Search results for "resolution."
showing 10 items of 1825 documents
Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium as Racemization Catalyst in the Dynamic Kinetic Resolution of Secondary Alcohols
2009
Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium has been prepared and its structure confirmed by X-ray analysis. This complex shows excellent catalytic activity and modest stability against air in racemization reactions of secondary alcohols. In Candida antarctica lipase B (CAL-B) catalyzed dynamic kinetic resolution (DKR) of 1-phenyl- and 1-(furan-2-yl)ethanol compounds, the new complex shows improved performance as an alcohol racemization catalyst in comparison with its well-known pentaphenylcyclopentadienyl analogue, hitherto considered as the leading catalyst candidate. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
Structure of keyhole limpet hemocyanin type 1 (KLH1) at 15 Å resolution by electron cryomicroscopy and angular reconstitution † 1 †This article is de…
1997
Abstract A three-dimensional reconstruction of keyhole limpet hemocyanin type 1 (KLH1) has been obtained using electron cryomicroscopy at liquid helium temperatures and single particle image processing. The use of a high-contrast embedding medium, 1% (w/v) glucose and 2% (w/v) ammonium molybdate (pH 7.0), enables high-resolution electron micrographs to be recorded close to focus, i.e. with excellent transfer of high-resolution information, while maintaining enough image contrast to localise the individual macromolecules in the images. When low-pass filtered to ∼45 A resolution, the new 15 A resolution reconstruction is very similar to the earlier reconstructions of gastropodan hemocyanins o…
A histological study of a femur of Plagiosuchus, a Middle Triassic temnospondyl amphibian from southern GEmany, using thin sections and micro-CT scan…
2013
AbstractThe histology of a femur of Plagiosuchus, a Middle Triassic temnospondyl amphibian, is described on the basis of two supplementary methods: classic thin sectioning and micro-CT scanning. In addition, the effectiveness of high-resolution micro-CT scanning for histological analysis is assessed. A classic, mid-shaft thin section of the femur was prepared, but prior to slicing two micro-CT scans were made. One of these has an image stack of a total of 1,024 images in the horizontal plane and a slice thickness of 87.8 μm, so that the entire bone could be captured, while the second was at mid-shaft region only, yet with a higher resolution of 28.3 μm and an image stack of 787 images in th…
Retrieving and broadcasting near-real-time biophysical parameters from MODIS and SEVIRI receiving stations at the global change unit of the Universit…
2015
We present here the automatic processing chains implemented at the Global Change Unit of the University of Valencia. These allow for a near-real-time retrieval of various biophysical parameters from both Sun-synchronous TERRA/AQUA Moderate Resolution Imaging Spectroradiometer MODIS and geostationary Meteosat Second Generation Spinning Enhanced Visible and Infrared Imager MSG SEVIRI sensors. Retrieved parameters, namely sea and land surface temperatures SST and LST, respectively, normalized difference vegetation index NDVI, and vegetation condition index VCI, are similar for both sensors, and specific approaches have been developed and implemented for near-real-time parameter retrievals: htt…
Improved superresolution in coherent optical systems.
2001
Objects that temporally vary slowly can be superresolved by the use of two synchronized moving masks such as pinholes or gratings. This approach to superresolution allows one to exceed Abbe’s limit of resolution. Moreover, under coherent illumination, superresolution requires a certain approximation based on the time averaging of intensity rather than of field distribution. When extensive digital postprocessing can be incorporated into the optical system, a detector array and some postprocessing algorithms can replace the grating that is responsible for information decoding. In this way, no approximation is needed and the synchronization that is necessary when two gratings are used is simpl…
Optimization of a Time-to-Digital Converter and a coincidence map algorithm for TOF-PET applications
2015
This contribution describes the optimization of a multichannel high resolution Time-to-Digital Converter (TDC) in a Field-Programmable Gate Array (FPGA) initially capable of obtaining time resolutions below 100ps for multiple channels. Due to its fast propagation capability it has taken advantage of the FPGA internal carry logic for accurate time measurements. Furthermore, the implementation of the TDC has been performed in different clock regions and tested with different frequencies as well, achieving improvements of up to 50% for a pair of channels. Moreover, since the TDC is potentially going to be used in a trigger system for Positron Emission Tomography (PET), the algorithm for coinci…
Integrating Social Skills in Task-Oriented 3D IVA
2005
This paper presents a set of mechanisms oriented to incorporate social information into the decision taking of task-oriented 3DIVA. The aim of this approach is to integrate collaborative skills in different character's roles (seller/buyer, worker, pedestrian, etc.) in order to enhance its behavioral animation. The collective intelligence expected in this kind of multi-character domains (e.g. storytelling, urban simulation, interactive games, etc.) requires agents able to dialogue/interact with other characters, to autonomously group/ungroup (according to their goals), or to distribute tasks and coordinate their execution for solving possible conflicts. The social model implemented follows t…
Design and development of a fNIRS system prototype based on SiPM detectors
2014
Functional Near Infrared Spectroscopy (fNIRS) uses near infrared sources and detectors to measure changes in absorption due to neurovascular dynamics in response to brain activation. The use of Silicon Photomultipliers (SiPMs) in a fNIRS system has been estimated potentially able to increase the spatial resolution. Dedicated SiPM sensors have been designed and fabricated by using an optimized process. Electrical and optical characterizations are presented. The design and implementation of a portable fNIRS embedded system, hosting up to 64 IR-LED sources and 128 SiPM sensors, has been carried out. The system has been based on a scalable architecture whose elementary leaf is a flexible board …
Superresolving optical system with time multiplexing and computer decoding
2008
Objects that have slow temporal variations may be superresolved with two moving masks such as pinhole or grating. The first mask is responsible for encoding the input image, and the second one performs the decoding operation. This approach is efficient for exceeding the resolving capability beyond Abbe’s limit of resolution. However, the proposed setup requires two physical gratings that should move in a synchronized manner. We propose what is believed to be a novel configuration in which the second grating responsible for the information decoding is replaced with a detector array and some postprocessing digital procedures. In this way the synchronization problem that exists when two gratin…
Prediction Model Selection and Spare Parts Ordering Policy for Efficient Support of Maintenance and Repair of Equipment
2010
The prediction model selection problem via variable subset selection is one of the most pervasive model selection problems in statistical applications. Often referred to as the problem of subset selection, it arises when one wants to model the relationship between a variable of interest and a subset of potential explanatory variables or predictors, but there is uncertainty about which subset to use. Several papers have dealt with various aspects of the problem but it appears that the typical regression user has not benefited appreciably. One reason for the lack of resolution of the problem is the fact that it has not been well defined. Indeed, it is apparent that there is not a single probl…