Search results for "network"
showing 10 items of 7718 documents
From self-inclusion and host-guest complexes to channel structures
2012
Various supramolecular interactions are applied as driving forces in self-assembly and molecular recognition processes. Single crystal X-ray diffraction method is especially important for solid-state studies of non-covalent interactions as it reveals their influence on the molecular and supramolecular structures. This paper discusses structures of two completely different types of compounds in which a variety of intermolecular interactions are involved. It will be shown that strong and weak intermolecular hydrogen bonds in N-alkylammonium resorcinarene salts, depending on the type of anion, inclusion of resorcinarene upper rim pendant group or solvent molecules into the cavity, strongly aff…
Combining Cyanometalates and Coordination Clusters: An Alternative Synthetic Route toward Original Molecular Materials
2013
International audience; With the discovery of molecules or molecule-based compounds that can display blocked magnetization, magnetic ordering or switchable magnetic bistability, the research efforts devoted to molecular magnetic materials have considerably increased over the past two decades, fully exploiting the advantages of the bottom-up approach. 1-4 This research field focuses on promising properties for potential technological applications such as information storage, quantum computing and spintronics at the molecular scale, but it also provides fundamental insights into original quantum phenomena. 5,6 Coordination chemists have developed efficient synthetic tools for the preparation …
A spin-crossover complex based on a 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) ligand functionalized with a carboxylate group
2014
Combining Fe(ii) with the carboxylate-functionalized 2,6-bis(pyrazol-1-yl)pyridine (bppCOOH) ligand results in the spin-crossover compound [Fe(bppCOOH)2](ClO4)2 which shows an abrupt spin transition with a T1/2 of ca. 380 K and a TLIESST of 60 K due to the presence of a hydrogen-bonded linear network of complexes.
A comprehensive in situ and remote sensing data set from the Arctic CLoud Observations Using airborne measurements during polar Day (ACLOUD) campaign
2019
The Arctic CLoud Observations Using airborne measurements during polar Day (ACLOUD) campaign was carried out north-west of Svalbard (Norway) between 23 May and 6 June 2017. The objective of ACLOUD was to study Arctic boundary layer and mid-level clouds and their role in Arctic amplification. Two research aircraft (Polar 5 and 6) jointly performed 22 research flights over the transition zone between open ocean and closed sea ice. Both aircraft were equipped with identical instrumentation for measurements of basic meteorological parameters, as well as for turbulent and radiative energy fluxes. In addition, on Polar 5 active and passive remote sensing instruments were installed, while Polar 6 …
Machine learning regression algorithms for biophysical parameter retrieval: Opportunities for Sentinel-2 and -3
2012
Abstract ESA's upcoming satellites Sentinel-2 (S2) and Sentinel-3 (S3) aim to ensure continuity for Landsat 5/7, SPOT-5, SPOT-Vegetation and Envisat MERIS observations by providing superspectral images of high spatial and temporal resolution. S2 and S3 will deliver near real-time operational products with a high accuracy for land monitoring. This unprecedented data availability leads to an urgent need for developing robust and accurate retrieval methods. Machine learning regression algorithms may be powerful candidates for the estimation of biophysical parameters from satellite reflectance measurements because of their ability to perform adaptive, nonlinear data fitting. By using data from …
A 3-Year Sample of Almost 1,600 Elves Recorded Above South America by the Pierre Auger Cosmic-Ray Observatory
2020
The time and location of the 1,598 verified and reconstructed elves, used for the analysis showcased in this paper, are publicly available on the website of the Pierre Auger Observatory (https://www.auger.org/ index.php/science/data). We wish to thank the World Wide Lightning Location Network (http://wwlln.net), a collaboration among over 50 universities and institutions, for providing the lightning location data used in this paper. We acknowledge Robert Marshall for providing one of the most advanced elve simulations to the public, a key tool in understanding the elves observed by the Pierre Auger Observatory. The successful installation, commissioning, and operation of the Pierre Auger Ob…
Boulder coastal deposits at Favignana Island rocky coast (Sicily, Italy): Litho-structural and hydrodynamic control
2018
Boulders are frequently dislodged from rock platforms, transported and deposited along coastal zones by high-magnitude storm waves or tsunamis. Their size and shape are often controlled by the thickness of bedding planes as well as by high-angle to bedding fracture network. We investigate these processes along two coastal areas of Favignana Island by integrating geological data for 81 boulders, 49 rupture surfaces (called sockets) and fracture orientation and spacing with four radiocarbon dates, numerical hydrodynamic analysis, and hindcast numerical simulation data. Boulders are scattered along the carbonate platform as isolated blocks or in small groups, which form, as a whole, a disconti…
The joint sets on the Lilstock Benches, UK. Observations based on mapping a full resolution UAV-based image
2021
Outcrop studies of fracture networks are important to understand fractured reservoirs in the subsurface, but complete maps of all fractures in large outcrops are rare due to limitations of outcrop and image resolution. We manually mapped the first full-resolution UAV-based, Gigapixel dataset and DEM of the wave-cut Lilstock Benches in the southern Bristol Channel basin, a classic outcrop of layer-bound fracture networks in limestones. We present a map of the patterns and age relationships of successive sets of joints in dm-thick limestone layers separated by claystone beds. Using interpretation criteria based on crosscutting relationships, abutting and joint length, up to eight successive s…
Statistical retrieval of atmospheric profiles with deep convolutional neural networks
2019
Abstract Infrared atmospheric sounders, such as IASI, provide an unprecedented source of information for atmosphere monitoring and weather forecasting. Sensors provide rich spectral information that allows retrieval of temperature and moisture profiles. From a statistical point of view, the challenge is immense: on the one hand, “underdetermination” is common place as regression needs to work on high dimensional input and output spaces; on the other hand, redundancy is present in all dimensions (spatial, spectral and temporal). On top of this, several noise sources are encountered in the data. In this paper, we present for the first time the use of convolutional neural networks for the retr…
Edge-Based Missing Data Imputation in Large-Scale Environments
2021
Smart cities leverage large amounts of data acquired in the urban environment in the context of decision support tools. These tools enable monitoring the environment to improve the quality of services offered to citizens. The increasing diffusion of personal Internet of things devices capable of sensing the physical environment allows for low-cost solutions to acquire a large amount of information within the urban environment. On the one hand, the use of mobile and intermittent sensors implies new scenarios of large-scale data analysis