Search results for "isotope ratio"

showing 10 items of 222 documents

Long-term summer temperature variations in the Pyrenees from detrended stable carbon isotopes

2015

Abstract Substantial effort has recently been put into the development of climate reconstructions from tree-ring stable carbon isotopes, though the interpretation of long-term trends retained in such timeseries remains challenging. Here we use detrended δ13C measurements in Pinus uncinata tree-rings, from the Spanish Pyrenees, to reconstruct decadal variations in summer temperature back to the 13th century. The June-August temperature signal of this reconstruction is attributed using decadally as well as annually resolved, 20th century δ13C data. Results indicate that late 20th century warming has not been unique within the context of the past 750 years. Our reconstruction contains greater …

530 PhysicsIsotopes of carbonStable isotope ratioClimatologyGlobal warmingPaleoclimatologyEarth and Planetary Sciences (miscellaneous)DendrochronologyClimate changeContext (language use)Dendroclimatology550 Earth sciences & geologyGeologyGeochronometria
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Persistent link between Caribbean precipitation and Atlantic Ocean circulation during the Last Glacial revealed by a speleothem record from Puerto Ri…

2020

The sensitivity of tropical Atlantic precipitation patterns to the mean position of the Intertropical Convergence Zone (ITCZ) at different time scales is well‐known. However, recent research suggests a more complex behavior of the northern hemispheric tropical rain belt related to the ITCZ in the western tropical Atlantic. Here we present a precisely dated speleothem multi‐proxy record from a well‐monitored cave in Puerto Rico, covering the period between 46.2 and 15.3 ka. The stable isotope and trace element records document a pronounced response of regional rainfall to abrupt climatic excursions in the North Atlantic across the Last Glacial such as Heinrich stadials and Dansgaard/Oeschger…

551.7Atmospheric Sciencegeographygeography.geographical_feature_categoryStable isotope ratio550.28Last GlacialspeleothemsOcean currentPaleontologySpeleothemstable isotopesprecipitation reconstructionOceanographyOceanographyHeinrich stadialsPrecipitationGlacial periodGeologyDansgaard/Oeschger cycles
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Thermomineral waters of Greece: geochemical characterization

2020

75 °C). In terms of pH most results vary from 5.5 to 823 °C) ii) warm (23 40 °C) iii) thermal (40 75 °C) and iv) hyperthermal (&gtfew springs show either very low pH (&lt10) proposing serpentinization processes. Regarding TDS concentrations collected waters can be subdivided into low salinity (up to 1.5 g/L) brackish (up to 20 g/L) and saline (up to 43 g/L). The medium high salinities can be justified by mixing with sea water and/or strong waterrock interaction processes. Isotope composition of O and H ranges from 12.7 to +2.7 ‰ SMOW and from 91 to +12 ‰ SMOW respectively and is generally comprised between the Global Meteoric Water Line and the East Mediterranean Meteoric Water Line. Only few water samples show a positive shift for δ18O possibly related to high temperature waterrock interaction processes. Carbon dioxide (18 997000 μmol/mol) or N2 (1100 989000 μmol/mol) or CH4 (&ltMany geothermal areas of Greece are located in regions affected by Miocene or Quaternary volcanism and in continental basins characterised by elevated heat flow. Moreover the majority of them is found along the coast as well as in islands of the Aegean Sea and thus thermal water is often brackish to saline due to marine intrusion into costal aquifer. In the present study almost 300 thermal and cold mineral water samples were collected along the Hellenic territory with their physicochemical parameters (temperature pH electrical conductivity and Eh) and the amount of bicarbonates (titration with 0.1N HCl) being determined in situ. Additionally gases found either in free or dissolved phase were sampled. Both water and gas samples were analysed at the INGVPa laboratories for major ions (Ion Chromatography) silica (Inductively Coupled Plasma Optical Emission Spectrometry) chemical composition of free and dissolved gases (Gas Chromatography) water isotopes (O and H) and carbon and helium isotopes of free and dissolved gases (Mass Spectrometry). The temperature of the investigated waters ranges from 6.5 to 98°C pH from 1.96 to 11.98 whilst Total Dissolved Solids (TDS) from 0.06 to 43 g/L. Based on the temperature parameter waters can be divided into four groups: i) cold (&lt0.5 913000 μmol/mol) are the prevailing gas species found in the studied sites. The δ13CCO2 values ranged from 20.1 to +8.5 ‰ whilst the isotope ratio of He from 0.21 to 6.71 R/RA.4) suggesting interaction with H2Srich gases or very high pH values (&gtSettore GEO/08 - Geochimica E Vulcanologia
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Petrography and carbonate isotope stratigraphy from MIS AND-1B core, Antarctica: Evidence of the early Pliocene warming event

