Search results for "engineering.material"
showing 10 items of 2352 documents
Biopolymeric bilayer films produced by co-extrusion film blowing
2018
Abstract Biodegradable packaging promises a more environmentally friendly future. Nevertheless, a single biopolymer often lacks of some important properties. In order to contribute to this challenge, biodegradable bilayer films from poly(lactic acid) (PLA) and MaterBi® were prepared in this work and compared with monolayer films obtained with both the polymers. The prepared films were fully characterized through morphological, mechanical, thermal, chemical, optical and water contact angle analyses. Furthermore, the hydrolytic degradation of monolayer and bilayer films was studied by performing tests at three different pH. The morphological analysis revealed that PLA/MaterBi bilayer films sh…
Zn,Al hydrotalcites calcined at different temperatures: Preparation, characterization and photocatalytic activity in gas–solid regime
2011
Abstract Layered double hydroxides (LDH) containing zinc and aluminium within the brucite-like layers and carbonate as the interlayer anion have been used as precursors for the preparation of mixed metal oxides by calcination. Zinc oxide and the ZnAl 2 O 4 spinel were formed with different degree of crystallinity depending of two parameters, i.e., the Zn 2+ /Al 3+ molar ratio and the calcination temperature (500–800 °C) of the LDH precursor. A pure spinel phase was obtained to remove ZnO upon a basic post-treatment in NaOH solution of the samples calcined at 800 °C. All the samples were tested for the photodegradation of 2-propanol in gas–solid regime. All the samples resulted active as het…
Evolution of mica fish in mylonitic rocks
2003
Abstract Mineral fish are lozenge-shaped porphyroclasts, single crystals in a finer grained matrix, which occur in ductile shear zones and which are commonly used as shear sense indicators. Mineral fish of biotite, tourmaline, K-feldspar, garnet, hypersthene and quartz occur in mylonites but most common are white mica fish. These mica fish can be subdivided into six morphological groups that develop by different mechanisms determined by different initial shapes and orientations. The principal mechanisms of formation are intracrystalline deformation combined with rigid body rotation. Concomitant selective grain size reduction occurs by recrystallisation, cataclastic separation, pressure solu…
Site-specific halloysite functionalization by polydopamine: A new synthetic route for potential near infrared-activated delivery system
2022
Abstract Halloysite nanotubes (HNTs) represent a versatile core structure for the design of functional nanosystems of biomedical interest. However, the development of selective methodologies for the site-controlled functionalization of the nanotubes at specific sites is not an easy task. This study aims to accomplish a procedure for the site-selective/specific, “pin-point”, functionalization of HNTs with polydopamine (HNTs@PDA). This goal was achieved, at pH 6.5, by exploiting the basicity of ZnO nanoparticles anchored on the HNTs external surface (HNTs@ZnO) to induce a punctual polydopamine polymerization and coating. The morphology and the chemical composition of the nanomaterial was demo…
Correlation between optical properties and barrier composition in InxGa1−xP/GaAs quantum wells
1998
9 páginas, 11 figuras.
Vibrational Properties of CuO and Cu4O3 from First-Principles Calculations, and Raman and Infrared Spectroscopy
2012
International audience; A combined experimental and theoretical study is reported on the vibrational properties of tenorite CuO and paramelaconite Cu4O3. The optically active modes have been measured by Raman scattering and infrared absorption spectroscopy. First-principles calculations have been carried out with the LDA+U approach to account for strong electron correlation in the copper oxides. The vibrational properties have been computed ab initio using the so-called direct method. Excellent agreement is found between the measured Raman and infrared peak positions and the calculated phonon frequencies at the Brillouin zone center, which allows the assignment of all prominent peaks of the…
U–Pb SIMS dating of synkinematic granites: timing of core-complex formation in the northern Anatolide belt of western Turkey
2005
Secondary ion mass spectrometry (SIMS) U–Th–Pb dating of magmatic zircon from the synkinematic Egrigoz and Koyunoba granites and a leucogranite dyke dates core-complex formation in the northern Anatolide belt of western Turkey at 24–19 Ma. The granites intrude into the footwall of the Simav detachment and are strongly elongated in the NNE direction parallel to tectonic transport on the detachment. Although large parts of the granites are undeformed, localized mylonitic to ultramylonitic deformation occurs directly beneath the Simav detachment and preserves evidence of progressive deformation from ductile to brittle conditions. Oscillatory zoned rims of long-prismatic zircon from the Egrigoz…
Intrusion mechanisms in a turbidite sequence; the Voetspoor and Doros plutons in NW Namibia
2007
Abstract Two syntectonic plutons of Cambrian age intruded Neoproterozoic metaturbidites in Namibia at the junction of the NS trending Kaoko and EW trending Damara belts. Sinistral transpression in the Kaoko Belt produced km-scale upright D1 folds overprinted by minor D2 folds. D3 is associated with N–S shortening in the Damara Belt. The plutons show two main pulses of intrusion: hornblende syenite intruded late during D1 or during D2 and biotite granite during D3. Each tectonic event produced a strain shadow defined by the shape of folds and the foliation trend around the plutons. The internal igneous fabric and the arrangement of wall rock xenoliths that locally make up 50% of the intrusio…
Revalorization of cellulosic wastes from Posidonia oceanica and Arundo donax as catalytic materials based on affinity immobilization of an engineered…
2020
Catalytic materials obtained by enzyme immobilization have multiple potential applications in the food industry. The choice of the immobilization method and support may be critical to define the properties of the immobilized enzyme compared to the soluble form. Although the use of immobilized enzymes shows multiple advantages, their catalytic efficiency is compromised in many instances. Molecular engineering techniques have been used to generate hybrid proteins where the enzyme of interest is fused to a module with affinity to a specific biopolymer. Binding of the hybrid TmLac-CBM2 protein, in which the β-galactosidase from Thermotoga maritima is fused to a carbohydrate-binding module from …
Tissue response and biomaterial integration: the efficacy of in vitro methods
2002
Implantation involves tissue trauma, which evokes an inflammatory response, coupled to a wound healing reaction, involving angiogenesis, fibroblast activation and matrix remodelling. Until now the type and extent of such reactions to give optimal integration of various biomaterials are practically unknown. Three principal fields of research can yield useful data to understand these phenomena better: studies on explanted biomaterials, animal models and relevant in vitro techniques. This paper will present examples of the latter field and the application of endothelial cell (EC) culture systems to study the effects of important tissue (e.g. pro-inflammatory cytokines, chemokines) and material…