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Natural oxygenation of Champagne wine during ageing on lees: A metabolomics picture of hormesis

2016

International audience; The oxygenation of Champagne wine after 4 and 6 years of aging on lees in bottle was investigated by FTICR-MS and UPLC-Q-TOF-MS. Three levels of permeability were considered for the stoppers, ranging from 0.2 to 1.8 mg/L/year of oxygen transfer rate. Our results confirmed a good repeatability of ultrahigh resolution FTICR-MS, both in terms of m/z and coefficient of variation of peak intensities among biological replicates. Vintages appeared to be the most discriminated features, and metabolite annotations suggested that the oldest wines (2006) were characterized by a higher sensitivity towards oxygenation. Within each vintage, the oxygenation mechanisms appeared to b…

business.product_categoryTime FactorsChampagne wineMass-spectrometryWineNetwork01 natural sciencesLeesMass SpectrometryAnalytical ChemistryGechanisms[SDV.IDA]Life Sciences [q-bio]/Food engineeringMetabolitesChromatography High Pressure LiquidUltra-performance liquid chromatography-mass spectrometryPrincipal Component AnalysisChemistry[ SDV.IDA ] Life Sciences [q-bio]/Food engineeringDiscriminant Analysisfood and beverages04 agricultural and veterinary sciencesGeneral Medicine040401 food scienceGlutathionePhenolicsVintageEvolutionSparkling winesDirect injection Fourier transform ion cyclotron resonance mass spectrometry0404 agricultural biotechnologyMetabolomicsHormesisPhytoalexinsOxidationBottleHumansMetabolomicsLeast-Squares AnalysisWineChromatography010401 analytical chemistryHormesisReproducibility of ResultsOxygenationInterfaceSulfur-dioxide0104 chemical sciencesOxygenFood StorageAgeingbusinessFood Science
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Sport and Quality of Life

2022

Negli ultimi trent’anni lo sport ha assunto un significato molto rilevante nella vita delle persone e, seppure con notevoli differenze, sia nei paesi a sviluppo economico avanzato, sia in quelli in via di sviluppo. A livello individuale, esso ha costituito un’area di investimento identitario quando ha assunto la forma di sport spettacolo del quale fruire, alimentando la pratica del tifo e il fandom o costituendo il modello di uno stile di vita vincente; ma anche quando ha assunto la forma di pratica del tempo libero attraverso la quale tenersi in forma, facendo crescere, in questo caso, la diffusione di una cultura della salute e del benessere. Si tratta di due modalità di approcciare al co…

but also when he took the form of free time practice through which to keep fit making grow in this case the diffusion of a culture of health and well-being. These are two ways of approaching the consumption of sports by spectators and actorIn the last thirty years sport has taken on a very significant meaning in people's lives and albeit with considerable differences both in advanced economic development countries and in developing countries. On an individual level it constituted an area of identity investment when it assumed the shape of “sport spectacle” to be enjoyed fueling the practice of cheering and fandom or constituting the model of a winning lifestyleand the two ways of use can be strongly related to the perception and assessment of the quality of life. The “semantic universes” which however connote sport and “free time sports” have often appeared polarized. Commercial sport and sports professionalism are intertwined with the institutions of economics politics and culture which above all stress its “spectacularity” in order to capture first and foremost the audience. But also the sport of leisure time is intertwined with the actions of the institutions of economics politics and culture with the difference that these stress above all its “healthy value” aimed at the “healthy and rational” investment of time in an activity which improves the quality of life in the short medium and long period. This polarization between the consumption of sport entertainment - commercial sport - and the consumption of sport as a leisure activity - sport for all - has become increasingly interconnected precisely because of the increased collective identity demand via sport. In other words we have witnessed the spread of shape of sports entertainment that recall the importance of sports for psychophysical well-being for integration and social participation for the reduction of social inequalities ethnic and cultural differences and in which the importance assumed was weakened in the show from agonism from competition from the physical confrontation between two contenders or two teams. A sport in which we act with competitors as well as against competitors. And on the other hand we have gradually witnessed the spectacularization of sports in our free time to the point that the sharing of the results obtained through the declination of a competitive spirit that presents itself as directed no longer against other contenders but against its own performance limits it has become the way in which each person makes part of his or her own life spectacular the one he often considers most authentic. The aim of this work is to describe how the intertwining between the commercial/professional dimension of the sports show and the playful/recreational dimension of sports practice are fueled by a demand and an offer of social identity that characterizes these two “semantic universes”.Settore SPS/07 - Sociologia Generale
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First Measurement of the $Q^2$ Dependence of the Beam-Normal Single Spin Asymmetry for Elastic Scattering off Carbon

2018

We report on the first Q^{2}-dependent measurement of the beam-normal single spin asymmetry A_{n} in the elastic scattering of 570 MeV vertically polarized electrons off ^{12}C. We cover the Q^{2} range between 0.02 and 0.05  GeV^{2}/c^{2} and determine A_{n} at four different Q^{2} values. The experimental results are compared to a theoretical calculation that relates A_{n} to the imaginary part of the two-photon exchange amplitude. The result emphasizes that the Q^{2} behavior of A_{n} given by the ratio of the Compton to charge form factors cannot be treated independently of the target nucleus.

