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showing 10 items of 6771 documents
Characteristics of industrially manufactured amorphous hydrogenated carbon (a-C:H) depositions on high-density polyethylene
2016
Industrially high-density polyethylene (HDPE) was successively covered by two types of amorphous hydrogenated carbon (a-C:H) films, one more flexible (f-type) and the other more robust (r-type). The films have been grown by radio frequency plasma-enhanced chemical vapor deposition (RF-PECVD) technique with acetylene plasma. The surface morphology of both types has been studied by atomic force microscopy (AFM) and scanning electron microscopy (SEM). Contact angle measurements and Raman spectroscopy analysis were done to investigate the surface wettability and carbon chemical composition. Both types display similar morphology and grain growth pattern. Contact angle measurements revealed surfa…
Theoretical insights on the importance of anchoring vs molecular geometry in magnetic molecules acting as junctions
2019
The anchoring of the molecule to an electrode is known to be a key factor in single-molecule spintronics experiments. Likewise, a relaxation down to the most stable geometry is a critical step in theoretical simulations of transport through single-molecule junctions. Herein we present a set of calculations designed to analyze and compare the effect of different anchoring points and the effect of perturbations in the molecular geometry and interelectrode distance. As model system we chose the [V($\alpha$-C$_3$S$_5$)$_3$]$^{2-}$ complex connecting two Au(111) electrodes in a slightly compressed geometry. In our calculations, the attachment happens through an S-Au bond, a common anchoring stra…
Modification of magnetic anisotropy in Ni thin films by poling of (011) PMN-PT piezosubstrates
2016
ABSTRACTThis study reports the magnetic and magnetotransport properties of 20 nm thick polycrystalline Ni films deposited by magnetron sputtering on unpoled piezoelectric (011) [PbMg1/3Nb2/3O3]0.68-[PbTiO3]0.32 (PMN-PT) substrates. The magnetoresistance (MR), as well as the magnetization reversal, is found to depend on the polarization state of the piezosubstrate. Upon poling the PMN-PT substrate, which results in a transfer of strain to the Ni film, the MR value decreases by a factor of 12 at room temperature and a factor of 21 at 50 K for the current direction along the PMN-PT [100] direction, and slightly increases for the [01] current direction. Simultaneously, a strong increase in the …
Zn-substituted iron oxide nanoparticles from thermal decomposition and their thermally treated derivatives for magnetic solid-phase extraction
2020
Abstract Controlled thermal decomposition of zinc and iron acetylacetonates in the presence of oleic acid and oleylamine provided surfactant-capped magnetic nanoparticles with narrow size distribution and the mean diameter of ≈15 nm. The combined study by XRD, XRF and Mossbauer spectroscopy revealed three important features of the as-prepared nanoparticles. First, the actual ratio of Zn:Fe was considerably lower in the product compared to the initial ratio of metal precursors (0.14 vs. 0.50). Second, a pure stoichiometric Zn-doped magnetite system, specifically of the composition Zn0.37Fe2.63O4, with no signatures of oxidation to maghemite was formed. Third, Zn2+ ions were distributed at bo…
Dielectric breakdown of fast switching LCD shutters
2017
Fast liquid crystal optical shutters due to fast switching, vibrationless control and optical properties have found various applications: substitutes for mechanical shutters, 3D active shutter glasses, 3D volumetric displays and more. Switching speed depends not only on properties of liquid crystal, but also on applied electric field intensity. Applied field in the shutters can exceed >10 V/micron which may lead to dielectric breakdown. Therefore, a dielectric thin film is needed between transparent conductive electrodes in order to reduce breakdown probability. In this work we have compared electrical and optical properties of liquid crystal displays with dielectric thin films with thickne…
Co-Deposition and Characterization of Hydroxyapatite-Chitosan and Hydroxyapatite-Polyvinylacetate Coatings on 304 SS for Biomedical Devices
2019
During the last decades, biomaterials have been deeply studied to perform and improve coatings for biomedical devices. Metallic materials, especially in the orthopedic field, represent the most common material used for different type of devices thanks to their good mechanical properties. Nevertheless, low/medium resistance to corrosion and low osteointegration ability characterizes these materials. To overcome these problems, the use of biocoatings on metals substrate is largely diffused. In fact, biocoatings have a key role to confer biocompatibility properties, to inhibit corrosion and thus improve the lifetime of implanted devices. In this work, the attention was focused on Hydroxyapatit…
The Matrix Effect and Application of the Multi-Parameter Optimization Method for X-Ray Spectrometric Determination of the Quantitative Composition of…
2018
Determining the quantitative composition of clay samples with X-ray fluorescent spectrometry is complicated because of the matrix effect, in which any element can increase or decrease the analytical signals of other elements. In order to predict the properties of clays, it is essential to know their precise chemical composition. Therefore, using the standard addition method was determined calibration and empirical influence coefficients, as well as the true composition of the elements. Farther, these coefficients were used to correct the matrix effect and develop a multi-parameter optimization method. It was determined that in clay samples, consisting of Si, Al, Fe, K, Mg, Ca, Na and Ti oxi…
Wear and corrosion resistant performance of thermal-sprayed Fe-based amorphous coatings: A review
2019
Abstract Thermal sprayed Fe-based amorphous coatings exhibit excellent wear and corrosion resistance, and thus have been widely utilized for enhancing the performance of material surfaces. In this paper, important research progresses achieved in regards to deposition technologies and properties of thermal sprayed Fe-based amorphous coatings are reviewed. In particular, the dependence of wear and corrosion resistance of the coatings on processing parameters, e.g., kinetic energy, particle size, gas flow rate, and heat treatment temperature are summarized. Moreover, the utilization of reinforced phases and alloy elements for enhancing the wear and corrosion resistance of the coatings are pres…
Growth of WC–Cr–N and WC–Al–N coatings in a RF-magnetron sputtering process
2013
Tungsten carbide-based coatings have been used in a wide variety of industrial applications such as high speed cutting tools, extrusion dies, drills, aerospace industries, and more. A few reports on ternary and quaternary coatings of WC with other elements indicate good prospects for these material systems. The present study focuses on the formation of quaternary WCeCreN and WCeAleN coatings during the simultaneous reactive RF-magnetron sputtering of tungsten carbide and Al or Cr targets in an argon/nitrogen gas mixture. The resulting coatings, with thicknesses of 3.5 mme8.2 mm, were characterized by using several analytical techniques including X-ray diffraction, SEM/EDS, AFM, and X-ray ph…
Deposition of hollow sphere In2O3 coatings by liquid flame spray
2019
Hollow sphere In(OH)3 coatings were deposited by a simple liquid flame spray with hollow sphere In(OH)3 suspension, which was synthesized by improved soft template methods. The morphology of the In...