Search results for "graphe"
showing 10 items of 563 documents
Structural and thermal stability of graphene oxide-silica nanoparticles nanocomposites
2017
Abstract The investigation of the thermal stability up to 400 °C of Graphene Oxide (GO) and GO-silica nanoparticles (n-SiO2) composites prepared by direct mixture of GO and n-SiO2 is reported. Using Scanning Electron Microscopy, X-ray Photoelectron Spectroscopy, Energy Dispersive X-ray analysis, Atomic Force Microscopy, Raman and Infrared absorption measurements a thorough characterization of the prepared materials is carried out. By deepening the changes induced in the 2D Raman spectral region of GO at about 2900 cm−1 the comprehension of an interplay, driven by the thermally induced changes of the material, between inter-valley and intra-valley vibrational transitions is elucidated. This …
Hybrid and 2D nanomaterials
2020
International audience; In order to still improve the performances of chemical sensors, numerous hybrid materials were synthesized that combined at least two types of materials reported in the three previous chapters. We will distinguish materials combining macrocyclic molecules with polymers, those in which these molecules are associated to carbonaceous materials, mainly carbon nanotubes (CNTs) and graphene, and organic-inorganic hybrid materials. In this chapter, we will also include 2D materials introduced recently as sensing materials after the huge development of graphene and graphene oxide-based materials.
Photothermal Ablation of Cancer Cells Using Folate-Coated Gold/ Graphene Oxide Composite
2017
Objective: A new tumor targeted polymer-coated gold/graphene hybrid has been developed for achieving simultaneously thermoablation and chemoterapy of folate receptor-positive cancer cells. Methods: The gold/graphene hybrid was prepared by depositing gold nanospheres onto graphene oxide and coating it with an inulin-folate conjugate. Paclitaxel was loaded by sonication. The hybrid was characterized by UV-Vis spectroscopy, DSC analysis and SEM microscopy. The cytotoxicity, thermoablation and anticancer activity were evaluated in vitro on MCF-7 and 16 HBE. Results: In vitro tests showed that the paclitaxel-loaded hybrid improved the effectiveness of the drug especially after photothermal treat…
Tunable phonon-cavity coupling in graphene membranes
2016
A major achievement of the past decade has been the realization of macroscopic quantum systems by exploiting the interactions between optical cavities and mechanical resonators. In these systems, phonons are coherently annihilated or created in exchange for photons. Similar phenomena have recently been observed through phonon-cavity coupling - energy exchange between the modes of a single system mediated by intrinsic material nonlinearity. This has so far been demonstrated primarily for bulk crystalline, high-quality-factor (Q > 105) mechanical systems operated at cryogenic temperatures. Here, we propose graphene as an ideal candidate for the study of such nonlinear mechanics. The large …
A perpendicular graphene/ferromagnet electrode for spintronics
2020
We report on the large-scale integration of graphene layers over a FePd perpendicular magnetic anisotropy (PMA) platform, targeting further downscaling of spin circuits. An L10 FePd ordered alloy showing both high magneto-crystalline anisotropy and a low magnetic damping constant, is deposited by magnetron sputtering. The graphene layer is then grown on top of it by large-scale chemical vapor deposition. A step-by-step study, including structural and magnetic analyses by x-ray diffraction and Kerr microscopy, shows that the measured FePd properties are preserved after the graphene deposition process. This scheme provides a graphene protected perpendicular spin electrode showing resistance t…
Impact of nitrogen doping on the band structure and the charge carrier scattering in monolayer graphene
2021
The addition of nitrogen as a dopant in monolayer graphene is a flexible approach to tune the electronic properties of graphene as required for applications. Here, we investigate the impact of the doping process that adds N dopants and defects on the key electronic properties, such as the mobility, the effective mass, the Berry phase, and the scattering times of the charge carriers. Measurements at low temperatures and magnetic fields up to 9 T show a decrease of the mobility with increasing defect density due to elastic, short-range scattering. At low magnetic fields weak localization indicates an inelastic contribution depending on both defects and dopants. Analysis of the effective mass …
Graphene in strong laser field: experiment and theory
2015
The interaction of graphene nanoparticles and strong 64 fs pulses is examined. We demonstrate high-order harmonic generation in the plasma contained in crumpled sheets of graphene. The morphological studies of the debris of ablated graphene, application of single-color and two-color pumps of graphene-containing plasma, and theoretical consideration of the high-order harmonic generation in this medium are presented.
Real-time monitoring of graphene patterning with wide-field four-wave mixing microscopy
2016
The single atom thick two-dimensional graphene is a promising material for various applications due to its extraordinary electronic, optical, optoelectronic, and mechanical properties. The demand for developing graphene based applications has entailed a requirement for development of methods for fast imaging techniques for graphene. Here, we demonstrate imaging of graphene with femtosecond wide-field four-wave mixing microscopy. The method provides a sensitive, non-destructive approach for rapid large area characterization of graphene. We show that the method is suitable for online following of a laser patterning process of microscale structures on single-layer graphene. peerReviewed
Graphene Cardboard: from Ripples to Tunable Metamaterial
2014
Recently graphene was introduced with tunable ripple texturing, a nanofabric enabled by graphene's remarkable elastic properties. However, one can further envision sandwiching the ripples, thus constructing composite nanomaterial, graphene cardboard. Here the basic mechanical properties of such structures are investigated computationally. It turns out that graphene cardboard is highly tunable material, for its elastic figures of merit vary orders of magnitude, with Poisson ratio tunable from 10 to -0.5 as one example. These trends set a foundation to guide the design and usage of metamaterials made of rippled van der Waals solids.
Graphene and Fullenene Clusters
2017
Interacting induced-dipoles polarization in code POLAR permits calculating molecular polarizability, which is tested with endohedral metallofullerenes Scn@Cm and clusters Cn (fullerene, graphene, GR). Polarizability identifies aggregates with dissimilar numbers of atoms and separates isomers. Results are of the same order of magnitude as reference computations performed with code PAPID. Polarizability bulk limit is estimated from Clausius–Mossotti relationship. Polarizability trend for clusters vs. size is unexpected: they are more polarizable than bulk. Theory yielded the same for small Sin, Gen and GanAsm; however, experiment oppositely deferred for larger Sin, GanAsm and GenTem. Smaller …