Search results for "reduction"
showing 10 items of 2058 documents
High-density polyethylene facial implants show surface oxidation in SEM and EDX examination: a pilot study.
2009
Previous histopathological studies on explanted Medpor high-density polyethylene (HDPE) facial implants indicated signs of material destruction and claimed to observe phagocytized HDPE particles within the tissue samples beside the usual type IV reaction with severe fibrosis. We examined new and explanted Medpor material with scanning electron microscopy (SEM) and energy-dispersive X-ray analysis (EDX). The implant surface of three patient-derived specimens showed significantly higher oxygenation in EDX analysis and morphological changes in SEM compared to the new unused material directly after opening of the package and after 1 year of exposure to air. Our preliminary findings indicate a p…
Oxidation of magnesia-supported Pd-clusters leads to the ultimate limit of epitaxy with a catalytic function
2005
Oxide-supported transition-metal clusters and nanoparticles have attracted significant attention owing to their important role as components of model catalysts, sensors, solar cells and magnetic recording devices. For small clusters, functionality and structure are closely interrelated. However, knowledge of the structure of the bare cluster is insufficient as the interaction with the chemical environment might cause drastic structural changes. Here we show by ab initio simulations based on the density functional theory that the reaction with molecular oxygen transforms small, non-crystalline, magnesia-supported Pd-clusters to crystalline Pd(x)O(y) nano-oxide clusters that are in epitaxy wi…
Analysis, characterization and minimization of IPMSMs cogging torque with different rotor structures
2015
This paper presents the analysis, characterization and comparison of the cogging torque components generated by five different IPMSM rotor structures. More in detail, an IPMSM model (named IPMSM1), which is derived from a commercial geometry, is analyzed by using a Finite Element Method (FEM) approach. Then, four other IPMSM models, which are obtained by modifying the IPMSM1 rotor structure and by maintaining the same stator configuration, are proposed and analyzed. From the obtained simulation results, the cogging torque components for each structure are determined and compared. From this comparison, a significant cogging torque decrease is occurring for the modified geometries, without af…
Surface functionalization of metal-organic frameworks for improved moisture resistance
2018
Metal-organic frameworks (MOFs) are a class of porous inorganic materials with promising properties in gas storage and separation, catalysis and sensing. However, the main issue limiting their applicability is their poor stability in humid conditions. The common methods to overcome this problem involve the formation of strong metal-linker bonds by using highly charged metals, which is limited to a number of structures, the introduction of alkylic groups to the framework by post-synthetic modification (PSM) or chemical vapour deposition (CVD) to enhance overall hydrophobicity of the framework. These last two usually provoke a drastic reduction of the porosity of the material. These strategie…
Engineering of Nanofibrous Amorphous and Crystalline Solid Dispersions for Oral Drug Delivery
2018
Poor aqueous solubility (<0.1 mg/mL) affects a significant number of drugs currently on the market or under development. Several formulation strategies including salt formation, particle size reduction, and solid dispersion approaches have been employed with varied success. In this review, we focus primarily on the emerging trends in the generation of amorphous and micro/nano-crystalline solid dispersions using electrospinning to improve the dissolution rate and in turn the bioavailability of poorly water-soluble drugs. Electrospinning is a simple but versatile process that utilizes electrostatic forces to generate polymeric fibers and has been used for over 100 years to generate synthet…
Evaluation of Gallium Nitride Transistors in Electronic Power Conditioners for TWTAs
2015
The aim of this paper is to evaluate the benefits of replacing Si Mosfets transistors with enhancement mode GaN transistors in a Half-Bridge Zero Voltage and Zero Current Switching Power Switching Converter (ZVZCPS). This converter is usually used as power supply of the travelling-wave tube amplifiers (TWTAs) in aerospace applications. In this paper, firstly the converter is theoretically analyzed, obtaining its operation, losses and efficiency equations, these equations are used to obtain optimizations maps based on the main system parameters. In this way, the ideal design parameters can be visually obtained. These optimization maps are the key to quantify the potential benefits of GaN tra…
DC and 1/f noise characterization of cryogenically cooled pseudomorphic HEMT's
2002
Pseudomorphic (AlGaAs/InGaAs/GaAs) HEMT's have exhibited the best noise performance over the entire LF-to-microwave frequency range if compared to MESFET's and conventional GaAs HEMT's, due to either a reduced flicker noise, a lower G/R contribution and a smaller high-field diffusion noise. We have recently investigated the microwave (up to 18 GHz) noise properties of packaged pseudomorphic HEMT's from 290 K down to cryogenic temperature values. The current experimental work is aimed at extending such analysis to the LF noise range and at low temperatures. Cryogenic noise spectra (1 Hz to 100 KHz) and DC characteristics have therefore been recorded and the relevant observations on the devic…
Influence of FRP wrapping techniques on the compressive behavior of concrete prisms
2006
Abstract Results of an experimental investigation on the compressive behavior of concrete prisms with square cross-section, externally wrapped with carbon fiber reinforced plastic (CFRP) sheets are presented. The effects of the following parameters were analyzed: local reinforcement at the corners and continuous layers; horizontal and vertical discontinuous strips; number of continuous layers—length of specimens. An analytical model is proposed to determine the maximum bearing capacity of compressed concrete members with square cross-section and externally wrapped with FRP for the different configurations examined, and also able to consider the strength reduction with the length increase of…
A Cap-Model for Masonry-Like Material Constitutive Laws
1995
An accurate description of the constitutive behaviour of masonry-like materials is an essential target for obtaining an effective analysis-tool of masonry structures. In this paper an idealized constitutive model of such materials is proposed taking into account some peculiar features of masonry: -i) a limited strength in compression; -ii) a very limited ability to withstand tensile stresses; -iii) a softening behaviour due to a progressive reduction of the tensile strength during a monotonically increasing loading.
Experimental investigation on compressive behavior of bottle-shaped struts
2011
The goal of this investigation was the experimental verification of the dispersion of compression in bottle-shaped struts. Two typical bottle shapes were generated under load in compression concrete—both drilled and undrilled—and were reinforced concrete prismatic members with loading steel plate having a reduced area with respect to the entire cross section of the members. Axial load, and axial and lateral strains were recorded during the tests to evaluate the effects of key parameters. The comparative analysis of the experimental results showed that: 1) the presence of a hole produces a variation on the stress and strain distribution and a reduction in the load-carrying capacity; 2) the r…