Search results for "n-type"
showing 10 items of 66 documents
Monolayer and multilayer field-effect transistors based on a high-mobility n-type polymer: effect of the polymeric texture on charge transport
2012
Tri-alkenyl polyhedral oligomeric silsesquioxanes as comonomers and active center modifiers in ethylene copolymerization catalyzed by bis(phenoxy-imi…
2018
Abstract In copolymerization of ethylene (E) with tri-alkenyl-silsesquioxanes (POSS-6-3 and POSS-10-3) were used bis(phenoxy-imine) titanium, zirconium and vanadium catalysts, as well as salen-type vanadium catalysts. There were obtained copolymers with POSS-R-3 units as side branches of polymer chains. The type of employed bis(phenoxy-imine) titanium, zirconium and vanadium catalysts and salen-type catalyst of vanadium determined the copolymer chain termination reactions, as well as the mechanism of modification of the active species by the POSS-R-3 comonomer. POSS-R-3 comonomers caused selective poisoning of bis(phenoxy-imine) zirconium catalyst and they provided protection against tight …
On Language Adequacy
2015
Abstract The paper concentrates on the problem of adequate reflection of fragments of reality via expressions of language and inter-subjective knowledge about these fragments, called here, in brief, language adequacy. This problem is formulated in several aspects, the most general one being: the compatibility of the language syntax with its bi-level semantics: intensional and extensional. In this paper, various aspects of language adequacy find their logical explication on the ground of the formal-logical theory of syntax T of any categorial language L generated by the so-called classical categorial grammar, and also on the ground of its extension to the bi-level, intensional and ex- tensio…
Screening of ligands for the Ullmann synthesis of electron-rich diaryl ethers
2012
In the search for new ligands for the Ullmann diaryl ether synthesis, permitting the coupling of electron-rich aryl bromides at relatively low temperatures, 56 structurally diverse multidentate ligands were screened in a model system that uses copper iodide in acetonitrile with potassium phosphate as the base. The ligands differed largely in their performance, but no privileged structural class could be identified.
The discovery of a Mycenaean-type tholos tomb in the Bronze Age necropolis of the Gazzi buried floodplain (Messina, Southern Italy): new geological a…
2019
This paper deals with a monument that is, up to this date, unique in Sicily and in the Italian peninsula: the Mycenaean-type tholos tomb of the Gazzi necropolis in Messina. A recent excavation in the alluvial deposits revealed extensive traces of a funerary area with a tholos tomb and several enchytrismos tombs with skeletal remains, presumably dated back to the end of the Early or the initial stage of the Middle(?) Bronze Age. The present multi-disciplinary investigation has been developed to analyse new data related to sediments, building stones and skeletal remains of this funerary area. The stratigraphic succession hosting the necropolis was formed by overbank sediments deposited on the…
Postęp badań w zakresie polimeryzacji olefin
2011
Na podstawie obszernego przeglądu literatury omówiono rozwój katalizatorów metaloorganicznych stosowanych w procesie polimeryzacji olefin z uwzględnieniem najnowszych badań w tym zakresie. Przedstawiono możliwości otrzymywania z ich udziałem produktów o różnej strukturze i właściwościach. Na tle postępu w technologii otrzymywania poliolefin scharakteryzowano wyniki najnowszych prac zespołu opolskiego, od wielu lat biorącego aktywny udział w badaniach nad opracowaniem i oceną właściwości katalitycznych kolejnych, nowych grup metaloorganicznych katalizatorów polimeryzacji i kopolimeryzacji olefin. Szczególną uwagę poświęcono katalizatorom zaliczanym do grupy układów postmetalocenowych z ligan…
Electrodeposition and characterization of Mo oxide nanostructures
2015
Template electrodeposition has been used to grow uniform arrays of molybdenum oxide nanostructures in polycarbonate membrane. Several parameters have been investigated, like electrodeposition, time and solution pH. These parameters do not influence the nature of the deposit that always consists of mixed valence molybdenum oxides, whereas the nanostructure morphology changes with pH. In particular, at low pH (2.7), nanotubes are formed, whilst arrays of nanowires are obtained above pH 5.5. This change of morphology is likely due to H2 bubbles evolution during the electrochemical deposition, particularly occurring at low pH. It was found that fast removal of H2 bubbles through vigorous stirri…
Galvassāpju izplatība Latvijas Universitātes medicīnas studentu vidū
2022
Ievads: Galvassāpju traucējumi, galvenokārt primārie, tiek uzskatīti par nopietnām globālām veselības problēmām, kas izraisa ievērojamu invaliditātes slogu slimniekiem, lai arī paradoksālā kārtā, bieži tiek ignorēti un nenovērtēti. Cilvēki savos produktīvajos gados irvisvairāk skartā grupa, un to vidū ir arī studenti. Mērķis: Pētījuma mērķis bija apkopot Latvijas Universitātes medicīnas studentu galvassāpju epidemioloģiskos un klīniskos raksturojumus, lainoteiktu cefalģijas izplatību, novērtētu riska faktorus, provocējošos faktorus, galvassāpju ietekmi un to mazināšanu ar medikamentiem, kā arī noskaidrot iespējamos iemeslus, kādēļ pētāmā populācija izvairās no specializētas galvassāpju trau…
Sleep disturbances in tension-type headache and migraine
2017
Current research into the pathogenesis of tension-type headache (TTH) and migraine is focused on altered nociceptive pain processing. Among the potential factors that influence sensitization mechanisms, emotional stress, depression, or sleep disorders all have an essential role: they increase the excitability of nociceptive firing and trigger hyperalgesic responses. Sleep disturbances and headache disorders share common brain structures and pathogenic mechanisms and TTH, migraine, and sleep disturbances often occur together; for example, 50% of individuals who have either TTH or migraine have insomnia. Moreover, insomnia and poor sleep quality have been associated with a higher frequency an…
Differential blockade by nifedipine and ω-conotoxin GVIA of α1- and β1-adrenoceptor-controlled calcium channels on motor nerve terminals of the rat
1990
Electrically evoked release of [3H]acetylcholine ([3H]ACh) from the rat phrenic nerve and its facilitation by stimulation of presynaptic alpha 1- and beta 1-adrenoceptors were investigated in the absence and presence of nifedipine and omega-conotoxin GVIA. Both calcium channel antagonists did not modify electrically evoked [3H]ACh release, but selectively blocked the effect triggered by both facilitatory adrenergic receptors. The increase in [3H]ACh release mediated via beta 1-adrenoceptor activation was abolished by low concentrations (1 nM) of omega-conotoxin GVIA, whereas nifedipine (100 nM) abolished the facilitatory effect mediated via alpha 1-adrenoceptor stimulation. Therefore, the b…