Search results for "melting"
showing 10 items of 238 documents
MoSi2 laser cladding—A new experimental procedure: double-sided injection of MoSi2 and ZrO2
2003
International audience; In the last decade, development of low density advanced material systems for service at temperatures up to 1300 °C was one of the goals of many researches. This kind of material should mainly have moderate fracture toughness and should exhibit oxidation resistant behaviour at low and intermediate temperature. One of the most studied materials continues to be the intermetallic compound MoSi2. The molybdenum disilicide has been considered as an attractive candidate due to its melting point (2030 °C) and excellent oxidation resistance at high temperatures. The main problem associated with the MoSi2 layer synthesized using laser beam is the layer fragility. To avoid this…
Hyperbranched Polylactide Copolymers
2006
A series of hyperbranched poly(l-lactide) (PLLA) copolymers were prepared by copolymerization of dilactide with 2,2-bis(hydroxymethyl)butyric acid (BHB) as an AB2 comonomer via a combined ring-open...
Generation of Earth's early continents from a relatively cool Archean mantle
2019
This research has been supported by DFG grant, SPP 1833 Building a Habitable Earth and MAGMA Consolidator Grant (ERC project #71143). Several lines of evidence suggest that the Archean (4.0 2.5 Ga) mantle was hotter than today's potential temperature (TP) of 1350 ° C. However, the magnitude of such difference is poorly constrained, with TP estimation spanning from 1500 ° C to 1600 ° C during the Meso‐Archean (3.2‐2.8 Ga). Such differences have major implications for the interpreted mechanisms of continental crust generation on the early Earth, as their efficacy is highly sensitive to the TP. Here, we integrate petrological modeling with thermomechanical simulations to understand the dynami…
Internal Differentiation of the Archean Continental Crust: Fluid-Controlled Partial Melting of Granulites and TTG-Amphibolite Associations in Central…
2009
Fault bound blocks of granulite and enderbite occur within upper amphibolite-facies migmatitic tonalitic-trondhjemitic-granodioritic (TTG) gneisses of the Iisalmi block of Central Finland. These units record reworking and partial melting of different levels of the Archean crust during a major tectonothermal event at 2·6-2·7 Ga. Anhydrous mineral assemblages and tonalitic melts in the granulites formed as a result of hydrous phase breakdown melting reactions involving amphibole at peak metamorphic conditions of 8-11 kbar and 750-900°C. A nominally fluid-absent melting regime in the granulites is supported by the presence of carbonic fluid inclusions. The geochemical signature of light rare e…
Contribution to the study of physico-chemical properties of surfaces modified by last treatment : application to the enhancement of localized corrosi…
2011
Metallic materials are more and more used in severe conditions with particularly strong request for improving their behavior in aggressive environment and especially over long periods. The objective of this PhD work is to estimate the potentiality of a laser surface melting treatment on the improvement of the stainless steel 304L corrosion resistance, surface treatments by laser can be revisited on the basis of a recent change in the laser technology. In the frame of this work, a nano-pulsed laser fiber was chosen : it allows the treated surface to be melted for few microns in depth, followed by an ultra-fast solidification occuring with cooling rates up to 1011 K/s. The combination of thes…
Classical growth of hard-sphere colloidal crystals.
1995
The classical theory of nucleation and growth of crystals is examined for concentrated suspensions of hard-sphere colloidal particles. The work of Russel is modified, extended, and evaluated, explicitly. Specifically, the Wilson-Frenkel growth law is modified to include the Gibbs-Thomson effect and is evaluated numerically. The results demonstrate that there is a critical nucleus radius below which crystal nuclei will not grow. A kinetic coefficient determines the maximum growth velocity possible. For large values of this coefficient, quenches to densities above the melting density show interface limited growth with the crystal radius increasing linearly with time. For quenches into the coe…
Kristallisations- und schmelzverhalten von copolymeren aus 3,3-bis(chlormethyl)oxetan und ß-propiolacton
1974
Einkristalle von Copolymeren aus 3,3-Bis(chlormethyl)oxetan und s-Propiolacton wurden bezuglich Schmelzverhalten, Schmelzenthalpie, Dichte und Langperiode untersucht. Aus der Messung der Schmelzenthalpie und der Dichte berechnen sich Kristallisationsgrade von 50—60% in guter Ubereinstimmung mit einem Modell, welches den Ausschlus der aus s-Propiolacton (PL) entstandenen Grundbausteine von dem aus Sequenzen der 3,3-Bis(chlormethyl)oxetan (BCMO-)Einheiten aufgebauten Gitter verlangt. Im Vergleich zu reinem Poly-BCMO wird die Dicke der Copolymereinkristalle nur wenig durch Anderung der Kristallisationstemperatur beEinflust. Wegen des blockartigen Aufbaus der Copolymeren bestimmt die mittlere S…
Molecular association in low-temperature and high-pressure polymorphs of 1,1,1,2-tetrachloroethane
2010
Interactions and aggregation of 1,1,1,2-tetrachloroethane molecules, Cl3CCH2Cl, have been investigated at low temperature and high pressure. Isobaric and isochoric crystallizations led to two polymorphs, characterized by single-crystal X-ray diffraction. The low-temperature polymorph α is monoclinic, space group C2/c, with molecules orientationally disordered in two sites at the temperature independent 70:30 rate. In isothermal conditions (295 K) 1,1,1,2-tetrachloroethane freezes at 0.73 GPa. The high-pressure polymorph β is monoclinic, space group P21/c, with the molecules fully ordered. The molecular aggregation at varied thermodynamic conditions results from the interplay of halogen inte…
Schmelz- und kristallisationserscheinungen bei makromolekularen substanzen. V. Partielles schmelzen und neukristallisieren von terylen
1960
Das nach dem Erhitzen oft innerhalb von Sekunden stattfindende partielle Schmelzen und erneute Kristallisieren von Terylen konnte mittels einer Abschreckmethode quantitativ untersucht werden. Die je nach der thermischen Vorbehandlung verschiedenen Schmelzkurven wurden unbeeinflust von Neukristallisationseffekten aufgenommen und weiterhin der Nachweis erbracht, das nur die gesamte Schmelzkurve und nicht der Kristallisationsgrad allein den kristallinen Zustand einer Probe ausreichend charakterisiert. Mikroskopische Untersuchungen zeigten, das partielles Schmelzen und Neukristallisation innerhalb der Spharolithe stattfinden. Weiterhin wurde die Kristallisation beim Abkuhlen von partiell geschm…
Classification et chronologie de bas fourneaux de réduction du fer à usage unique au sud-ouest du Niger
2016
In southwestern Niger, near Niamey, several thousand single-use bloomery furnaces have been mapped and identified. The archaeological study of approximately 30 furnaces and their slag reveals the existence of four methods for iron smelting: three types of pit furnace and one slag-tapping type. The slag pit furnaces are clearly differentiated by the form and volume of their pits. All slag-tapping furnaces drain off slag through small openings. The slag is tapped either vertically or laterally. According to radiocarbon dates, the smelting activity developed in the 2 nd century AD and intensified through to the 14 th century. It continued to evolve until the middle of the 20 th century. The lo…