Search results for "force"
showing 10 items of 3423 documents
Molecular equilibrium structures from experimental rotational constants and calculated vibration–rotation interaction constants
2002
A detailed study is carried out of the accuracy of molecular equilibrium geometries obtained from least-squares fits involving experimental rotational constants B(0) and sums of ab initio vibration-rotation interaction constants alpha(r)(B). The vibration-rotation interaction constants have been calculated for 18 single-configuration dominated molecules containing hydrogen and first-row atoms at various standard levels of ab initio theory. Comparisons with the experimental data and tests for the internal consistency of the calculations show that the equilibrium structures generated using Hartree-Fock vibration-rotation interaction constants have an accuracy similar to that obtained by a dir…
Drilling characteristics and properties analysis of fiber reinforced polymer composites: A comprehensive review
2023
Fiber-reinforced polymer (FRP) composites play a vital role in the production of structural and semi-structural components for engineering applications. The drilling process is a commonly employed machining process for FRP composites to join the FRP structural elements. Usually, the FRP composites possess a heterogeneous nature because of their multi-layered structure, hybridization, and the presence of multi-phase materials. Hence, common problems like delaminations, fuzzing, buckling, cracking, matrix and fiber burning occur during the drilling operations. These problems cause dimensional inaccuracy, poor surface finish, and tool wear and reduce the mechanical strength of the composites. …
Effect of FRP strengthening on the flexural behaviour of calcarenite masonry walls
2017
The use of fiber-reinforced polymers (FRP) for structural strengthening has become increasingly popular in recent years. Several applications of FRP have been proposed and applied, depending on the target of the technique, kind and/or material of the structural member. In particular, because of their great tensile strength, FRP materials are commonly used to enhance the out-of-plane behaviour of masonry walls, allowing to increase their strength, ductility and improving safety against overturning. For these reasons, FRP laminates are often applied in vulnerable ancient buildings in seismic areas to reinforce façades and walls with poor structural features. However, some issues arise when a…
Weighting non-covalent forces in the molecular recognition of C60. Relevance of concave–convex complementarity
2008
The relative contributions of several weak intermolecular forces to the overall stability of the complexes formed between structurally related receptors and [60]fullerene are compared, revealing a discernible contribution from concave–convex complementarity. Viruela Martin, Pedro Manuel, Pedro.M.Viruela@uv.es ; Viruela Martin, Rafael, Rafael.Viruela@uv.es ; Orti Guillen, Enrique, Enrique.Orti@uv.es
R.C. columns strengthened by PBO-FRCM under axial force and bending moment
2017
Fabric-Reinforced Cementitious Matrix (FRCM) systems, also known as Textile Reinforced Concrete (TRC) are nowadays widely used as confining material to enhance both strength and deformation capacity of columns of seismic resistant r.c. frames. In the past, when carbon fiber was used in the textile, experimental results showed that the efficiency of the wrapping is limited by the connection between substrate and fiber, which is not as effective as when epoxy resins are used. To improve the strength of the connection between fibres and mortar binder in FRCM system, the use of p-Phenylene BenzobisOxazole (PBO), having a molecular structure capable of establishing chemical bonds with hydrated c…
Evaluation of interlaminar delaminations in titanium-graphite fibre metal laminates by infrared NDT techniques
2018
Abstract Fibre Metal Laminates (FMLs) describe a number of aerospace-grade layered structural materials where thin metal alloy foils are interleaved with Fibre Reinforced Polymer (FRP) plies. Such material hybridisation at the layer meso-scale poses a challenge for non-destructive testing (NDT). On the other hand, the need for NDT inspection of FMLs arises due to the potential development of interlayers disbonds, both during fabrication or in-service. This work describes the successful implementation of two Infrared-NDT approaches to evaluate a defected FML panel made of Titanium/Graphite (Ti-Gr). One technique is based on the modulation of the deployed heat from a low-cost halogen lamp, to…
Nanofabrication of TaS2 conducting layers nanopatterned with Ta2O5 insulating regions via AFM
2013
It is demonstrated how local oxidation nanolithography performed with an atomic force microscope (AFM-LON) may be successfully employed for the nanopatterning of insulating regions of Ta2O5 on TaS2 ultrathin metallic layers. This provides a simple approach for the fabrication of electronic devices, such as single-electron transistors, at the nanoscale.
Nanomanufacturing/Nanotechnology
2008
This chapter provides comprehensive knowledge regarding the fabrication of nanoproducts and element of micro-electromechanical systems using various techniques and processes. Both well-established techniques, such as nanomachining (ultra-precision) and new trends in improving nanoprocesses taking into account AFM, laser beam machining, electron beam machining processes are overviewed. The background of nanomachining processes, including typical machining operations such as turning, milling and grinding and different construction materials (metallic and nonmetallic), is outlined. The physical mechanisms responsible for the transition from brittle to ductile regime machining are explained. Mo…
Chemical Design and Magnetic Ordering in Thin Layers of 2D Metal–Organic Frameworks (MOFs)
2021
Through rational chemical design, and thanks to the hybrid nature of metal−organic frameworks (MOFs), it is possible to prepare molecule-based 2D magnetic materials stable at ambient conditions. Here, we illustrate the versatility of this approach by changing both the metallic nodes and the ligands in a family of layered MOFs that allows the tuning of their magnetic properties. Specifically, the reaction of benzimidazole-type ligands with different metal centers (MII = Fe, Co, Mn, Zn) in a solventfree synthesis produces a family of crystalline materials, denoted as MUV-1(M), which order antiferromagnetically with critical temperatures that depend on M. Furthermore, the incorporation o…
The evolution of market power in European banking
2017
This paper analyses the effect that European financial market integration has had on the evolution of the banks' market power disparities. The results show that market power disparity has narrowed among eurozone banks. The reduction is attributable to the convergence in the average levels of market power of the European banking sectors. In contrast, the disparities observed within each country have remained stable. As a result, the measures adopted to advance towards a single banking market should be complemented by measures at the national level designed to intensify competition among the banks within a given country.