Search results for "resolution."
showing 10 items of 1825 documents
Space-Frequency Quantization for Image Compression With Directionlets
2007
The standard separable 2-D wavelet transform (WT) has recently achieved a great success in image processing because it provides a sparse representation of smooth images. However, it fails to efficiently capture 1-D discontinuities, like edges or contours. These features, being elongated and characterized by geometrical regularity along different directions, intersect and generate many large magnitude wavelet coefficients. Since contours are very important elements in the visual perception of images, to provide a good visual quality of compressed images, it is fundamental to preserve good reconstruction of these directional features. In our previous work, we proposed a construction of critic…
Sub-milliarcsecond imaging of a bright flare and ejection event in the extragalactic jet 3C 111
2020
Context. Flares in radio-loud active galactic nuclei are thought to be associated with the injection of fresh plasma into the compact jet base. Such flares are usually strongest and appear earlier at shorter radio wavelengths. Hence, very long baseline interferometry (VLBI) at millimeter(mm)-wavelengths is the best-suited technique for studying the earliest structural changes of compact jets associated with emission flares. Aims. We study the morphological changes of the parsec-scale jet in the nearby (z = 0.049) γ-ray bright radio galaxy 3C 111 following a flare that developed into a major radio outburst in 2007. Methods. We analyse three successive observations of 3C 111 at 86 GHz with th…
Acylative Dynamic Kinetic Resolution of Secondary Alcohols: Tandem Catalysis by HyperBTM and Bäckvall's Ruthenium Complex.
2021
Non-enzymatic dynamic kinetic resolution (DKR) of secondary alcohols by enantioselective acylation using an isothiourea-derived HyperBTM catalyst and racemization of slowly reacting alcohol by Backvall's ruthenium complex is reported. The DKR approach features high enantioselectivities (up to 99:1), employs easy-to-handle crystalline 4-nitrophenyl isobutyrate as the acylating reagent, and proceeds at room temperature and under an ambient atmosphere. The stereoinduction model featuring cation-π system interactions between the acylated HyperBTM catalyst and π electrons of an alcohol aryl subunit has been elaborated by DFT calculations.
Investigation of Activities for Pt-M Bimetallic Nanoparticles Catalysts on the Oxygen Reduction Reaction
2015
Bi-metallic Pt3Ni/C and Pt3Co/C electrocatalysts were successfully synthesized by a solvent free chemical vapour deposition method with a narrow particle size distribution. The results showed that the electrochemical surface area was increased by adding the additional Ni or Co to a pure Pt catalyst. Pt3Ni/C catalyst exhibited a significant enhancement of oxygen reduction reaction activity. The catalysts were characterized by EDS, XRD, HRTEM and electrochemical activity was determined using cyclic voltammetry.
Laboratory measurements and astronomical search for the HSO radical
2016
[Context] Despite the fact that many sulfur-bearing molecules, ranging from simple diatomic species up to astronomical complex molecules, have been detected in the interstellar medium, the sulfur chemistry in space is largely unknown and a depletion in the abundance of S-containing species has been observed in the cold, dense interstellar medium. The chemical form of the missing sulfur has yet to be identified.
From Single Molecules to Nanoscopically Structured Materials: Self-Assembly of Metal Chalcogenide/Metal Oxide Nanostructures Based on the Degree of P…
2011
A chemically specific and facile method for the immobilization of metal oxide nanoparticles onto the surface of IF-MoS2 nested fullerenes is reported. The modification strategy is based on the chalcophilic affinity of transition metals such as Fe2+/Fe3+, Fe3+, or Zn2+ as described by the Pearson HSAB concept. The binding capabilities of the 3d metals are dictated by their Pearson hardness. Pearson hard cations such as Fe3+ (Fe2O3) do not bind to the chalcogenide surfaces; borderline metals such as Fe2+ (Fe3O4) or Zn2+ (ZnO) bind reversibly. Pearson-soft metals like Au bind irreversibly. The immobilization of metal oxide nanoparticle colloids was monitored by transmission electron microscopy…
Ethnicity, 2016/14 : Disputes and Ethnicity
2016
"Ethnicity" – a peer-reviewed journal was established by the Institute of Philosophy and Sociology (University of Latvia). The journal publishes original works about ethnicity in different fields of knowledge – sociology, history, social linguistics, social psychology, law, political science.
Eco-friendly cavity-containing iron oxides prepared by mild routes as very efficient catalysts for the total oxidation of VOCs
2018
Iron oxides (FeOx) are non-toxic, non-expensive and environmentally friendly compounds, which makes them good candidates for many industrial applications, among them catalysis. In the present article five catalysts based on FeOx were synthesized by mild routes: hydrothermal in subcritical and supercritical conditions (Fe-HT, Few200, Few450) and solvothermal (Fe-ST1 and Fe-ST2). The catalytic activity of these catalysts was studied for the total oxidation of toluene using very demanding conditions with high space velocities and including water and CO2 in the feed. The samples were characterized by X-ray diffraction (XRD), scanning and high-resolution transmission electron microscopy (SEM and…
Intervención en Libia: La responsabilidad de proteger a debate
2011
Resumen El trabajo analiza el origen y evolución del concepto de la responsabilidad de proteger, sus antecedentes en la década de los noventa del S. XX, su formulación en el Informe sobre La responsabilidad de proteger, y su consolidación posterior con especial atención al Documento Final de la Cumbre de 2005. Se examina asimismo el modo en que se ha aplicado esta norma emergente en la Resolución 1973 del Consejo de Seguridad, de 17 de marzo de 2011, que ha autorizado el uso de la fuerza en Libia. Y se concluye que casi todas las limitaciones y objeciones que se están planteando en relación con esta intervención, probablemente son consustanciales al modo en que actualmente se ponen en prác…
Ideas, conceptos y dilemas para la implementación de una plataforma nacional de ODR en materia de consumo en Chile desde la perspectiva UE
2019
En la presente tesis hemos desarrollado una extensiva investigación monográfica en busca del concepto de ODR (online dispute resolution), el cual se encuentra en un constante desarrollo en el quehacer jurídico procesal comparado, sobre todo en materia del derecho de consumidor en el espacio de integración de la Unión Europea, con el impulso otorgado a la materia por la directiva 2011/2013 EU y el Reglamento 534/2013 EU,y la consecuente transposición de dichas normas a las tradiciones jurídicas de los Estados miembros. La búsqueda para generar un marco jurídico cada vez más proclive al consumidor dentro del mercado único europeo, ha impulsado el desarrollo de la legislación comunitaria, y la…