Search results for "exciton"
showing 10 items of 317 documents
Unconditional generation of bright coherent non-Gaussian light from exciton-polariton condensates
2012
Exciton-polariton condensates are considered as a deterministic source of bright, coherent non-Gaussian light. Exciton-polariton condensates emit coherent light via the photoluminescence through the microcavity mirrors due to the spontaneous formation of coherence. Unlike conventional lasers which emit coherent Gaussian light, polaritons possess a natural nonlinearity due to the interaction of the excitonic component. This produces light with a negative component to the Wigner function at steady-state operation when the phase is stabilized via a suitable method such as injection locking. In contrast to many other proposals for sources of non-Gaussian light, in our case, the light typically …
Two-Color Single-Photon Emission from In As Quantum Dots: Toward Logic Information Management Using Quantum Light
2014
In this work, we propose the use of the Hanbury-Brown and Twiss interferometric technique and a switchable two-color excitation method for evaluating the exciton and noncorrelated electron-hole dynamics associated with single photon emission from indium arsenide (InAs) self-assembled quantum dots (QDs). Using a microstate master equation model we demonstrate that our single QDs are described by nonlinear exciton dynamics. The simultaneous detection of two-color, single photon emission from InAs QDs using these nonlinear dynamics was used to design a NOT AND logic transference function. This computational functionality combines the advantages of working with light/photons input/output device…
Size-And Wavelength-Dependent Two-Photon Absorption Cross-Section of CsPbBr3 Perovskite Quantum Dots
2017
All-inorganic colloidal perovskite quantum dots (QDs) based on cesium, lead, and halide have recently emerged as promising light emitting materials. CsPbBr3 QDs have also been demonstrated as stable two-photon-pumped lasing medium. However, the reported two photon absorption (TPA) cross sections for these QDs differ by an order of magnitude. Here we present an in-depth study of the TPA properties of CsPbBr3 QDs with mean size ranging from 4.6 to 11.4 nm. By using femtosecond transient absorption (TA) spectroscopy we found that TPA cross section is proportional to the linear one photon absorption. The TPA cross section follows a power law dependence on QDs size with exponent 3.3 +- 0.2. The …
Comments on the through space singlet energy transfers and energy migration (exciton) in the light harvesting systems
2008
Recent findings on the photophysical investigations of several cofacial bisporphyrin dyads for through space singlet and triplet energy transfers raised several serious questions about the mechanism of the energy transfers and energy migration in the light harvesting devices, notably LH II, in the heavily studied purple photosynthetic bacteria. The key issue is that for simple cofacial or slipped dyads with controlled geometry using rigid spacers or spacers with limited flexibilities, the fastest possible rates for singlet energy transfer for three examples are in the 10 x 10(9)s(-1) (i.e. just in the 100 ps time scale) for donor-acceptor distances approaching 3.5-3.6 A. The reported time s…
Excitonic absorption and Urbach's tail in bismuth sulfide single crystals
1988
The absorption coefficient of bismuth sulfide single crystals has been measured through more than four orders of magnitude and in the range of energies from 1.25 to 1.70 eV. A detailed study as a function of temperature has been carried out from 29 to 300 K. An Urbach tail for low values of absorption has been found. This tail and its temperature evolution fit the expression for ionic materials. An excitonic region appears at low temperature and the shape of the exciton peak is Gaussian, which corresponds to a strong exciton-phonon coupling. The exciton binding energy is estimated (28±3 meV) and then the energy gap at 29 K is obtained (Eg=1.523±0.003 eV). The fundamental electronic transiti…
Resonant hyper-Raman scattering in spherical quantum dots
1998
A theoretical model of resonant hyper-Raman scattering by an ensemble of spherical semiconductor quantum dots has been developed. The electronic intermediate states are described as Wannier-Mott excitons in the framework of the envelope function approximation. The optical polar vibrational modes of the nanocrystallites (vibrons) and their interaction with the electronic system are analized with the help of a continuum model satisfying both the mechanical and electrostatic matching conditions at the interface. An explicit expression for the hyper-Raman scattering efficiency is derived, which is valid for incident two-photon energy close to the exciton resonances. The dipole selection rules f…
Pressure dependence of the exciton absorption and the electronic subband structure of aGa0.47In0.53As/Al0.48In0.52As multiple-quantum-well system
1992
We have measured the optical absorption of a ${\mathrm{Ga}}_{0.47}$${\mathrm{In}}_{0.53}$As/${\mathrm{Al}}_{0.48}$${\mathrm{In}}_{0.52}$As multiple quantum well at 10 K for pressures up to 7 GPa. The energies of optical transitions between heavy- and light-hole subbands and electron levels of the wells show a blueshift with pressure similar to the bulk lowest direct band gap. We observe a decrease with pressure of the energy splitting between heavy- and light-hole subbands with the same quantum number n. From the analysis of the absorption line shape, we have obtained the pressure dependences of exciton binding energies, oscillator strengths, and linewidths. These results are interpreted in…
Ultrafast non-linear optical signal from a single quantum dot: exciton and biexciton effects
2002
We present results on both the intensity and phase-dynamics of the transient non-linear optical response of a single quantum dot (SQD). The time evolution of the Four Wave Mixing (FWM) signal on a subpicosecond time scale is dominated by biexciton effects. In particular, for the cross-polarized excitation case a biexciton bound state is found. In this latter case, mean-field results are shown to give a poor description of the non-linear optical signal at small times. By properly treating exciton-exciton effects in a SQD, coherent oscillations in the FWM signal are clearly demonstrated. These oscillations, with a period corresponding to the inverse of the biexciton binding energy, are correl…
Theory of radiative recombination from the metastable excited states of quantum dots
1998
The radiative recombination of an exciton ~electron-hole pair! confined in a semiconductor quantum dot is studied within a general model based on the effective-mass approximation. The dependence of the photoluminescence spectrum on the size of the dot and the magnetic field describe well a series of recent experimental results. In particular, a characteristic splitting of the main photoluminescence peak into a doublet or triplet is observed at the critical size and magnetic field, as a consequence of the appearance of metastable states in the exciton spectrum. @S0163-1829~98!06915-X#
Polaronic-type excitons in ferroelectric oxides: Microscopic calculations and experimental manifestation
2002
We discuss the current experimental and theoretical understanding of new polaronic-type excitons in ferroelectric-oxides charge-transfer vibronic excitons ~CTVE’s!, which are pairs of strongly correlated electronic and hole polarons. It is shown that charge-transfer‐lattice distortion interactions are the driving forces for CTVE formation. Hartree-Fock-type calculations performed in the framework of the intermediate neglect of differential overlap ~INDO! method as well as photoluminescence, second-harmonic generation, and UVabsorption high-temperature studies performed for ABO3 ferroelectric oxides strongly support the CTVE existence. Both single CTVE and a phase of strongly correlated CTVE…