Search results for "ferroelectric"
showing 10 items of 374 documents
Probing Nanoscale Ferroelectricity by Ultraviolet Raman Spectroscopy
2006
We demonstrated that ultraviolet Raman spectroscopy is an effective technique to measure the transition temperature ( T c ) in ferroelectric ultrathin films and superlattices. We showed that one-unit-cell-thick BaTiO 3 layers in BaTiO 3 /SrTiO 3 superlattices are not only ferroelectric (with T c as high as 250 kelvin) but also polarize the quantum paraelectric SrTiO 3 layers adjacent to them. T c was tuned by ∼500 kelvin by varying the thicknesses of the BaTiO 3 and SrTiO 3 layers, revealing the essential roles of electrical and mechanical boundary conditions for nanoscale ferroelectricity.
Neutron powder diffraction study in the mixed molecular system (NaCN)1−x(KCN)x
1989
A detailed structural analysis of (NaCN${)}_{1\mathrm{\ensuremath{-}}\mathrm{x}}$(KCN${)}_{\mathrm{x}}$ mixed crystals with x=0.02, 0.19, and 0.95 was performed by neutron powder diffraction. The structural parameters of the cubic phases were refined, applying a model of preferred orientations. Different noncubic low-temperature phases were observed for x=0.02 and 0.95. For x=0.02 the antiferroelectric ordering of ${\mathrm{CN}}^{\mathrm{\ensuremath{-}}}$ dipoles at low temperatures is accompanied by significant alkali-alkali and alkali-${\mathrm{CN}}^{\mathrm{\ensuremath{-}}}$ sublattice shifts. Structural data are presented together with previous results for mixed crystals with x=0.59 and…
Strain-induced improvement of retention loss in PbZr0.2Ti0.8O3 films
2015
The retention behavior of nanoscale domains in PbZr0.2Ti0.8O3 thin films is investigated by in-situ controlling the epitaxial strain arising from a piezoelectric substrate. The retention behavior in our sample shows strong polarity-dependence: Upward-poled domains exhibit excellent stability, whereas downward-poled domains reveal a stretched exponential decay. Reversible release of in-plane compressive strain strongly reduced the retention loss, reflected in an enhancement of the relaxation time by up to one order of magnitude. We tentatively attribute the observed behavior to a strain dependence of the built-in field at the interface to the La0.7Sr0.3MnO3 bottom electrode, with a possible …
Nanopatterned ferroelectric crystals for parametric generation
2006
We report on recent results by surface periodic poling on lithium niobate and lithium tantalate. Such approach allows periodic inversion of the second order susceptibility with nanoscale features using insulating masks. We achieved a world-best 200 nm feature size, as well as good compatibility with alpha-phase proton exchanged channel waveguides in lithium niobate. Preliminary results of surface periodic poling in lithium tantalate also show similar characteristics. Surface poling is best suited for integrated optics devices in technologically-demanding configurations such as backward second harmonic generation and counter propagating optical parametric amplification
Guided-wave frequency doubling in surface periodically poled lithium niobate: competing effects
2007
We carried out second-harmonic generation in quasi-phase-matched ? -phase lithium niobate channel waveguides realized by proton exchange and surface periodic poling. Owing to a limited ferroelectric domain depth, we could observe the interplay between second-harmonic generation and self-phase modulation due to cascading and cubic effects, resulting in a nonlinear resonance shift. Data reduction allowed us to evaluate both the quadratic nonlinearity in the near infrared as well as the depth of the uninverted domains. © 2007 Optical
Single-Event Effects in the Peripheral Circuitry of a Commercial Ferroelectric Random Access Memory
2018
International audience; This paper identifies the failure modes of a commercial 130-nm ferroelectric random access memory. The devices were irradiated with heavy-ion and pulsed focused X-ray beams. Various failure modes are observed, which generate characteristic error patterns, affecting isolated bits, words, groups of pages, and sometimes entire regions of the memory array. The underlying mechanisms are discussed.
Radiation-induced point defects in simple oxides
1998
We present a survey of recent theoretical studies of radiation-induced point defects in simple oxides with emphasis on highly ionic MgO, partly-covalent corundum (Al2O3) and ferroelectric KNbO3. The atomic and electronic structure of the electronic (F a and F centers) and hole centers, as well as interstitial atoms therein are discussed in light of the available experimental data. Results for defect diAusion and photo-stimulated F a fi F center conversion are also ana
Dielectric properties of barium strontium titanate / non ferroelectric oxide ceramic composites
2001
International audience; Barium strontium titanate ceramics present high dielectric permittivity and tunability. In order to reduce their permettivity and loss tangent while keeping tunability, various composites of barium strontium titanate oxide...
Non-linear dielectric behaviour and glass phase in Sr1-xCaxTiO3(x= 0.002 andx= 0.003)
1999
This work reports a study of the temperature and electric field dependence of the dielectric constant of strontium calcium titanate. The first part of the paper is focused on the analysis of a mean-field model for the polar clusters generated by the random impurities of calcium. It is shown that the dipolar moments within each cluster can be represented by an equivalent quantum two-level system. General expressions for the temperature and field dependence of the Edward-Anderson order parameter and of the electrical polarization are given. Analytical solutions are also obtained in the limit of high temperatures and in the limit of high tunnelling frequencies. The second part of the work repo…
Structure and properties of epitaxial ferroelectric PbLu0.5Nb0.5O3thin films
2001
Abstract Epitaxial thin film heterostructures of PbLu0.5Nb0.5O3 (PLuN) and La0.5Sr0.5CoO3 (LSCO) were deposited by in situ pulsed laser ablation onto MgO and LaAlO3 (100) substrates. The formation of crystalline phases, epitaxy, film-electrode-substrate orientation relationships, crystal perfection and chemical order were studied by x-ray diffraction. The structural properties were found to depend on the deposition conditions and on the substrate. The perovskite PLuN films were pseudocubic and epitaxial, with (001) planes parallel to the substrate surface. At room temperature, Au/PLuN/LSCO capacitors exhibited ferroelectric behavior and zero-field dielectric permittivity about e ≅ 210–260, …