragenesis. Although the ultrapotassic rocks display a range of K 2 O contents (0·9–8·4 wt %) that may partly reflect alteration processes, they display subduction-related trace element signatures characterized by significant enrichment of large ion lithophile elements and light rare earth elements relative to high field strength elements and heavy rare earth elements and depletion of Nb and Ta. However, their initial…
Petrogenesis of orogenic lamproites of the Bohemian Massif: Sr–Nd–Pb–Li isotope constraints for Variscan enrichment of ultra-depleted mantle domains
2016
Abstract During convergence of Gondwana-derived microplates and Laurussia in the Palaeozoic, subduction of oceanic and continental crusts and their sedimentary cover introduced material of regionally contrasting chemical and isotopic compositions into the mantle. This slab material metasomatised the local mantle, producing a highly heterogeneous lithospheric mantle beneath the European Variscides. The eastern termination of the European Variscides (Moldanubian and Saxo-Thuringian zones of Austria, Czech Republic, Germany and Poland) is unusual in that the mantle was modified by material from several subduction zones within a small area. Orogenic lamproites sampled this lithospheric mantle, …
The nature of radiohaloes in biotite: Experimental studies and modeling
2001
Several micro-techniques (confocal laser-Raman microprobe, optical absorption micro-spectroscopy, high-resolution transmission electron microscopy, electron microprobe analysis) were employed in the detailed characterization of radiohaloes in biotites from two Variscan rocks from Germany. The studied biotites are intermediate members of the phlogopite-annite series with Mg/Fe 2+ ratios in the range 1.6–1.0. Radiohaloes in biotite resulted from the impact of 4 He cores (α-particles) emitted from actinide-bearing inclusions. Monte Carlo simulations yielded α ( 238 U, 235 U, and 232 Th series) penetration ranges in biotite between 12.5 and 37.3 μm, which are in reasonable agreement with the ob…
Cosmic-ray exposure ages of pallasites
2015
We analyzed cosmogenic nuclides in metal and/or silicate (primarily olivine) separated from the main-group pallasites Admire, Ahumada, Albin, Brahin, Brenham, Esquel, Finmarken, Glorieta Mountain, Huckitta, Imilac, Krasnojarsk, Marjalahti, Molong, Seymchan, South Bend, Springwater, and Thiel Mountains and from Eagle Station. The metal separates contained an olivine fraction which although small, <1 wt% in most cases, nonetheless contributes significantly to the budgets of some nuclides (e.g., up to 35% for Ne-21 and Al-26). A correction for olivine is therefore essential and was made using model calculations and/or empirical relations for the production rates of cosmogenic nuclides in iron …