Search results for "photovoltaic"
showing 10 items of 646 documents
High voltage vacuum-deposited CH3NH3PbI3-CH3NH3PbI3 tandem solar cells
2018
The recent success of perovskite solar cells is based on two solid pillars: the rapid progress of their power conversion efficiency and their flexibility in terms of optoelectrical properties and processing methods. That versatility makes these devices ideal candidates for multi-junction photovoltaics. We report an optically optimized double junction CH3NH3PbI3–CH3NH3PbI3 tandem solar cell where the matched short-circuit current is maximized while parasitic absorption is minimized. The use of an additive vacuum-deposition protocol allows us to reproduce calculated stack designs, which comprise several charge selective materials that ensure appropriate band alignment and charge recombination…
Vacuum deposited perovskite solar cells employing dopant-free triazatruxene as the hole transport material
2017
Abstract Planar perovskite solar cells using organic charge selective contacts were fabricated. In a vacuum deposited perovskite-based solar cell, dopant and additive free triazatruxene as the hole transport layer was introduced for device fabrication. High open-circuit voltage of 1090 mV was obtained using methylammonium lead iodide (Eg=1.55 eV) as light harvesting material, thus representing a loss of only 460 mV which is in close vicinity of mature silicon technology (400 mV). The devices showed a very competitive photovoltaic performance, monochromatic incident photon-to-electron conversion efficiency of 80% and the power conversion efficiencies in excess of 15% were measured with a neg…
Fabrication and Characterisation of Perovskite Thin Films for Photovoltaic Application
2018
This paper presents an alternative way to obtain perovskite thin films for photovoltaic application. This technique results more competitive, scalable, low-cost, reproducible and is different from other most common methods of fabrication.
New concepts and applications in macromolecular chemistry of fullerenes
2010
A new classification on the different types of fullerene-containing polymers is presented according to their different properties and applications they exhibit in a variety of fields. Because of their interest and novelty, water-soluble and biodegradable C(60)-polymers are discussed first, followed by polyfullerene-based membranes where unprecedented supramolecular structures are presented. Next are compounds that involve hybrid materials formed from fullerenes and other components such as silica, DNA, and carbon nanotubes (CNTs) where the most recent advances have been achieved. A most relevant topic is still that of C(60)-based donor-acceptor (D-A) polymers. Since their application in pho…
Metal thin-film temperature sensor embedded in heat-sink for CPV cells characterization
2014
The efficiency of a photovoltaic cell is dependent on its temperature, for this reason an accurate measurement of this parameter is important to fully characterize the device and to optimize its performance. For CPV applications a significant heat flux is needed to remove excess heat from the cell towards a heat sink, making it difficult to derive the cell temperature. In fact, measurements performed directly between the cell and the heat-sink, by use of commercial bulk sensors, would produce a significant disturbance in the heat flow; on the other hand, a measurement performed out of the cell / heat sink axis would be subject to large uncertainties, due to the high radial temperature gradi…
Analytic JV-Characteristics of Ideal Impurity PV-Cells
2017
In this article the mathematical modeling of idealized impurity photovoltaic cells is greatly simplified through the derivation of analytic JV-characteristics. The resulting expressions are also facilitating the intuitive understanding of such photovoltaic devices. The new model is used to investigate the sensitivity of impurity photovoltaic cells to the absorption band width, the impurity related absorptivity and the external radiative efficiency. It is found that impurities with narrow absorption bands or low absorptivity can greatly reduce the efficiency of the device, even if they are fully radiative and have energy levels situated at optimal positions in the band gap. It is also found …
External quantum efficiency measurements used to study the stability of differently deposited perovskite solar cells
2020
The instability exhibited by perovskite solar cells when exposed to the environment under illumination is one of the major obstacles for the entry of perovskite technology in the photovoltaic market. In this work, we use the external quantum efficiency (EQE) technique to study the photoinduced degradation of two types of solar cells having CH3NH3PbI3 as an absorber layer: one deposited by spin coating with an n-i-p architecture and the other deposited by evaporation with an inverted p-i-n structure. We also study the effect of different encapsulants to protect the cells against atmospheric agents. We find that EQE provides information regarding the areas of the cell most susceptible to degr…
Modeling and parameter identification of crystalline silicon photovoltaic devices
2011
This paper tests the standard single-exponential model of the electrical characteristics of crystalline-Si photovoltaic devices, focusing on the (apparent) shunt current. Measured characteristics of illuminated polycrystalline-Si photovoltaic modules are modeled, and the apparent shunt current is analyzed. It is shown that an Ohmic-like behavior only takes place at voltages well below the maximum-power point. At higher voltages, the apparent shunt current quickly drops to negligible values. Modeling a crystalline-Si PV device with a fixed shunt resistance may therefore lead to underestimation of the maximum power exceeding 10% at certain irradiance levels.
Moisture ingress in photovoltaic modules: A review
2021
Abstract Moisture ingress in photovoltaic (PV) modules is the core of most degradation mechanisms that lead to PV module power degradation. Moisture in EVA encapsulant can lead to metal grids corrosion, delamination and discolouration of encapsulants, potential induced degradation, optical and adhesion losses. The present work is a review of literature on the causes, effects, detection, and mitigation techniques of moisture ingress in PV modules. Literature highlights on determining the diffusivity, solubility, and permeability of polymeric components of PV modules via water vapour transmission rate tests, gravimetric, and immersion methods, have been presented. Electroluminescence, photolu…