Search results for "passiv"
showing 10 items of 512 documents
Kinetics of Bulk Lifetime Degradation in Float‐Zone (FZ) Silico n : Fast Activation and Annihilation of Grown‐In Defects and the Role of Hydrogen vs …
2020
Float-zone (FZ) silicon often has grown-in defects that are thermally activated in a broad temperature window (≈300–800 °C). These defects cause efficient electron-hole pair recombination, which deteriorates the bulk minority carrier lifetime and thereby possible photovoltaic conversion efficiencies. Little is known so far about these defects which are possibly Si-vacancy/nitrogen-related (VxNy). Herein, it is shown that the defect activation takes place on sub-second timescales, as does the destruction of the defects at higher temperatures. Complete defect annihilation, however, is not achieved until nitrogen impurities are effused from the wafer, as confirmed by secondary ion mass spectro…
Passivity Breakdown: Development and Application of Local Chemical and Electrochemical Probe Methods
2018
Abstract The most identified classes of phenomena at the origin of the passivity breakdown and the electrochemical and chemical factors controlling the induced localized corrosion are summarized before introducing the scientific concepts at the origin of the design of the local probe techniques used in recent advances in understanding localized corrosion processes. Examples concerning the surface reactivity of aluminium alloys are presented to support a final discussion on the needs for experimental developments with capabilities to support modelling.
ZnS Ultrathin interfacial layers for optimizing carrier management in Sb2S3-based photovoltaics
2021
Antimony chalcogenides represent a family of materials of low toxicity and relative abundance, with a high potential for future sustainable solar energy conversion technology. However, solar cells based on antimony chalcogenides present open-circuit voltage losses that limit their efficiencies. These losses are attributed to several recombination mechanisms, with interfacial recombination being considered as one of the dominant processes. In this work, we exploit atomic layer deposition (ALD) to grow a series of ultrathin ZnS interfacial layers at the TiO2/Sb2S3 interface to mitigate interfacial recombination and to increase the carrier lifetime. ALD allows for very accurate control over th…
Impurity analyses of silicon wafers from different manufacturing routes and their impact on LID of finished solar cells
2013
Summarizes the measurements of impurity concentrations in directionally solidified silicon ingots from different feedstocks. The substitutional Carbon and interstitial Oxygen are measured on as-sawn wafers using FTIR. Active iron concentration is mapped on a-Si:H passivated wafers. It is observed that these impurities present in Elkem Solar Grade Silicon (ESS™) concentrations are comparable to the standard polysilicon which are in the acceptable ranges for silicon for solar industry. The measured LID of the finished solar cells is also comparable.
Thermal atomic layer deposition of AlOxNy thin films for surface passivation of nano-textured flexible silicon
2019
Abstract Aluminum oxynitride (AlOxNy) films with different nitrogen concentration are prepared by thermal atomic layer deposition (ALD) for flexible nano-textured silicon (NT-Si) surface passivation. The AlOxNy films are shown to exhibit a homogeneous nitrogen-doping profile and the presence of an adequate amount of hydrogen, which is investigated by Time-of-Fight Elastic Recoil Detection Analysis (ToF-ERDA). The effective minority carrier lifetimes are measured after the NT-Si surface passivation; the minimum surface recombination velocity (SRV) of 5 cm-s−1 is achieved with the AlOxNy film in comparison to the Al2O3 and AlN films (SRV of 7–9 cm-s−1). The better SRV with AlOxNy film is due …
Passivity-based output feedback control of Markovian jump systems with discrete and distributed time-varying delays
2013
In this article, we present a new method in designing mode-dependent passivity-based output feedback controllers for Markovian jump systems with time-varying delays. Both discrete and distributed delays are considered in the model. A Lyapunov–Krasovskii function is constructed to establish new required sufficient conditions for ensuring exponentially mean-square stability and the passivity criteria, simultaneously. The method produces linear matrix inequality formulation that allows obtaining controller gains based on a convex optimisation method. Finally, a numerical example is given to illustrate the effectiveness of our approach.
A passivity approach to control of Markovian jump systems with mixed time-varying delays
2013
This paper investigated the problem of control design for a class of stochastic systems with Markovian jump parameters and time-varying delays. For the model under consideration, a passivity-based approach is introduced for designing mode-dependent output feedback controllers with mixed discrete and distributed delays. A Lypunov-Krasovskii function (LKF) is defined to establish new required sufficient conditions for ensuring exponentially mean-square stability and the passivity criteria, simultaneously. Moreover, controller gains are calculated based on a convex optimization method by solving a Linear Matrix Inequality (LMI). Finally, simulation results are provided to illustrate the effect…
An Experimental Investigation on the Air Permeability of Passive Ventilation Grilles
2015
Abstract The need of increasing both energy saving and acoustic insulation has leaded to the design of lowest air permeability frames resulting in the worsening of indoor air quality. Moreover, sometime in several civil-use existing buildings (i.e. schools or houses, historical buildings) mechanical ventilation systems cannot be installed due to non-removable constraints. In these cases, passive ventilation grilles are a cheap and effective solution for the ventilation. This work deals with an in-depth experimental analysis about the air permeability values measured over a set of passive ventilation grilles available on the market. Obtained results often showed performances very far to thos…
How and When Do Leaders Influence Employees' Well-Being? Moderated Mediation Models for Job Demands and Resources
2019
Following the call of recent reviews on leadership and well-being, the purpose of this study is to examine how and when two contrasting leadership styles, transformational leadership (TFL) and passive-avoidant leadership (PAL), are related to employees’ anxiety and thereby either promote or inhibit employees’ well-being. Using the prominent job demands-resources (JD-R) model as a theoretical framework, we propose that the relationship between leadership behavior and anxiety is mediated by organizational job demands, namely, role ambiguity (RA), and job resources, namely, team climate for learning (TCL), as well as moderated by autonomy as important job characteristic. A sample of 501 knowle…
Monitoring the habitat use of common Bottlenose Dolphins (Tursiops truncatus) using passive acoustics in a Mediterranean marine protected area
2014
The Mediterranean Tursiops truncatus subpopulation has been classified as Vulnerable on the IUCN Red List because of its decline. This species in coastal areas is exposed to a wide variety of threats: directed kills, bycatch, reduced prey availability caused by environmental degradation and overfishing, habitat degradation including disturbances from boat traffic and noise. Despite the increase in boat traffic in the Mediterranean Sea, the effect on T. truncatus’ habitat use has been studied in little detail and few data have been published. This study represents the first attempt to characterise spatial and temporal habitat use by T. truncatus and its relation to boat traffic in the Isole …