Search results for "linear dichroism"
showing 10 items of 32 documents
A Theoretical Model for Excitation Energy Transfer in Chlorosomes: Lamellar and Rod-Shaped Antenna Structures
2008
A model based on exciton theory is presented for description of excitation energy transfer in chlorosomes. Three models to describe the internal organization of the pigments inside the chlorosome were considered, a stack of single-wall rods, a stack of double-wall rods and a stack of lamellae directed along the long axis of the chlorosome. Simulated absorption, circular dichroism and linear dichroism spectra of single-wall rod and the lamella structures turned out to be practically identical. It was shown that rod—rod interactions may localize the exciton states in the regions of a rod facing a neighboring rod. Such localized states provide a fast excitation energy transfer mechanism in per…
Magneto-optical linear dichroism in threshold photoemission electron microscopy of polycrystalline Fe films.
2000
Magnetic linear dichroism in threshold photoemission has been exploited to obtain magnetic contrast in a photoemission electron microscope using a mercury arc lamp. The dichroism at threshold can be described similar to the magneto-optical Kerr effect in the region of visible light. The asymmetry of electron intensity observed for a 100 nm polycrystalline Fe film on silicon is A=(0.37+/-0.05)%. The asymmetry occurs for the geometry of the transverse Kerr effect. For unpolarized light the asymmetry was about half the value observed for linearly polarized light. Threshold photoemission microscopy has a large potential for high resolution magnetic domain imaging with fast data acquisition.
Infrared linear dichroism spectroscopy by a double modulation technique
1990
A linear IR dichroism experiment has been devised using a FTIR instrument in combination with a photoelastic modulator. Based on the Mueller-Stokes calculus, a method to directly obtain the absorbance spectra Av parallel and Av perpendicular from the modulated interferogram is developped, which allows the sensitive evaluation of the dichroic ratio. The photoelastic modulator, in combination with a FTIR instrument, offers high sensitivity, high speed, excellent signal to noise ratio and a broad spectral range from 3300 to 850 cm-1. First experimental results obstained from SBS block copolymer are reported.
Linear infrared dichroism by a double modulation technique
1991
In the first part of this paper an experimental setup using Fourier-transform infrared spectroscopy (FTIR) in combination with a photoelastic modulator (PEM) for linear dichroism measurements is described. The second part shows the influence of PEM-amplitude and scan-velocity on the sensitivity of the instrument. The third part deals with the fringe-problem in the baselines of absorbance spectra and its influence on the determination of the linear dichroic ratio.
Surface magnetism studied by photoelectron spectromicroscopy with high spatial and time resolution
2004
Abstract Photoemission electron microscopy (PEEM) is widely used for the study of magnetic surfaces and thin films. Ferromagnetic and antiferromagnetic microstructures are investigated exploiting magnetic circular and linear dichroism in the soft X-ray range using tuneable synchrotron radiation. Local dichroism spectroscopy gives access to magnetic moments of the elements in compounds or multilayer materials. Beyond these achievements, the method bears a high future potential with respect to an increased lateral resolution via aberration correction of the electron optics and a high time resolution in the 100 ps range for the study of dynamic processes. In addition, photoelectron spin polari…
DNA interaction of CuII, NiII and ZnII functionalized salphen complexes: studies by linear dichroism, gel electrophoresis and PCR.
2013
The interaction of salphen-type NiII, CuII and ZnII complexes with native DNA was investigated by exploiting linear dichroism experiments. The NiII complex behaves as a typical intercalator, binding strongly and stiffening and unwinding the DNA. The strength of the DNA interaction is slightly weaker for the copper complex and much weaker for the zinc complex. Plasmid-DNA gel electrophoresis experiments indicated that while CuII and ZnII complexes do not induce the unwinding of supercoiled DNA, the NiII complex has a nuclease activity without the addition of external agents. On the other hand, as shown in the PCR assays, we demonstrate that, at the used concentrations, only the CuII complex …
Photocontrolled On-Surface Pseudorotaxane Formation with Well-Ordered Macrocycle Multilayers.
2016
The photoinduced pseudorotaxane formation between a photoresponsive axle and a tetralactam macrocycle was investigated in solution and on glass surfaces with immobilized multilayers of macrocycles. In the course of this reaction, a novel photoswitchable binding station with azobenzene as the photoswitchable unit and diketopiperazine as the binding station was synthesized and studied by NMR and UV/Vis spectroscopy. Glass surfaces have been functionalized with pyridine-terminated SAMs and subsequently with multilayers of macrocycles through layer-by-layer self assembly. A preferred orientation of the macrocycles could be confirmed by NEXAFS spectroscopy. The photocontrolled deposition of the …
Spin-resolved low-energy and hard x-ray photoelectron spectroscopy of off-stoichiometric Co2MnSi Heusler thin films exhibiting a record TMR
2015
Half-metallic Co2MnSi-based Heusler compounds have attracted attention because they yield very high tunnelling magnetoresistance (TMR) ratios. Record TMR ratios of 1995% (at 4.2 K) are obtained from off-stoichiometric Co2MnSi-based magnetic tunnel junctions. This work reports on a combination of band structure calculations and spin-resolved and photon-polarisation-dependent photoelectron spectroscopy for off-stoichiometric Heusler thin films with the composition Co2Mn1.30Si0.84. Co and Mn are probed by magnetic dichroism in angle-resolved photoelectron spectroscopy at the 2p core level. In contrast to the delocalised Co 3d states, a pronounced localisation of the Mn 3d states is deduced fro…
Flexible Chirality in Self-Assembled N-Annulated Perylenedicarboxamides.
2017
N-annulated perylenedicarboxamides 1-3 form supramolecular polymers with a strong tendency to aggregate. The bundles of fibers formed generate a spontaneous anisotropy that conditions the chiroptical features of the described molecules in solution; a strong linear dichroism effect accompanies the circular dichroism (CD) outcome. There is no influence of the point chirality existing at the side chains of 1 and 2, and these molecules present the same chiroptical features as achiral 3. Mechanical rotary stirring increases the CD response and the sign of the dichroic signal changes with the stirring direction. Theoretical calculations indicate that the self-assembly of 1-3 in helical columnar s…
Single molecule probing of dynamics in supercooled polymers
2011
6 pages; International audience; Fluorescence experiments with single BODIPY molecules embedded in a poly(methyl acrylate) matrix have been performed at various temperatures in the supercooled regime. By using pulsed excitation, fluorescence lifetime and linear dichroism time trajectories were accessible at the same time. Both observables have been analyzed without data binning. While the linear dichroism solely reflects single particle dynamics, the fluorescence lifetime observable depends on the molecular environment, so that the dynamics from the polymer host surrounding a chromophore contributes to this quantity. We observe that the lifetime correlation decays slightly faster than polar…