Search results for "layer"
showing 10 items of 2667 documents
Strong influence of lowermost stratospheric ozone on lower tropospheric background ozone changes over Europe
2007
[1] Using ozone measurements from two sounding sites and two high-altitude stations in Central Europe, we show evidence for a dominant influence of changes in lowermost stratospheric ozone on the variability and overall upward trend of background ozone in the lower troposphere (3000–3500 m asl) during the 1992–2004 period. Numerical simulations with a stratospheric chemistry transport model suggest that changes in lower stratospheric ozone were driven by dynamics rather than by changes in stratospheric chlorine loading. In addition, Lagrangian model simulations indicate that changes in downward transport of ozone from the stratosphere into the troposphere were dominated by changes in lowerm…
Low temperature atomic layer deposition of noble metals using ozone and molecular hydrogen as reactants
2013
Abstract Atomic layer deposition (ALD) of noble metals by thermal processes has relied mostly on the use of molecular oxygen as a reactant at temperatures of 200 °C and above. In this study, the concept of using consecutive ozone and molecular hydrogen pulses with noble metal precursors in ALD is introduced for palladium, rhodium, and platinum metals. This approach facilitates the growth of noble metal thin films below 200 °C. Also the ALD of palladium oxide thin films is demonstrated by the ozone-based chemistry. The growth rates, resistivities, crystallinities, surface roughnesses, impurity contents, and adhesion of the films to the underlying Al 2 O 3 starting surface are reported and th…
Control of Oxygen Nonstoichiometry and Magnetic Property of MnCo2O4 Thin Films Grown by Atomic Layer Deposition
2010
Spinel-structured (Mn,Co)3O4 thin films were reproducibly fabricated by atomic layer deposition (ALD) using Mn(thd)3, Co(thd)2, and ozone as precursors. A full control of the cation ratio was achieved in the temperature interval 140−160 °C within which also the growth rate remained constant. Precise control of the oxygen content of as-deposited MnCo2O4+δ films was achieved through postdeposition heat treatments at prefixed temperatures in air and N2 atmospheres, as evidenced from the monotonous increases of both the unit cell volume and the Curie temperature (TC) with increasing annealing temperature/decreasing oxygen partial pressure. The TC value varied from 92 K for the as-deposited MnCo…
Ozone-Based Atomic Layer Deposition of Al2O3 from Dimethylaluminum Chloride and Its Impact on Silicon Surface Passivation
2017
Dimethylaluminum chloride (DMACl) as an aluminum source has shown promising potential to replace more expensive and commonly used trimethylaluminum in the semiconductor industry for atomic layer deposited (ALD) thin films. Here, the Al2O3 DMACl-process is modified by replacing the common ALD oxidant, water, by ozone that offers several benefits including shorter purge time, layer-by-layer growth, and improved film adhesion. It is shown that the introduction of the ozone instead of water increases carbon and chlorine content in the Al2O3, while long ozone pulses increase the amount of interfacial hydrogen at silicon surface. These are found to be beneficial effects regarding the surface pass…
Selectivity improvement of semi-conducting gas sensors by selective filter for atmospheric pollutants detection
2006
International audience; The monitoring of atmospheric pollution using chemical gas sensors is a challenge due to the lack of selectivity of most existing devices. However, their performances can be improved using filtering films achieving the separation or the removal of some gases. This study is focused on the detection of carbon monoxide and of oxidant pollutants (nitrogen dioxide and ozone) by sensors constituted of SnO2, or phthalocyanine compounds. Two types of filters were investigated. Filters based on MnO2 powder are successful to remove ozone while preserving nitrogen dioxide in a large temperature range from ambient to 400 -C, but they partially convert carbon monoxide. The second…
Effect of ozone concentration on silicon surface passivation by atomic layer deposited Al2O3
2015
Abstract We study the impact of ozone-based Al2O3 Atomic Layer Deposition (ALD) on the surface passivation quality of crystalline silicon. We show that the passivation quality strongly depends on the ozone concentration: the higher ozone concentration results in lower interface defect density and thereby improved passivation. In contrast to previous studies, our results reveal that too high interface hydrogen content can be detrimental to the passivation. The interface hydrogen concentration can be optimized by the ozone-based process; however, the use of pure ozone increases the harmful carbon concentration in the film. Here we demonstrate that low carbon and optimal hydrogen concentration…
Surface investigation of plasma HMDSO membranes post-treated by CF4/Ar plasma
2002
Fluorination treatment has been performed on polysiloxane membranes using a plasma glow discharge of a gases mixture CF4 and argon (plasma enhanced chemical vapor deposition). Atomic force microscopy, XPS analyses and contact angle measurements have been undertaken to explain the surface transformation and behavior, which strongly depend on the morphology, the composition and the hydrophilic/hydrophobic character of the plasma-polymerized initial membranes. Main result is that fluorination, which leads to hydrophobic membranes, has a more relevant effect on amorphous silica-like membranes than on polymer-like ones, according to their chemical composition whereas the plasma surface reaction …
BIODEGRADABLE BILAYER FILMS PREPARED BY CO-EXTRUSION
2017
The sensitivity for reducing packaging waste drove academic and industrial efforts to search compostable or biodegradable bio-sourced polymeric materials. Multilayer systems represent a suitable strategy to obtain the required properties and to improve biopolymer performance. The aim of the current work is the coextrusion film blowing of a biodegradable bilayer film PLA/MaterBi with the purpose to overcome the drawbacks of the individual components.
Performance of porous silica layers in open-tubular columns for liquid chromatography
1989
Abstract Progress has been made in the preparation of porous silica layers in fused-silica capillaries for open-tubular liquid chromatography. The porous silica layer is prepared by (i) static coating of the silica precursor, polyethoxysiloxane (PES), followed by (ii) converting the PES film into a porous silica layer with ammonia solution. The porous silica layer can be easily modified by silane reagents commonly used in packed column high-performance liquid chromatography. The performance of the silica layer with the different phase systems was tested with polyaromatic hydrocarbons and derivatized amino acids as samples.
Hydrodynamics of a cocurrent downflow of gas and foaming liquid through the packed bed. Part II. Liquid holdup and gas pressure drop
2003
Abstract In the present study the results of experiments have been presented whose aim was to determine the values of liquid holdup as well as gas pressure drop through the packing for systems foaming under the pulse flow regime. On the basis of 245 experimental points for the pulse flow regime the verification of the models describing the hydrodynamics of the system has been performed. Attention was focused on the models of Benkrid et al. (Chem. Eng. Sci. 52 (1997) 4021), Pina et al. (AIChE J. 47 (2001) 19) and Fourar et al. (Chem. Eng. Sci. 56 (2001) 5987). It has been concluded that none of the models analysed describes the hydrodynamics of the foaming systems with enough accuracy. Next,…