Search results for "ionic"
showing 10 items of 2016 documents
Computer modeling of metal colloid formation in tracks of swift heavy ions in ionic solids
2001
Abstract We present results of computer modelling of the aggregation of primary radiation defects—F centers—in ionic crystals within tracks of swift heavy ions. We study how F-aggregate properties depend on the initial density of primary Frenkel defects in the track and its radius. The mean number of F centers in aggregates is typically very small, about five defects, which greatly complicates detection of expected metal colloids by ESR.
Radiation-induced point defects in simple oxides
1998
We present a survey of recent theoretical studies of radiation-induced point defects in simple oxides with emphasis on highly ionic MgO, partly-covalent corundum (Al2O3) and ferroelectric KNbO3. The atomic and electronic structure of the electronic (F a and F centers) and hole centers, as well as interstitial atoms therein are discussed in light of the available experimental data. Results for defect diAusion and photo-stimulated F a fi F center conversion are also ana
Electrical properties of Au/CdZnTe/Au detectors grown by the boron oxide encapsulated Vertical Bridgman technique
2016
Abstract In this work we report on the results of electrical characterization of new CdZnTe detectors grown by the Boron oxide encapsulated Vertical Bridgman technique (B-VB), currently produced at IMEM-CNR (Parma, Italy). The detectors, with gold electroless contacts, have different thicknesses (1 and 2.5 mm) and the same electrode layout, characterized by a central anode surrounded by a guard-ring electrode. Investigations on the charge transport mechanisms and the electrical contact properties, through the modeling of the measured current–voltage ( I – V ) curves, were performed. Generally, the detectors are characterized by low leakage currents at high bias voltages even at room tempera…
Laser spectroscopy with an electrostatic ConeTrap
2017
A compact electrostatic trap has been designed and installed as part of the recent upgrades to the IGISOL IV facility. The ConeTrap provides an in vacuo optical pumping site for low energy (800 eV) ionic ensembles available for interaction periods of 10-100 ms. At present, 6.7(3) % of injected mass A=98 ions can be trapped, stored for 5 ms, extracted and transported to a laser-ion interaction region. This fraction represents those ions for which no perturbation to total energy or energy spread is observed. Proposed enhancements to the trap are designed to improve the trapping efficiency by up to a factor of 5. Differential pumping and reduction in background pressure below the present 10−6 …
0.1-10 MeV Neutron Soft Error Rate in Accelerator and Atmospheric Environments
2021
Neutrons with energies between 0.1-10 MeV can significantly impact the Soft Error Rate (SER) in SRAMs manufactured in scaled technologies, with respect to high-energy neutrons. Their contribution is evaluated in accelerator, ground level and avionic (12 km of altitude) environments. Experimental cross sections were measured with monoenergetic neutrons from 144 keV to 17 MeV, and results benchmarked with Monte Carlo simulations. It was found that even 144 keV neutrons can induce upsets due to elastic scattering. Moreover, neutrons in the 0.1-10 MeV energy range can induce more than 60% of the overall upset rate in accelerator applications, while their contribution can exceed 18% in avionics.…
A study of a helium-jet ion guide for an on-line isotope separator
1981
Abstract A new method based on helium-jet techniques permits primary recoil ions, produced in radioactive decay or in nuclear reactions to be run directly through a mass separator. Results obtained with a 227 Ac source promise qualities complementary with those obtained with conventional ion sources and indicate an overall efficiency of the order of 10%. Preliminary results with 20 Na recoils from the 20 Ne(p,n)-reaction indicate that most of the ionic species transported out from the target chamber are negatively charged.
The Szilard–Chalmers effect in macrocyclic ligands to increase the specific activity of reactor-produced radiolanthanides: Experiments and explanatio…
2012
Abstract Successful utilization of medical isotopes in the radiolabeling reactions to a significant degree depends on the technically achievable specific activity. In this respect, the Szilard-Chalmers effect is considered in detail as a radiochemical tool to increase the specific activity of radionuclides produced by direct nuclear reactions. In the present study, a physico-chemical model is described utilizing the specific aspects of thermodynamically and kinetically stabilised metal-ligand complexes. The approach is applied as a proofof- principle study to increase the specific activity of 166Ho, produced via the (n, γ) nuclear reaction. As a target material, 165Ho-DOTA is used. In this …
Reactions of benzothiete with phosphorus nucleophiles - a novel type of arbuzov rearrangement
1989
The reaction of trialkylphosphites or related P-nucleophiles with benzothiete (1) leads to zwitter ionic species, which show an Arbuzov - like rearrangement to the products 4 and 7, respectively. New heterocyclic ring systems are generated in the case of cyclic esters. The normal SN2 reaction leads to the 1:2 adducts 9, whereas in an SN1 process the 1:1 adduct 13 is formed.
ChemInform Abstract: Reactions of Benzothiete with Phosphorus Nucleophiles. A Novel Type of Arbuzov Rearrangement.
1989
The reaction of trialkylphosphites or related P-nucleophiles with benzothiete (1) leads to zwitter ionic species, which show an Arbuzov - like rearrangement to the products 4 and 7, respectively. New heterocyclic ring systems are generated in the case of cyclic esters. The normal SN2 reaction leads to the 1:2 adducts 9, whereas in an SN1 process the 1:1 adduct 13 is formed.
Established cotton stainer gut bacterial mutualists evade regulation by host antimicrobial peptides
2019
Symbioses with microorganisms are ubiquitous in nature and confer important ecological traits to animal hosts but also require control mechanisms to ensure homeostasis of the symbiotic interactions. In addition to protecting hosts against pathogens, animal immune systems recognize, respond to, and regulate mutualists. The gut bacterial symbionts of the cotton stainer bug, Dysdercus fasciatus, elicit an immune response characterized by the upregulation of c-type lysozyme and the antimicrobial peptide pyrrhocoricin in bugs with their native gut microbiota compared to that in dysbiotic insects. In this study, we investigated the impact of the elicited antimicrobial immune response on the estab…