2011

Abstract A large portion of ANDRILL (ANtarctic geological DRILLing) core AND-1B recovered in the Western Ross Sea and spanning the early Pliocene has been investigated in order to obtain a detailed carbonate isotope record from Antarctic margin sediments through the early Pliocene warming event. Petrographic observations and mineralogical analyses reveal the authigenic nature of the carbonate and small proportions of Fe and Mg incorporated within the calcite lattice. High productivity conditions testified by ~ 80 m-thick diatomite interval (383 to 460 mbsf) well fit with the composite nature of the authigenic carbonate generally characterizing organic matter-rich sediments. As is known, sed…

ANDRILLCalciteGlobal and Planetary Changegeographygeography.geographical_feature_categoryδ13CStable isotope ratioδ18OGlacierAuthigenicearly PlioceneOceanographypalaeoclimatePetrographychemistry.chemical_compoundPaleontologychemistrystable isotopeAntarcticaCarbonateGeologyGlobal and Planetary Change
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Carbon and nitrogen stable isotope ratios of soils and grasses as indicators of soil characteristics and biological taxa

2019

Abstract The use of stable isotope techniques can assist in understanding interactions of plants with various abiotic and biotic processes. In the research, we focused on carbon (C) and nitrogen (N) isotopes because they are the most important resources influencing plant function and the biogeochemical cycles. The 13C/12C and 15N/14N ratios in plants and in soils and the relationships between these ratios and biological and environmental factors of widely distributed native C3 plants (couch grass, plantain and yarrow) collected from two sites in St. Petersburg, Russia were studied. The soil characteristics of the sites were rather different. This had a significant effect on the isotope rati…

Abiotic componentBiogeochemical cycleIsotopeSoil textureStable isotope ratiochemistry.chemical_element010501 environmental sciences010502 geochemistry & geophysics01 natural sciencesPollutionNitrogenAgronomychemistryGeochemistry and PetrologySoil waterEnvironmental ChemistryEnvironmental scienceCarbon0105 earth and related environmental sciencesApplied Geochemistry
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Sr-isotope analysis of speleothems by LA-MC-ICP-MS: High temporal resolution and fast data acquisition

2017

Speleothems are well established climate archives. A wide array of geochemical proxies, including stable isotopes and trace elements are present within speleothems to reconstruct past climate variability. However, each proxy is influenced by multiple factors, often hampering robust interpretation. Sr isotope ratios (87Sr/86Sr) can provide useful information about water residence time and water mixing in the host rock, as they are not fractionated during calcite precipitation. Laser ablation multi-collector-inductively coupled plasma mass spectrometry (LA-MC-ICP-MS) has rarely been used for determination of Sr isotope signatures in speleothems, as speleothems often do not possess appropriate…

Ablation TechniquesSpeleothemMineralogyF700F800F600010502 geochemistry & geophysics01 natural sciencesF900chemistry.chemical_compoundGeochemistry and Petrology0105 earth and related environmental sciencesIsotope analysisCalcitegeographygeography.geographical_feature_categoryLaser ablationIsotopeStable isotope ratio010401 analytical chemistryGeology0104 chemical scienceschemistry13. Climate actionCarbonateGeology
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Carbon stable isotope composition of charophyte organic matter in a small and shallow Spanish water body as a baseline for future trophic studies

