Search results for "force"
showing 10 items of 3423 documents
Molecular dynamics of CH4/N2 mixtures on a flexible graphene layer: adsorption and selectivity case study
2019
We theoretically investigate graphene layers, proposing them as membranes of subnanometer size suitable for CH4/N2 separation and gas uptake. The observed potential energy surfaces, representing the intermolecular interactions within the CH4/N2 gaseous mixtures and between these and the graphene layers, have been formulated by adopting the so-called Improved Lennard-Jones (ILJ) potential, which is far more accurate than the traditional Lennard-Jones potential. Previously derived ILJ force fields are used to perform extensive molecular dynamics simulations on graphene's ability to separate and adsorb the CH4/N2 mixture. Furthermore, the intramolecular interactions within graphene were explic…
Numerical and Experimental Assessment of FRP-Concrete Bond System
2021
Fiber reinforced polymer (FRP) composite systems are widely used to repair structurally deficient constructions thanks to their good corrosion resistance, light weight and high strength. The quality of the FRP-substrate interface bond is a crucial parameter affecting the performance of retrofitted structures. In this study, ultrasonic testing have been used to assess the quality of the bonding. In the case of FRP laminates adhesively bonded to concrete, high scattering attenuation occurs due to the presence of concrete heterogeneities. The substrate material behaves almost like a perfect absorber generating a considerable number of short-spaced echo peaks that make the defect echo not disti…
The influence of steel fibres on compressive and tensile strength of ultra high performance concrete : A review
2020
Abstract This review paper presents the effects of steel fibre reinforcement regarding the compressive and tensile strength of UHPC. The intention is to give an overview of the research field and supply guidance for future research. Relevant papers were identified through a systematic literature search. An accumulation of the results shows that fibres have potential for improving the tensile strength of UHPC. The effect depends on fibre content, type and hybrid combinations. The effect of fibres on compressive strength seems to be questionable. Variations in test specimen geometry and other factors might also influence the results.
Influence of the chemical dissolution of MnS inclusions on the composition of passive films and the local electrochemical behaviour of stainless stee…
2006
Abstract Immersion of stainless steel containing MnS inclusions in aqueous electrolytes leads to the chemical dissolution of these heterogeneities. Chemical dissolution of MnS inclusions in 1M NaCl, pH=3 was studied using in-situ AFM and the dissolution rate of MnS was estimated between 0.04 and 0.19 μm 3 /min. The local electrochemical measurements reveal that the chemical dissolution of MnS inclusions promotes pitting corrosion. Similary, chemical dissolution of MnS inclusions in IM NaClO 4 , pH=3 solution modified the surface close to the inclusions by the presence of FeSO 4 in the passive film.
On the determination of the intramolecular potential energy surface of polyatomic molecules: Hydrogen sulfide and formaldehyde as an illustration
2009
International audience; We present here an approach for determining the Hamiltonian of polyatomic molecules that allows one to successfully solve the problem of potential energy surface (PES) determination via construction and diagonalization of a Hamiltonian matrix of large dimension. In the suggested approach, the Hamiltonian is very simple and can be used both for any "normal" polyatomic molecule and for any isotopic species of a molecule. Molecules with two to four equivalent X-Y bonds are considered, and for illustration of the efficiency of the suggested approach, numerical calculations are made for the three-atomic (hydrogen sulfide) and four-atomic (formaldehyde) molecules.
Ambipolar MoS2 Transistors by Nanoscale Tailoring of Schottky Barrier Using Oxygen Plasma Functionalization
2017
One of the main challenges to exploit molybdenum disulfide (MoS2) potentialities for the next-generation complementary metal oxide semiconductor (CMOS) technology is the realization of p-type or ambipolar field-effect transistors (FETs). Hole transport in MoS2 FETs is typically hampered by the high Schottky barrier height (SBH) for holes at source/drain contacts, due to the Fermi level pinning close to the conduction band. In this work, we show that the SBH of multilayer MoS2 surface can be tailored at nanoscale using soft O-2 plasma treatments. The morphological, chemical, and electrical modifications of MoS2 surface under different plasma conditions were investigated by several microscopi…
7.22 Health Monitoring of High Performance Composite Pressure Vessels
2018
The most important form of damage in carbon fiber reinforced composite pressure vessels is the failure of the fibers however the rate of fiber failure is controlled by the viscoelastic nature of the matrix, which determines overall in-service lifetimes. This type of damage is very different from that encountered with metal pressure vessels and requires a detailed understanding in order to ensure reliability. Innovative proof testing methods based on these processes are necessary. The damage processes and the means of quantifying them are discussed. Their reliability under pressure over periods of decades is analyzed. Intrinsic safety factors linked directly to the properties of the composit…
Debonding Phenomena in CFRP Strengthened Calcarenite Masonry Walls and Vaults
2009
In this paper the results of an experimental investigation on full-scale reinforced masonry elements like vaults and walls are presented. The masonry type is constituted by calcarenite ashlars and bed joint mortar and the reinforcement is constituted by Carbon Fibre Reinforced Polymer (CFRP) strips. Preliminary experimental results obtained in a previous research by the authors on the local behaviour at the interface CFRP-calcarenite are summarized. Tests with controlled displacement are carried out on out-of-plane loaded walls and cylindrical vaults loaded at a quarter of the span. Results of tests carried out before and after the application of the reinforcement made it possible to evalu…
Environmental chamber for an atomic force microscope.
2007
A commercial atomic force microscope (AFM), originally designed for operation in ambient conditions, was placed inside a compact aluminum chamber, which can be pumped down to high vacuum levels or filled with a desired gaseous atmosphere, including humidity, up to normal pressure. The design of this environmental AFM is such that minimal intrusion is made to the original setup, which can be restored easily. The performance inside the environmental chamber is similar to the original version.
Detection of defects buried in metallic samples by scanning microwave microscopy
2011
This paper reports the local detection of buried calibrated metal defects in metal samples by a new experimental technique, scanning microwave microscopy. This technique combines the electromagnetic measurement capabilities of a microwave vector network analyzer with the subnanometer-resolution capabilities of an atomic force microscope. The network analyzer authorizes the use of several frequencies in the range 1--6 GHz, allowing three-dimensional tomographical investigation, which is useful for the detection of bulk defects in metal materials.