Search results for "isolation"

Pulmonary and lobar isolation in a patient with aspergilloma within a tuberculous cavity

2015

2021

FTIR spectroscopy was combined with the matrix isolation technique and quantum chemical calculations with the aim of studying complexes of isocyanic acid with sulfur dioxide. The structures of the HNCO⋯SO2 complexes of 1:1, 1:2 and 2:1 stoichiometry were optimized at the MP2, B3LYPD3, B2PLYPD3 levels of theory with the 6-311++G(3df,3pd) basis set. Five stable 1:1 HNCO⋯SO2 complexes were found. Three of them contain a weak N-H⋯O hydrogen bond, whereas two other structures are stabilized by van der Waals interactions. The analysis of the HNCO/SO2/Ar spectra after deposition indicates that mostly the 1:1 hydrogen-bonded complexes are present in argon matrices, with a small amount of the van de…

Medicinal plants and antimicrobial activity.

2005

In the present paper, we analyze the past, present and future of medicinal plants, both as potential antimicrobial crude drugs as well as a source for natural compounds that act as new anti-infection agents. In the past few decades, the search for new anti-infection agents has occupied many research groups in the field of ethnopharmacology. When we reviewed the number of articles published on the antimicrobial activity of medicinal plants in PubMed during the period between 1966 and 1994, we found 115; however, in the following decade between 1995 and 2004, this number more than doubled to 307. In the studies themselves one finds a wide range of criteria. Many focus on determining the antim…

Isolation and identification of the antibacterial compounds from Helichrysum stoechas.

1991

Fractionation of the dicholoromethane extract of the aerial parts of Helichrysum stoechas yielded seven isolates (1-7), which exhibited varying antimicrobial activity against Gram-positive bacteria. Pure compounds 1-3 have been previously reported in the same species and 4 and 5 were identified as italipyrone and plicatipyrone, previously isolated from H. italicum and H. plicatum. The two other isolates are helipyrone (6) and homoarenol (7) mixed with related substances. Compound 6c (4,4'-dihydroxy-5,6,5',6'-tetramethyl-3,3'-methylen-di-pyr-2-one) and 6b helipyrone with one methyl substitution, have not been previously reported in other species.

Die Wirkung von Pharmaka auf die Elimination von Noradrenalin aus der Perfusionsfl�ssigkeit und die Noradrenalinaufnahme in das isolierte Herz

1964

Isolation, Identification, and Chemical Synthesis of 6α-Hydroxyraumacline: A Novel Alkaloid from CultivatedRauwolfia serpentinaCells

1992

From RAUWOLFIA SERPENTINA cells cultivated in the presence of ajmaline ( 2) the new indole alkaloid, 6alpha-hydroxyraumacline ( 1), was isolated. This alkaloid also occurs in significant amounts in the nutrition medium. A simple chemical synthesis of 1 was developed starting from ajmaline ( 2).

Two New Eudesmanolides from Artemisia caerulescens subsp. gargantae.

1990

Anharmonic Vibrational Spectrum and Experimental Matrix Isolation Study of Thioformic Acid Conformers -- Potential Candidates for Molecular Cloud and…

2021

Thioformic acid (TFA) is the sulfur analog of formic acid, the simplest organic acid. It has three analogues HCOSH, HCSOH, and HCSSH, each of them having two rotational isomeric (rotameric) forms: trans and cis where the trans form is energetically more stable. In this article, we study computational energetics and anharmonic vibrational spectrum of TFA including overtone and combination vibrations. We also studied experimental photoisomerization and photodecomposition channels of HCOSH molecules with different wavelengths. We suggest that TFA is a potential sulfur containing candidate molecule for interstellar and planetary observations and discuss these in a light of different radiation e…

On the design of a multiple-output DC/DC converter for the PHI experiment on-board of solar orbiter

2013

Power converters for experiments that have to fly on board space missions (satellite, launchers, etc.) have very stringent requirements due to its use in a very harsh environment. The selection of a suitable topology is therefore not only based on standard requirements but additional more strict ones have also to be fulfilled. This work shows the design procedure followed to build the Power Converter Module (PCM) for the Polarimetric and Helioseismic Imager (SO/PHI), experiment on board the Solar Orbiter Satellite. The selected topology has been a Push-Pull, for a power level of approximately 35 W and with seven output voltages. Galvanic isolation is needed from primary to secondary, but no…

Detecting Eccentricity and Demagnetization Fault of Permanent Magnet Synchronous Generators in Transient State

2019

Eccentricity and demagnetization fault of a four-pole 1.5 kW surface mounted permanent-magnet synchronous-generator (PMSG) were modelled by using time-discretised finite element analysis (FEA). Both fault types are caused by magnetic asymmetry in the generator. The faulty behaviour of a PMSG under transient operating condition is studied with FEA. Two search coils were wound around stator teeth on opposite sides of the rotor. The induced voltage from these coils will be equal in healthy case. A fault is detected when the induced voltages are non-identical. The simulation results revealed that the envelope of the induced search coil voltage had sinusoids during dynamic eccentricity and demag…