Search results for "flame"
showing 10 items of 108 documents
Improving detection limits for organotin compounds in several matrix water samples by derivatization-headspace-solid-phase microextraction and GC-MS.
2010
Triethyltin, tributyltin, diphenyltin and triphenyltin were selected as model compounds. The method is based on in situ ethylation and simultaneous headspace-solid-phase microextraction (HS-SPME) and gas chromatographic-mass spectrometry analysis (GC-MS). The extraction procedure was optimized studying some variables such as reaction time, salinity, sample volume and headspace volume. SPME-GC-MS and SPME-GC-FID techniques were compared; quality assurance parameters such as sensitivity, selectivity and precision were established. The proposed procedure showed limits of detection between 0.025 and 1 ng/L. The linearity was in the 0.025-5000 ng/L range. The precision expressed as relative stan…
Flamenco flamingos and pelicans. From purist flamenco to quinqui fusion. Duende y misterio del flamenco (Edgar Neville, 1952) y Dame veneno (Pedro Ba…
2012
El cine musical español se ha servido en numerosas ocasiones de los elementos característicos de la españolada, como es el caso del flamenco. Sin embargo, muy pocas películas se han detenido a analizarlo en profundidad. Contraviniendo esa tendencia, ‘Duende y misterio del flamenco’ (Edgar Neville) y ‘Dame veneno’ (Pedro Barbadillo) se nos muestran como dos rarezas capaces de reflexionar en profundidad sobre ese género musical y su evolución a partir de los años setenta. Evocadores de dos momentos bien diferenciados de la sociedad española, la comparación entre ambos filmes evidencia la evolución de la pureza del género a su fusión con otras músicas, reflejando de paso la apertura a la cultu…
Flamencos y pelícanos. Del flamenco purista a la fusión quinqui. Duende y misterio del flamenco (Edgar Neville, 1952) y Dame veneno (Pedro Barbadillo…
2012
El cine musical español se ha servido en numerosas ocasiones de los elementos característicos de la españolada, como es el caso del flamenco. Sin embargo, muy pocas películas se han detenido a analizarlo en profundidad. Contraviniendo esa tendencia, ‘Duende y misterio del flamenco’ (Edgar Neville) y ‘Dame veneno’ (Pedro Barbadillo) se nos muestran como dos rarezas capaces de reflexionar en profundidad sobre ese género musical y su evolución a partir de los años setenta. Evocadores de dos momentos bien diferenciados de la sociedad española, la comparación entre ambos filmes evidencia la evolución de la pureza del género a su fusión con otras músicas, reflejando de paso la apertura a la cultu…
The occurrence of Dechlorane Plus and related norbornene-based flame retardants in Baltic wild salmon (Salmo salar)
2015
Twenty five Baltic wild salmon (Salmo salar) specimens were analysed for the content of Dechlorane-related compounds (DRCs). Out of the ten analysed DRCs, seven compounds were detected in the muscle tissues of salmon, including Dechlorane (Dec) 602, Dec 603, syn- and anti-stereoisomers of Dechlorane Plus (DP), Dechlorane Plus monoadduct (1,3-DPMA), hexachlorocyclopentadienyl-dibromocyclooctane (DBHCTD), and Mirex. The concentrations of Dec 604 and two DP dechlorinated compounds - decachloropentacyclooctadecadiene (Cl10DP) and undecachloropentacyclooctadecadiene (Cl11DP) - were below the limit of detection in all samples. The aggregated concentrations of DRCs (ΣDRC) were in the range of 551-…
Recent Development in Analytical Methods for Identification of Off-Flavour Compounds
1983
The best resolution of individual off-flavour compounds is achieved by glass or quartz capillary gas chromatography. A special two-column system was used by which simultaneous instrumental detection and sniffing (odour desorption) of odorous compounds could be done. The measuring detectors were flame ionization (FID), electron capture (ECD), flame photometric (FPD) and a mass spectrometer (MS). Structural assignments of the odorous substances were done from MS data and verified by model compounds. Before the GC run the sample was collected at the head of the double column using a cold trap device. The sample for analysis was injected in liquid form or, more efficiently, thermally desorbed f…
Development and optimization of gas chromatography coupled to high resolution mass spectrometry based method for the sensitive determination of Dechl…
2017
An analytical method has been developed for the trace determination of 10 dechlorane-related compounds (DRCs) in food products by gas chromatography - high resolution mass spectrometry (GC-HRMS). The highest sensitivity of this instrumental analysis method was achieved by selection of the GC column type, optimization of the heated zones within the instrument, and adjusting the electron impact energy. The efficiency of solid phase extraction as clean-up procedure was also optimized. Two different types of cartridges - neutral silica gel and Florisil®, as well as seven organic solvents or their mixtures - n-hexane, cyclohexane, acetone, toluene, n-hexane/ethyl acetate, n-hexane/acetone, and n…
OVERVIEW OF ANALYTICAL PROCEDURES FOR FATTY AND RESIN ACIDS IN THE PAPERMAKING PROCESS
2012
This review describes the role of wood extractives, especially fatty and resin acids, in papermaking, as well as the importance of their removal from process waters. One of the main aims is also to illustrate versatile analysis methods for this purpose and highlight recent developments in corresponding applications. Most of the current methods require time-consuming and laborious sample pretreatment procedures prior to gas chromatography coupled either with flame ionization or mass selective detection. However, some faster, even online techniques with minimum sample pretreatment, are also available, mainly including high performance liquid chromatography coupled with mass spectrometry. The …
A chromatochemometric approach for evaluating and selecting the perfume maceration time.
2010
Abstract A chemometric treatment of the data obtained by gas chromatography (GC) with flame ionization detector (FID) has been proposed to study the maceration time involved in perfumes manufacture with the final purpose of reducing this time but preserving the organoleptic characteristics of the perfume that is being elaborated. In this sense, GC–FID chromatograms were used as a fingerprint of perfume samples subjected to different maceration times, and data were treated by linear discriminant analysis (LDA), by comparing to a set of samples known to be macerated or not, which were used as calibration objects. The GC–FID methodology combined with the treatment of data by LDA has been appli…
Flamed pyrolysis titanium oxide as functional coating for Al substrate
2009
El monogramista F.D.V. ¿Frans de Vriendt? A propósito de una Susana y los viejos firmada y fechada en 1543
2017
En este artículo analizamos una pintura flamenca inédita, que representa la escena de Susana y los viejos. Se conserva en una colección particular de Cartagena (Murcia). Está fechada en 1543 y firmada por F.D.V., monograma que plantea la principal incógnita de nuestra investigación. Tales siglas hacen pensar de inmediato en el pintor Frans Floris de Vriendt. En este sentido, los rasgos estilísticos de la obra están próximos al espíritu de este maestro. Sin embargo, diversas cuestiones nos impiden confirmar por el momento tal autoría. En el texto desarrollamos estas hipótesis y definimos la personalidad artística del que denominamos Monogramista F.D.V. In this paper, we analyze an unpublishe…