2015

<p>Quantitative descriptions of foodweb structure based on isotope niche space require knowledge of producers’ isotopic signatures. In freshwater ecosystems charophytes are one of the main components of submerged vegetation and the feeding base for many herbivorous consumers, but knowledge about their organic carbon isotopic signatures is sparse. In this study, the δ<sup>13</sup>C organic values (and organic %C and %N) of the four species of submerged macrophytes (three charophytes - <em>Chara hispida</em>, <em>Nitella hyalina</em> and <em>Tolypella glomerata </em>- and one angiosperm, <em>Myriophyllum spicatum</em>) growing …

Albufera de Valencia Natural Park.NicheMyriophyllum spicatumChara hispidaAquatic Scienceδ13C signatureBotanyOrganic matterlcsh:Physical geographylcsh:Environmental sciencesWater Science and TechnologyTrophic levellcsh:GE1-350Total organic carbonchemistry.chemical_classificationNitella hyalinaEcologyMyriophyllumbiologyEcologyStable isotope ratiolcsh:Geography. Anthropology. RecreationTolypella glomeratabiology.organism_classificationMacrophytelcsh:GchemistryBenthic zonelcsh:GB3-5030Journal of Limnology
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Beyond the grave: variability in Neolithic diets in Southern Germany?

2006

Abstract Carbon and nitrogen stable isotope analyses were undertaken on human and faunal remains from two Neolithic sites in Southern Germany; the LBK settlement at Herxheim and the middle Neolithic cemetery at Trebur. Stable isotope data were used to reconstruct the diets of individuals buried at these sites and to look at dietary variation between groups classified by their sex, age, grave goods and cultural affiliation. Overall there was surprisingly little variation in the diet between the groups, as described by the stable isotope analysis, despite significant differences in the composition of grave goods. Also surprising, considering the archaeological evidence for extensive grain cul…

Animal proteinArcheologyGrave goodsHistoryHabitatStable isotope ratioEcologyδ15NArchaeologyArchaeological evidenceHerxheimIsotope analysisJournal of Archaeological Science
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Zooplankton, lipids and stable isotopes: importance of seasonal, latitudinal, and taxonomic differences

2010

We found considerable seasonal, latitudinal, and taxonomic differences in zooplankton lipid content and concur- rent d 13 C values of zooplankton. We collected cladoceran as well as cyclopoid and calanoid copepod zooplankton from boreal and subarctic lakes throughout a year, allowing us to study zooplankton likely subjected to different isotopic fractionation processes and with highly variable lipid contents. Considerable seasonal variation was observed in the differ- ence between bulk and lipid-extracted zooplankton d 13 C values, indicating that seasonally changing lipid content intro- duced notable variation in zooplankton d 13 C values. The difference between bulk and lipid-extracted ma…

Aquatic environmentEcologyStable isotope ratioAquatic ScienceBiologyZooplanktonEcology Evolution Behavior and SystematicsAquatic organismsCanadian Journal of Fisheries and Aquatic Sciences
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Prospects of Ion Chemical Reactions with Heavy Elements in the Gas Phase

2001

Heavy element chemistry is related to the fundamental interest that lies in exploring the upper limits of the periodic table. Chemical properties of the heaviest elements have already been studied at single atoms in aqueous solutions and in the gas phase up to an atomic number Z = 107. These techniques allow to study nuclides with half lives as short as about 1 s. Next generation chemistry experiments could be envisaged with an ion trap technique already developed for stable isotopes. At very low production rates in the order of 1 per 100 s and/or half lives as short as about 10 ms, the ion-molecule reactions can be studied in a buffer gas cell, in which the heavy elements are stopped and t…

Aqueous solutionChemistryStable isotope ratioBuffer gasNuclideAtomic numberIon trapAtomic physicsChemical reactionIon
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