Search results for "monoisotopic"
showing 10 items of 10 documents
Automated untargeted stable isotope assisted lipidomics of liver cells on high glucose shows alteration of sphingolipid kinetics
2020
Abstract Untargeted lipidomics is a powerful tool to discover new biomarkers and to understand the physiology and pathology of lipids. The use of stable isotopes as tracers to investigate the kinetics of lipids is another tool able to supply dynamic information on lipid synthesis and catabolism. Coupling the two methodology is then very appealing in the study of lipid metabolism. The main issue to face is to perform thousands of calculations in order to obtain kinetic parameters starting from the MS raw data. An automated computerized routine able to do accomplish such task is presented in this paper. We analyzed the lipid kinetics of palmitic acid (PA) in hepatoma liver cells cultured in v…
High-Resolution Spectroscopy and Analysis of the ν3 and ν4 Fundamentals of Monoisotopic 70GeF4
2001
The first high-resolution study on germanium tetrafluoride is reported. We used a monoisotopic sample of (70)GeF(4). The FTIR spectra of the two infrared active fundamentals, namely the nu(4) (bending) and nu(3) (stretching) modes, were recorded at a temperature of ca. 210 K and a resolution (1/maximum optical path difference) of 0.0031 and 0.0023 cm(-1), respectively. These spectra were analyzed using the STDS software developed in Dijon. In both cases, we obtained a fit with a root mean square better than 1x10(-3) cm(-1). Both bands show very regular structures with no detectable perturbation. Copyright 2001 Academic Press.
Study of the v3 = 1 State of 80SeF6 by Fourier Transform Spectroscopy
1997
The Fourier transform infrared spectrum of monoisotopic 80SeF6 has been recorded in the 760-792 cm-1 region with an effective resolution of ca. 2.3 x 10(-3) cm-1. The 80SeF6 sample was prepared by burning monoisotopic 80Se powder (99.2%) in an excess of fluorine. The analysis of infrared transitions of the nu3 band enabled the determination of parameters of the Hamiltonian developed up to the third order and the fourth order. The standard deviation obtained is equal to 4 x 10(-4) cm-1 for the third-order development and 3.2 x 10(-4) cm-1 for the fourth-order development. In the two analyses, 2900 lines were assigned and fitted. Copyright 1997 Academic Press. Copyright 1997Academic Press
First spatial isotopic separation of relativistic uranium projectile fragments
1994
Abstract Spatial isotopic separation of relativistic uranium projectile fragments has been achieved for the first time. The fragments were produced in peripheral nuclear collisions and spatially separated in-flight with the fragment separator FRS at GSI. A two-fold magnetic-rigidity analysis was applied exploiting the atomic energy loss in specially shaped matter placed in the dispersive central focal plane. Systematic investigations with relativistic projectiles ranging from oxygen up to uranium demonstrate that the FRS is a universal and powerful facility for the production and in-flight separation of monoisotopic, exotic secondary beams of all elements up to Z = 92. This achievement has …
Isotopic Enriched and Natural SiC Junction Barrier Schottky Diodes Under Heavy Ion Irradiation
2022
The radiation tolerance of isotopic enriched and natural silicon carbide junction barrier Schottky diodes are compared under heavy ion irradiation. Both types of devices experience leakage current degradation as well as single-event burnout events. The results were comparable, although the data may indicate a marginally lower thresholds for the isotopic enriched devices at lower linear energy transfer (LET). Slightly higher reverse bias threshold values for leakage current degradation were also observed compared to previously published work.
Ion-optical layout of a powerful next-generation pre-separator for in-flight separation of relativistic rare isotopes
2006
Abstract Rare isotope beams can be efficiently produced at relativistic energies via projectile fragmentation and projectile fission. Magnetic rigidity analysis in combination with atomic energy loss ( Bρ –Δ E – Bρ method) in profiled matter placed at dispersive focal planes represents the tool for spatial separation in flight. The next-generation in-flight separators at high energies will consist of multiple degrader stages to provide intense monoisotopic fragment beams of all elements up to uranium. The pre-separator layout with the first degrader system holds many technical challenges, e.g. to handle the high-power primary beams characterized by a large range in time structure, from a DC…
High-Resolution Spectroscopy and Preliminary Analysis of the ν1/ν8 Dyad of SF535Cl
2001
Abstract The Fourier transform infrared spectrum of monoisotopic SF 5 35 Cl has been recorded in the 650- to 960-cm −1 region at a temperature of 203 K, a pressure of 0.2 mbar, and an instrumental bandwidth of 0.002 cm −1 . The ν 1 /ν 8 dyad near 900 cm −1 has been analyzed with an effective Hamiltonian developed up to the fourth order and the help of a recently developed set of programs called C 4 v TDS ( C 4 v Top Data System, http://www.u-bourgogne.fr/LPUB/C4VTDS.html ); 1346 transitions for ν 1 , 351 transitions for ν 8 , and 406 ground state combination differences have been assigned and fitted. A global fit has been obtained with an rms of 0.00082 cm −1 for the ν 1 ( a 1 ) band, of 0.…
Analysis of the infrared Fourier transform spectrum of the Dyad of 116SnH4
1990
Abstract The FTIR spectrum of monoisotopic 116SnH4 has been recorded with the Bruker 120 HR interferometer at Giessen, West Germany, in the ν 2 ν 4 range extending from 600 to 850 cm−1. The resolution (FWHM) was 2.1 × 10−3 cm−1. The Dyad ν 2 ν 4 (0100, 0001) was analyzed using a sixth-order Hamiltonian. The analysis of infrared transitions enabled us to determine 10 ground state parameters, 9 ν2 parameters, 17 ν4 parameters, and 18 interaction parameters. Of 3800 calculated transitions assigned to observed lines, 1183 unblended lines have been selected for the data refinement. For J ≤ 19, the value of the standard deviation is of the order of magnitude of the estimated experimental accuracy…
Penning trap at IGISOL
2002
The IGISOL facility [1] at the Department of Physics of the University of Jyvaskyla (JYFL) is delivering radioactive beams of short-lived exotic nuclei, in particular the neutron-rich isotopes from fission reaction. These nuclei are studied with the nuclear and collinear laser spectroscopy methods. In order to obtain a meaningful increase, in comparison to a standard level, of precision and sensitivity of such studies an improvement of the radioactive beam quality is necessary. This improvement will be achieved due to a radioactive beam handling which consists of three steps: beam cooling, bunching and (isobaric) purification. The latter means a possibility of obtaining a pure monoisotopic …
Trap-assisted studies of odd, neutron-rich isotopes from Tc to Pd
2012
We review the present and future of trap-assisted structure studies of odd, neutron-rich Tc, Ru, Rh and Pd isotopes at the limits of present experimental techniques. These nuclei of refractory elements are produced in light-particle induced fission and filtered by their mass number with the IGISOL mass separator. Further mass separation with the JYFLTRAP Penning trap system provides a clean, monoisotopic beam perfectly suited for precise nuclear spectroscopy. Connecting the IGISOL and the JYFLTRAP facilities to the recently installed MCC30/15 cyclotron opens new prospects for post-trap spectroscopy of very exotic, neutron-rich nuclei. peerReviewed