Search results for "force"
showing 10 items of 3423 documents
Double D–π–A branched dyes – a new class of metal-free organic dyes for efficient dye-sensitized solar cells
2017
Double branched donor acceptor compounds (D–π–A)2L, whose separate branches are linked by saturated chains or ring systems, are highly promising sensitizers for dye-sensitized solar cells (DSSCs). Their photovoltaic performance η (power conversion efficiency PCE) is higher than the η value of the corresponding single branched sensitizers D–π–A. This advantage can be attributed to the lower aggregation tendency and to the higher loading density of the chromophores on the semi-conductor surface (TiO2). Moreover, the intramolecular transfer of the excitation energy can enhance the contact time of the adsorbed dye molecules in the excited state S1 and thus reduce the unwanted charge recombinati…
Synthesis, properties and charge transfer complexes of covalently attached [60]fullerene-tetrathiafulvalenes
1997
Abstract The synthesis of several fulleropyrrolidines bearing differently substitued tetrathiafulvalenes is reported. The synthetic approach used allows the introduction of ethylene spacers between the TTF and the C 60 core. Charge transfer complexes obtained from these [60]fullerene-TTF systems by reaction with tetrafluoro-tetracyano-p-quinodimethane (TCNQF 4 ) show a semiconducting behaviour; theoretical calculations predict an intramolecular CT band from the TTF moiety to the C 60 core.
Local Reinforcement Effect of a Strain Gauge Installation on Low Modulus Materials
2005
The reinforcement effect of electrical resistance strain gauges is well documented in the technical literature. In this paper the local reinforcement effect in tension is studied by using a simple theoretical model by considering a strain gauge mounted on a semi-infinite plate having the same width of the strain gauge and subjected to a uniaxial tension load. Neglecting the effect of the adhesive layer and considering the interface shear stress as an exponential distribution, the proposed model gives a closed-form solution. In detail, this model permits a simple formula to be obtained which allows the user to correct the local reinforcement effect provided that a proper calibration is perfo…
Focus on the Essential: Extracting the Decisive Energy Barrier of a Complex Process
2019
Molecular processes at surfaces can be composed of a rather complex sequence of steps. The kinetics of even seemingly simple steps are demonstrated to depend on a multitude of factors, which prohibits applying a simple Arrhenius law. This complexity can make it challenging to experimentally determine the kinetic parameters of a single step. However, a molecular-level understanding of molecular processes such as structural transitions requires elucidating the atomistic details of the individual steps. Here, a strategy is presented to extract the energy barrier of a decisive step in a very complex structural transition by systematically addressing all factors that impact the transition kineti…
Cross-stream migration of a Brownian droplet in a polymer solution under Poiseuille flow
2018
The migration of a Brownian fluid droplet in a parallel-plate microchannel was investigated using dissipative particle dynamics computer simulations. In a Newtonian solvent, the droplet migrated toward the channel walls due to inertial effects at the studied flow conditions, in agreement with theoretical predictions and recent simulations. However, the droplet focused onto the channel centerline when polymer chains were added to the solvent. Focusing was typically enhanced for longer polymers and higher polymer concentrations with a nontrivial flow-rate dependence due to droplet and polymer deformability. Brownian motion caused the droplet position to fluctuate with a distribution that prim…
Optimal ferromagnetically-coated carbon nanotube tips for ultra-high resolution magnetic force microscopy
2013
Using single-walled carbon nanotubes homogeneously coated with ferromagnetic metal as ultra-high resolution magnetic force microscopy probes, we investigate the key image formation parameters and their dependence on coating thickness. The crucial step of introducing molecular beam epitaxy for deposition of the magnetic coating allows highly controlled fabrication of tips with small magnetic volume, while retaining high magnetic anisotropy and prolonged lifetime characteristics. Calculating the interaction between the tips and a magnetic sample, including hitherto neglected thermal noise effects, we show that optimal imaging is achieved for a finite, intermediate-thickness magnetic coating, …
Simultaneous measurement of temperature and strain in glass fiber/epoxy composites by embedded fiber optic sensors: I. Cure monitoring
2007
In this paper (Part I) the use of fiber optic sensors for real-time monitoring of the cure kinetics of GFRP composites is explored. The proposed sensing system allows the simultaneous measurement of both temperature and strain by monitoring the change in reflected wavelength from two coupled fiber Bragg grating (FBG) sensors that have been embedded into the composite laminate. Instrumented GFRP laminates with 12, 18 and 24 reinforcing plies, respectively, were prepared by means of the vacuum bagging technique. Samples were cured in a thermally controlled oven at 80 degrees C and 30 kPa for 240 min (isothermal stage) and then cooled down to ambient temperature by turning off the heating sour…
Electronic structure, lattice dynamics, and optical properties of a novel van der Waals semiconductor heterostructure: InGaSe2
2017
There is a growing interest in the property dependence of transition metal dichalcogenides as a function of the number of layers and formation of heterostructures. Depending on the stacking, doping, edge effects, and interlayer distance, the properties can be modified, which opens the door to novel applications that require a detailed understanding of the atomic mechanisms responsible for those changes. In this work, we analyze the electronic properties and lattice dynamics of a heterostructure constructed by simultaneously stacking InSe layers and GaSe layers bounded by van der Waals forces. We have assumed the same space group of GaSe, $P\overline{6}m2$ as it becomes the lower energy conf…
The Joining of LiNbO3, Quartz, TlBr-TlI and Other Optical Materials by the Use of Thin Metal Films as Bonding Agents
2000
A method of joining ferroelectric, optical and other non-metallic materials, such as lithium niobate, quartz, TlBr-TlI, glass, etc., at room temperature under a pressure of 0.1÷0.5 MPa is described. The surfaces to be joined are prepared to optical flatness, and indium or lead coatings as bonding agents are used. To obtain clean surfaces, procedures of the coating deposition and sample joining are performed in situ in a vacuum of l0-4 Pa. The strength of the obtained joints is about 20MPa for indium coatings and about 30MPa for lead coatings. It is supposed that attractive surface forces play a decisive role in the contact formation and bonding of the wafers. The method has been applied for…
Air lift relevance in a side-stream MBR system
2006
Nowadays, two main MBR configurations are developed in wastewater treatment (Fig. 1a and b). The former is based on a side stream membrane module position, it is generally developed for the industrial wastewater treatment because of its compactness even if it requires more energy due to the necessity of using high suspension flow rate recycles throughout the membrane module to minimise fouling rates [1]. With this configuration the membrane maintenance is easy because of the side stream position of the membrane module relatively to the bioreactor. The second configuration is based on the immersion of membrane module directly inside the bioreactor. This configuration is more extensive becaus…