Search results for "luminescence."
showing 10 items of 1568 documents
Bleach interference in forensic luminol tests on porous surfaces: more about the drying time effect.
2009
As criminals try to avoid leaving clues at the scene of a crime, bloodstains are often washed away, but fortunately for investigators, they are difficult to eliminate completely. Porous surfaces easily retain blood traces, which are sometimes invisible to the naked eye. The reagent of choice for detecting latent blood traces on all types of surfaces is luminol, but its main disadvantage is a high degree of sensitivity to oxidising contaminants in the blood sample. If household bleach is used to clean bloodstains, presumptive tests are invalidated. Hypochlorites, however, are known to be unstable and deteriorate over time, and this feature could be of help in preventing household bleach-indu…
<title>Luminescence of intrinsic defects in LiBaF<formula><inf><roman>3</roman></inf></formula></title&g…
2003
A wide emission band in the region of 425 nm is observed in all the examined crystals at photo and ionising irradiation. Maximum of the complex luminescence band is observed at 410 nm at 350 K and at 450 nm at 85 K. The shift of the peak of the band envelope towards shorter wavelengths as the temperature increases is related to thermal dependence of the intensity of elementary components of the luminescence band. The authors suggest that the complex luminescence band arises from electronic excitations at "antisite" defects, i.e., defects caused by stoichiometric deviations, when a portion of Li+ cations (cations of one type of the LiBaF3 crystal lattice) occupy sites of Ba2+ cations (cation…
Spray pyrolysis synthesis and characterization of Mg1-xSrxMoO4 heterostructure with white light emission
2020
[EN] Molybdates are inorganic materials with great potential in white phosphors application, being an alternative to traditional lighting sources. In this study, we report the synthesis and characterization of Mg1-xSrxMoO4 (x = 0, 0.25, 0.50, 0.75, and 1) powders with white light-emitting properties. Using X-ray diffraction, the formation of the monoclinic beta-MgMoO4 phase was observed for x = 0 and the formation of the tetragonal scheelite phase of SrMoO4 was observed for x = 1. The formation of a heterostructure composed of both phases was found for compositions with x = 0.25, 0.50 and 0.75. Scanning and trasmission electron microscopy images showed that the Mg1-xSrxMoO4 particles exhibi…
Iron’s Wake: The Performance of Quantum Mechanical-Derived Versus General-Purpose Force Fields Tested on a Luminescent Iron Complex
2020
Recently synthetized iron complexes have achieved long-lived excited states and stabilities which are comparable, or even superior, to their ruthenium analogues, thus representing an eco-friendly and cheaper alternative to those materials based on rare metals. Most of computational tools which could help unravel the origin of this large efficiency rely on ab-initio methods which are not able, however, to capture the nanosecond time scale underlying these photophysical processes and the influence of their realistic environment. Therefore, it exists an urgent need of developing new low-cost, but still accurate enough, computational methodologies capable to deal with the steady-state and trans…
Novel synthesis of up-conversion phosphor based on rare-earth doped NaLaF4
2011
In this work Er3+ doped NaLaF4 material has been synthesized Along with the description of the synthesis route, luminescence spectra and decay kinetics of both traditional and up-conversion luminescence of Er3+ will be presented for different Er3+ doping levels. It will be shown that the main mechanisms involved in the creation of the up-conversion luminescence in NaLaF4:Er3+ under excitation at about 975 nm are excited state absorption and energy transfer. Relative impact of either of the mechanisms in NaLaF4:Er3+ depends on both the concentration of Er3+ and on the excitation wavelength: the increase of either the concentration or the excitation wavelength leads to the prevalence of energ…
Up-Conversion Luminescence Processes in NaLaF4 Doped with Tm3+ and Yb3+ and Dependence on Tm3+ Concentration and Temperature
2021
In this work, luminescence processes in polycrystalline NaLaF4:Tm3+ and NaLaF4:Tm3+,Yb3+ materials were studied. Luminescence spectra and decay kinetics measurements were performed for NaLaF4 doped with various Tm3+ concentrations (0.01, 0.1, 0.5, 1, and 2 mol%) under direct excitation to 3P0, 1D2, 1G4, and 3H4 states. It was found that some of the Tm3+ excited states are more affected by Tm3+ concentration than other states. Under infrared excitation of Yb3+, energy transfer to Tm3+ occurred and intensive ultraviolet and blue up-conversion luminescence was observed. Possible up-conversion mechanisms are discussed. Spectroscopic measurements show that long-duration excitation radiation red…
Unveiling Molecular Changes in Water by Small Luminescent Nanoparticles
2017
This work was supported by the Spanish Ministerio de Educación y Ciencia (MAT2013-47395-C4-1-R and MAT2016-75362-C3-1- R) and by the COST Action CM1403. L.L.-P. thanks the Universidad Autónoma de Madrid for the “Formación de Personal Investigador (FPI-UAM)” program. P.H.-G. thanks the Spanish Ministerio de Economia y Competitividad (MINECO) for the Juan de la Cierva program. The authors from the University of Belgrade acknowledge the financial support of the Ministry of Education, Science and Technological Development of the Republic of Serbia (Project Nos. 45020 and 172056). M.I.M. thanks financial support from the Spanish Ministerio de Economía y Competitividad (MICINN) Project FIS2015-69…
Effect of plastic deformation on photoluminescence of ZnTe bulk monocrystals
1999
Abstract In this work ZnTe bulk single crystals have been deformed by axial compression with the aim of analyzing the luminescence properties related to intrinsic structural defects like dislocations. Plastic deformation greatly decreases the overall PL response, near-band-edge luminescence as well as deep level-related emissions. Results indicate a close relationship between the so-called Y1 and Y2 bands and the density of generated dislocations. Plastic deformation also produces an emission band at 603 nm whose intensity is proportional to the amount of introduced deformation.
Crystalline-Size Dependence of Dual Emission Peak on Hybrid Organic Lead-Iodide Perovskite Films at Low Temperatures
2018
In this work, we have investigated the crystalline-size dependence of optical absorption and photoluminescence emission of CH3NH3PbI3 films, which is necessary to identify the potential practical applications of the gadgets based on perovskite films. This study was carried out at low temperatures to minimize the extra complexity induced by thermal effects. The purpose was to clarify the origin of the dual emission peak previously reported in the literature. We found that the grain size is responsible for the appearance or disappearance of this dual emission on CH3NH3PbI3 at low temperatures, whereas we have inferred that the thickness of the perovskite layer is a much more important factor …
A high-accuracy calibration method for temperature dependent photoluminescence imaging
2019
This work demonstrates a novel technique for calibrating temperature dependent photoluminescence (PL) images of silicon wafers with high accuracy. The PL signal is calibrated using a heat-controlled photoconductance (PC) stage integrated into the PL imaging system. The PC signal is measured in true steady state condition and used to determine the calibration constant under the same temperature and illumination as the PL image, thus providing a high-precision calibration. This results in a robust method for imaging of important physical parameters, such as the minority carrier lifetime and the implied voltage at different temperatures, as well as the temperature coefficients and the recombin…