Search results for "grain"
showing 10 items of 752 documents
Studies and Researches on the Obtaining of Sintered Gradual Porous Structures by Irregular Nickel Powders Sedimentation
2012
The aim of this work is to obtain sintered porous membranes with graded structure for microfiltration by sedimentation and sintering of metallic powders. Our previous studies have demonstrated the possibility of obtaining sintered porous materials with graded structure by sedimentation. In this paper, irregular nickel particles were used having a grain size in the 2-90 µm range evaluated using scanning electron microscopy and laser scattering particle size analyzer. The powders were sedimented into a sintering die in a sedimentation medium consisting of water and dispersant agent. After drying, the samples were sintered at 1000°C for 10 minutes in vacuum (~1•10-3 Pa). The structures obtaine…
Improved Cu2O/AZO Heterojunction by Inserting a Thin ZnO Interlayer Grown by Pulsed Laser Deposition
2019
Cu2O/ZnO:Al (AZO) and Cu2O/ZnO/AZO heterojunctions have been deposited on glass substrates by a unique three-step pulsed laser deposition process. The structural, optical, and electrical properties of the oxide films were investigated before their implementation in the final device. X-ray diffraction analysis indicated that the materials were highly crystallized along the c-axis. All films were highly transparent in the visible region with enhanced electrical properties. Atomic force and scanning electron microscopies showed that the insertion of a ZnO layer between the Cu2O and AZO films in the heterojunction enhanced the average grain size and surface roughness. The heterojunctions exhibi…
Structural defects in Hg1−xCdxI2 layers grown on CdTe substrates by vapor phase epitaxy
1997
Hg1−xCdxI2 20–25-μm-thick layers with a uniform composition in the range of x = 0.1–0.2 were grown on CdTe substrates by vapor phase epitaxy (VPE). The growth was carried out using an α-HgI2 polycrystalline source at 200 °C and in the time range of 30–100 h. The layers were studied by scanning electron microscopy (SEM) and high resolution synchrotron x-ray topography (SXRT). The SEM and SXRT images of Hg1−xCdxI2 VPE layers allow one to identify the defects affecting the layer structure. The two main types of structural defects in the layers are subgrain boundaries and densely spaced striations similar to those referred generally to as vapor grown HgI2 bulk crystals. The effect of the growth…
An automated procedure for computing the packing properties of dense and locked sands by image analysis of thin sections
2014
The macroscopic mechanical behaviour of dense sands originates to a great extent from their microstructural characteristics such as the coordination number, the grain contact and the packing density indexes. The study of intergranular contacts and the reckoning of these indexes may be carried out on planar images of the grains either by means of time-consuming visual inspection assisted by CAD or by automatic image analysis. An innovative method for the automatic determination of microstructural characteristics of sands based on image analysis of thin section is proposed. Tests performed on a locked sand show that the proposed method is much more effective, convenient and faster than the us…
Effect of silicon on corrosion resistance of Ti–Si alloys
2011
Abstract The corrosion resistance of Ti–Si alloys has been studied in acid solutions and the alloys exhibit a high resistance to corrosion. SEM examinations combined with EDAX allowed to conclude that the passive films on Ti–Si alloys are mainly composed of TiO 2 /SiO 2 oxides. XPS analysis indicated the formation of Si–O and Si–O–Ti bonds in the passive film, respectively corresponding to SiO 2 and Si-doping TiO 2 . The effect of silicon on the corrosion was correlated to the formation of a stable SiO 2 film, Si-doping on TiO 2 and the extended lattice imperfections formed along TiO 2 /SiO 2 grain boundaries and phase-boundaries. The calculated donor densities based on the point defect mod…
Scanning electron microscopy analysis of defect clusters in multicrystalline solar grade silicon solar cells
2014
Solar cells from an identical commercial manufacturing unit have been investigated by electroluminescence to first detect the defect clusters. A further analysis has been done by scanning electron microscopy in secondary electron imaging mode to understand the propagation mechanism of defects. It appears that defect cluster boundaries can be very sharp or spread in the bulk with little apparent effect on the overall cell efficiency. And it is shown that grain boundaries act clearly as arrests to further propagation of these defects.
Electrical and structural characterization of metal-oxide-semiconductor capacitors with silicon rich oxide
2001
Metal-oxide-semiconductor capacitors in which the gate oxide has been replaced with a silicon rich oxide (SRO) film sandwiched between two thin SiO2 layers are presented and investigated by transmission electron microscopy and electrical measurements. The grain size distribution and the amount of crystallized silicon remaining in SRO after annealing have been studied by transmission electron microscopy, whereas the charge trapping and the charge transport through the dots in the SRO layer have been extensively investigated by electrical measurements. Furthermore, a model, which explains the electrical behavior of such SRO capacitors, is presented and discussed. © 2001 American Institute of …
PLZT—Synthesis, sintering and ceramics microstructure
2006
Abstract Producing of PLZT powders by original two-stage co-precipitation method from mixed solution of inorganic salts ZrOCl 2 ·8H 2 O, TiCl 4 , La(NO 3 ) 3 ·6H 2 O, Pb(NO 3 ) 2 , was carried out. The sequence of phases formed during PLZT synthesis has been studied by X-ray and DTA analysis. Ceramic samples were prepared by two-stage hot-pressing technology. Dielectric, ferroelectric and optical properties have been measured. Ceramic microstructures were studied by SEM with energy dispersive analytical capability (EDX). The fine-grained microstructure was quite uniform with the average grain size of 5–7 μm, without internal or grain boundary porosity. The optical transmittance of ceramic p…
Coarsened Lattice Model for Random Granular Systems
1998
In random systems consisting of grains with size distributions the transport properties are difficult to explore by network models. However, the concentration dependence of effective conductivity and its critical properties can be considered within coarsened lattice model proposed that takes into account information from experimentally known size histograms. For certain classes of size distributions the specific local arrangements of grains can induce either symmetrical or unsymmetrical critical behaviour at two threshold concentrations. Using histogram related parameters the non-monotonic behaviour of the conductor-insulator and conductor-superconductor threshold is demonstrated.
Stress/strain effects on electrochemical activity: Metallurgical/mechanical/interactions and surface reactivity
2021
Abstract Tribocorrosion is of complex nature as it involves multiscale interactions between mechanical, (electro-)chemical, physical, and material factors. The influence of mechanical stresses/strains on the surface reactivity of metallic alloys is described here. The electrochemical behavior and the corrosion resistance of engineering alloys are discussed in the presence of compressive and tensile stresses through different examples. The role of physical (formation of steps, roughness, microcracks), metallurgical (dislocations, crystallographic texture, and grain size), and chemical (passive film composition) changes induced by plastic deformation on electrochemical behavior and corrosion …