Search results for "quench"
showing 10 items of 306 documents
Strongly Red-Emissive Molecular Ruby [Cr(bpmp)2]3+ Surpasses [Ru(bpy)3]2+
2021
Gaining chemical control over the thermodynamics and kinetics of photoexcited states is paramount to an efficient and sustainable utilization of photoactive transition metal complexes in a plethora of technologies. In contrast to energies of charge transfer states described by spatially separated orbitals, the energies of spin-flip states cannot straightforwardly be predicted as Pauli repulsion and the nephelauxetic effect play key roles. Guided by multireference quantum chemical calculations, we report a novel highly luminescent spin-flip emitter with a quantum chemically predicted blue-shifted luminescence. The spin-flip emission band of the chromium complex [Cr(bpmp)2]3+ (bpmp = 2,6-bis(…
Nitrogen and sulfur co-doped carbon nanodots toward bovine hemoglobin: A fluorescence quenching mechanism investigation
2018
A deep understanding of the molecular interactions of carbon nanodots with biomacromolecules is essential for wider applications of carbon nanodots both in vitro and in vivo. Herein, nitrogen and sulfur co-doped carbon dots (N,S-CDs) with a quantum yield of 16% were synthesized by a 1-step hydrothermal method. The N,S-CDs exhibited a good dispersion, with a graphite-like structure, along with the fluorescence lifetime of approximately 7.50 ns. Findings showed that the fluorescence of the N,S-CDs was effectively quenched by bovine hemoglobin as a result of the static fluorescence quenching. The mentioned quenching mechanism was investigated by the Stern-Volmer equation, temperature-dependent…
Low temperature X-ray luminescence of KNbO3 crystals
2000
We have studied X-ray luminescence of KNbO3 single crystal. The 575 nm luminescence band has been studied in the temperature range of 15‐45 K. The quenching parameters were found to be Qa 12 3 meV and ma 4 10 11 s ˇ1 .N o luminescence has been observed under heavy ion excitation ( 86 Kr ions, 8.63 MeV/amu) even at 15 K. ” 2000 Elsevier
B parameters of the complete set of matrix elements of delta B = 2 operators from the lattice
2001
We compute on the lattice the ``bag'' parameters of the five (Delta B = 2) operators of the supersymmetric basis, by combining their values determined in full QCD and in the static limit of HQET. The extrapolation of the QCD results from the accessible heavy-light meson masses to the B-meson mass is constrained by the static result. The matching of the corresponding results in HQET and in QCD is for the first time made at NLO accuracy in the MSbar(NDR) renormalization scheme. All results are obtained in the quenched approximation.
Spectroscopic factor and proton formation probability for the d3/2 proton emitter 151Lu
2017
The quenching of the experimental spectroscopic factor for proton emission from the short-lived $d_{3/2}$ isomeric state in $^{151m}$Lu was a long-standing problem. In the present work, proton emission from this isomer has been reinvestigated in an experiment at the Accelerator Laboratory of the University of Jyv\"{a}skyl\"{a}. The proton-decay energy and half-life of this isomer were measured to be 1295(5) keV and 15.4(8) $\mu$s, respectively, in agreement with another recent study. These new experimental data can resolve the discrepancy in the spectroscopic factor calculated using the spherical WKB approximation. Using the R-matrix approach it is found that the proton formation probabilit…
Confirmation of gA quenching using the revised spectrum-shape method for the analysis of the 113Cd β-decay as measured with the COBRA demonstrator
2021
In this article we present an updated spectrum-shape analysis of the $^{113}$Cd fourfold forbidden non-unique $\beta$-decay transition in order to address the quenching of the weak axial-vector coupling $g_{\rm A}$ in low-momentum exchange nuclear processes. The experimental data were collected in a dedicated low-threshold run with the COBRA demonstrator at the LNGS and resulted in 44 individual $^{113}$Cd spectra. These data are evaluated in the context of three nuclear model frameworks based on a revised version of the spectrum-shape method and the conserved vector current hypothesis. The novel idea devised in the present work is to fit the value of the small relativistic nuclear matrix e…
Study of the recombination around the excitonic region of MBE ZnSe:Cl thin films
2008
The recombination processes around the excitonic region of undoped ZnSe and chlorine doped ZnSe thin films were studied by continuous-wave photoluminescence (cw-PL) and time-resolved photoluminescence (TRPL) spectroscopies. Samples with different chlorine concentration were obtained by varying the temperature of the Cl source. The evolution of the PL signal and its decay time were analyzed as a function of temperature. Activation energy (Ea) values associated to the quenching of the D0X and band-to-band emission were obtained from the temperature dependent cw-PL experiments. The activation energy was lower for the film with higher Cl content. The characteristic exponential decay time (TPL) …
Probing the quenching of gA by single and double beta decays
2013
Abstract Ground-state-to-ground-state two-neutrino double beta ( 2 ν β β ) decays and single beta (EC and β − ) decays are studied for the A = 100 (100Mo 100Tc 100Ru), A = 116 (116Cd 116In 116Sn) and A = 128 (128Te 128I 128Xe) nuclear systems by using the proton–neutron quasiparticle random-phase approximation exploiting realistic effective interactions in very large single-particle bases. The aim of this exercise is to see if both the single-beta and double-beta decay observables related to the ground states of the initial, intermediate and final nuclei participant in the decays can be described simultaneously by changing the value of the axial-vector coupling constant g A . In spite of th…
Macroalgal responses to ocean acidification depend on nutrient and light levels
2015
Ocean acidification may benefit algae that are able to capitalize on increased carbon availability for photosynthesis, but it is expected to have adverse effects on calcified algae through dissolution. Shifts in dominance between primary producers will have knock-on effects on marine ecosystems and will likely vary regionally, depending on factors such as irradiance (light vs. shade) and nutrient levels (oligotrophic vs. eutrophic). Thus experiments are needed to evaluate interactive effects of combined stressors in the field. In this study, we investigated the physiological responses of macroalgae near a CO2 seep in oligotrophic waters off Vulcano (Italy). The algae were incubated in situ …
Energy-Linked Reactions Catalyzed by the Purified ATPase Complex (F0F1) from Rhodospirillum rubrum Chromatophores
1980
1. The isolation of the F0F1-ATPase complex from Rhodospirillum rubrum chromatophores by the use of taurodeoxycholate is described. 2. The enzyme preparation contains about 12 polypeptides; five are subunits of the F1 moiety. 3. The ATPase activity of the purified enzyme is dependent on the addition of phospholipids. 4. Km-vales for Mg2+-ATP and Ca2+-ATP are similar to the values obtained for the membrane-bound enzyme. 5. The F0F1-ATPase complex is more than 70% inhibited by oligomycin and N,N′-dicyclohexyl-carbodiimide. 6. The F0F1-ATPase complex was integrated into liposomes. The reconstituted proteoliposomes catalyzed energy transduction as shown by ATP-dependent quenching of acridine dy…