Search results for "functional"
showing 10 items of 4822 documents
The Eco-tourist in Canadian and Italian national Parks
2013
The present paper aims to compare the image of the eco-tourist across languages and cultures, Canadian and Italian. An ad-hoc comparable corpus has been created from the official websites of National Parks which represent a kind of eco-tourist destination. The analysis attempts to trace a profile of Canadian and Italian eco-tourists Drawing upon the Functional Grammar (Halliday 1985) and addresses issues connected with Hall’s model (1983): Are Canadian and Italian ecotourism discourses shaped by their own cultural orientation, or do they attempt to speak in the tongue of the displaced tourist?
Anagraphical relationships and crime specialization within Cosa Nostra
2021
Abstract The aim of the present work is to investigate the relationships established within Cosa Nostra, by making use of networks and complex-systems methods. The analysis is performed at three different levels, that is, individuals, groups within mafia syndicates, and relationships amongst mafia syndicates. The reported empirical analysis is based on the criminal records of 632 affiliates to Cosa Nostra selected from a set of 125 judgements emitted by the Palermo courts from 2000 to 2014. According to the criminal records of the Palermo Prosecutor Office, such a dataset includes approximately 10% of the whole population of Cosa Nostra affiliates in western Sicily. Furthermore, the vital s…
On the intrinsic population of the lowest triplet state of uracil
2007
Abstract From CASPT2//CASSCF quantum-chemical computations it is determined that the lowest triplet state of uracil can be efficiently populated from the initially activated singlet manifold through respective singlet–triplet crossings of the singlet state with the low-lying 3nπ∗ state at 4.6 eV and with the lowest 3ππ∗ state at 4.2 eV located along the minimum energy path of the low-lying 1ππ∗ state. Large spin–orbit coupling elements predict, in particular for the former case, efficient intersystem crossing processes. The wavelength dependence measured for the triplet quantum yield can be explained by the location of the singlet–triplet crossing regions.
Origin of the large spectral shift in electroluminescence in a blue light emitting cationic iridium(III) complex
2007
A new, but archetypal compound [ Ir( ppy- F-2) (2)Me(4)phen] PF6, where ppy- F2 is 2-(2',4'- fluorophenyl) pyridine and Me(4)phen is 3,4,7,8- tetramethyl- 1,10- phenanthroline, was synthesized and used to prepare a solid-state light-emitting electrochemical cell (LEEC). This complex emits blue light with a maximum at 476 nm when photoexcited in a thin film, with a photoluminescence quantum yield of 52%. It yields an efficient single-component solid-state electroluminescence device with a current efficiency reaching 5.5 cd A(-1) and a maximum power efficiency of 5.8 Lm Watt(-1). However, the electroluminescence spectrum is shifted with respect to the photoluminescence spectrum by 80 nm resul…
Electronic and magnetic structure ofLa0.875Sr0.125MnO3calculated by means of hybrid density-functional theory
2007
We present the results of ab initio calculations on magnetic and electronic structures of La1�xSrxMnO3 at low doping, x =1/8. Using the B3LYP hybrid exchange-correlation functional within the framework of densityfunctional theory, we predict a ferromagnetic ground state for La0.875Sr0.125MnO3 in both the low-temperature orthorhombic and the high-temperature pseudocubic phases. This is in contrast to its parent compound LaMnO3, for which we find in agreement with experiment the layered antiferromagnetic state to be the most stable one. The calculated density of states and bond population analysis suggest a tendency of formation of half-metallic spin states in the band gap of both structures.
Assessing the Beneficial Effects of Economic Growth: The Harmonic Growth Index
2011
In this paper we introduce the multidimensional notion of harmonic growth as a situation of diffused well-being associated to an increase of per capita GDP. We say that a country experienced a harmonic growth if during the observed period all the key indicators, proxies of the endogenous and exogenous forces driving population well-being, show a significantly common pattern with the income dynamics. The notion is operationalized via an index of time series harmony which follows the functional data analysis approach. This Harmonic Growth Index (HGI) is based on comparisons between the coefficients from cubic B-splines interpolation. Such indices are then synthesized in order to provide the g…
Un programa de entrenamiento para familiares de pacientes con trastorno límite de la personalidad basado en la terapia dialéctica comportamental
2021
espanolLos familiares de pacientes con trastorno limite de la personalidad (TLP) experimentan ansiedad y depresion, y estan inmersos en un clima familiar disfuncional. Aunque existen tratamientos eficaces para el TLP, se ha prestado menos atencion a los familiares. El objetivo de este trabajo fue adaptar para familiares el entrenamiento grupal en habilidades de la terapia dialectica comportamental, en 14 sesiones. La muestra estuvo formada por 12 familiares: 50% madres, 41,7% padres y 8,3% parejas. Se evaluaron los niveles de depresion (BDI-II), ansiedad (OASIS) y emocion expresada (LEE-S) antes y despues de la intervencion. Los resultados indican que tras la intervencion se produce una mej…
First-principles calculations on surface hydroxyl impurities in BaF2
2012
Abstract OH − impurities located near the (1 1 1) BaF 2 surface have been studied by using density functional theory (DFT) with hybrid exchange potentials, namely DFT-B3PW. Twenty surface OH − configurations were studied, and the hydroxyls located on the first surface layer are the energetically most favorable configurations. For the (1 1 1) BaF 2 surface atomic layers, the surface hydroxyls lead to a remarkable XY -translation and a dilating effect in the Z -direction, overcoming the surface shrinking effect in the perfect slab. Bond population analysis shows that the surface effect strengthens the covalency of surface OH − impurities. The studies on band structures and density of states (…
Context-dependent foraging habitat selection in a farmland raptor along an agricultural intensification gradient
2021
Abstract Gradients of agricultural intensification in agroecosystems may determine uneven resource availability for predators relying on these man-made habitats. In turn, these variations in resource availability may affect predators’ habitat selection patterns, resulting in context-dependent habitat selection. We assessed the effects of gradients of landscape composition and configuration on habitat selection of a colonial farmland bird of prey, the lesser kestrel (Falco naumanni), relying on 76 GPS-tracked nestling-rearing individuals from 10 populations scattered along an agricultural intensification gradient. Analyses were conducted considering two ecological levels of aggregation (the …
Maximal isometric muscle strength and functional ability in daily activities among 75-year-old men and women
2007
The purpose of this study was to analyze whether functional ability in daily activities among 75-year-old men and women is predicted by physical activity, isometric muscle strength and simple function tests. In this representative sample of a general population of 405 75-year-olds, isometric muscle strength and functional ability in daily activities were closely related (odds ratio of disability 1.2–2.1), stressing the importance of strength in the truncus, proximal and distal muscle groups for daily activities. There were strong correlations between physical activity, isometric muscle strength as well as simple function tests and ability to manage daily activities. Those with even light ph…