carbon: targetelectron: polarized beammedia_common.quotation_subjectGeneral Physics and AstronomyElectron[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex]momentum transfer dependence01 natural sciencesAsymmetryMainz Linac0103 physical sciencesgallium: arsenicpolarization: transverseelektronsko raspršenje010306 general physicsNuclear ExperimentSpin-½media_commonPhysicsElastic scatteringform factor: ratioform factor: chargeexchange: two-photon010308 nuclear & particles physicsnucleus: targetizmjena dva fotonaelectron nucleus: elastic scatteringCharge (physics)amplitude analysisNATURAL SCIENCES. Physics.PRIRODNE ZNANOSTI. Fizika.spin: asymmetry: measuredElektronsko raspršenje izmjena dva fotonaAmplitudeCover (topology)High Energy Physics::ExperimentAtomic physicsradiation: laserBeam (structure)photoelectronexperimental results
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Reliability and Validity of The Finnish Version of The Boston Carpal Tunnel Questionnaire among Surgically Treated Carpal Tunnel Syndrome Patients

2019

Background and Aims: The Boston Carpal Tunnel Questionnaire is the most commonly used outcome measure in the assessment of carpal tunnel syndrome. The purpose of this study was to translate the original Boston Carpal Tunnel Questionnaire into Finnish and validate its psychometric properties. Materials and Methods: We translated and culturally adapted the Boston Carpal Tunnel Questionnaire into Finnish. Subsequently, 193 patients completed the Finnish version of the Boston Carpal Tunnel Questionnaire, 6-Item CTS Symptoms Scale, and EuroQol 5 Dimensions 12 months after carpal tunnel release. The Boston Carpal Tunnel Questionnaire was re-administered after a 2-week interval. We calculated cons…

carpal tunnel releaseMaleBoston Carpal Tunnel QuestionnairevaliditySYMPTOMSPsychometricsRESPONSIVENESS0302 clinical medicineQuality of lifeQUALITY-OF-LIFESurveys and QuestionnairesOutcome Assessment Health CareCarpal tunnel030212 general & internal medicineFinlandReliability (statistics)Outcome measuresMiddle AgedCarpal Tunnel Syndromemedicine.anatomical_structureFUNCTIONAL STATUSFemaleFunctional statusSymptom Assessmentmusculoskeletal diseasesAdultmedicine.medical_specialtyPsychometricsHANDVALIDATION03 medical and health sciencesmedicineCarpal tunnel releaseHumansTranslationsCarpal tunnel syndromeAgedreliabilitybusiness.industryFinnishReproducibility of ResultsRecovery of Function3126 Surgery anesthesiology intensive care radiologymedicine.diseasebody regionsSEVERITYCROSS-CULTURAL ADAPTATIONPhysical therapyDISABILITIESSurgeryTRANSLATIONbusiness030217 neurology & neurosurgeryScandinavian Journal of Surgery
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Mācību priekšmeta “Sports un veselība” integrācijas iespējas citos mācību priekšmetos.

2022

Diplomdarbā “Mācību priekšmeta “Sports un veselība” integrācijas iespējas citos mācību priekšmetos” ir analizēta informācija par sporta stundas uzbūvi, starppriekšmetu saiknes raksturojumu un veidošanos, ārzemju materiāliem par veselības un fiziskās aktivitātes mācību jomu citās valstīs un mācību programmām “Sports” un “Sports un veselība” atšķirībām. Sadarbībā ar citu mācību priekšmetu skolotājiem, ir izveidoti un aprobēti dažādi mācību materiāli, kurus var lietot mācību stundās un ārpusstundu aktivitātēs, izstrādāti metodiskie ieteikumi šo mācību materiālu lietošanai. Pētījumā izstrādātie materiāli tiek aprobēti Edgara Kauliņa Lielvārdes vidusskolā dažādās klasēs gan attālinātajā mācību p…

case studyteaching materialsPedagoģijainterdisciplinary connectionsport and healthachievable results
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A homemade device for linear sucrose gradients

2008

We have developed a simple and inexpensive device to obtain linear sucrose gradients with commonly used laboratory materials--a syringe, a flask, a plastic tube, and a piece of Pongo (Play-Doh). Refractive index values measured on sucrose fractions collected using our system demonstrate both the linearity and reliability of the gradients obtained.

centrifugationChromatographySucroseBiophysicsAnalytical chemistryReproducibility of ResultsLinearityCell BiologySucrose gradientsucrose gradientBiochemistryLinear gradientchemistry.chemical_compoundchemistryCentrifugation Density GradientCosts and Cost AnalysisTube (container)LaboratoriesMolecular BiologyRefractive indexlinear gradientAnalytical Biochemistry
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Indirect analysis of urea herbicides from environmental water using solid-phase microextraction.

2000

We described here a solid-phase microextraction procedure used to extract six urea pesticides-- chlorsulfuron, fluometuron, isoproturon, linuron, metobromuron and monuron--from environmental samples. Two polydimethylsiloxanes and a polyacrylate fiber (PA) are compared. The extraction time, pH control, addition of NaCl to the water and the influence of organic matter such as humic acid on extraction efficiency were examined to achieve a sensitive method. Determination was carried out by gas chromatography with nitrogen-phosphorus detection. The proposed method requires the extraction of 2 ml of sample (pH 4, 14.3%, w/v, NaCl) for 60 min with the PA fiber. The limits of detection range from 0…

chemistry.chemical_classificationDetection limitChromatographyFluometuronHerbicidesPhenylurea CompoundsOrganic ChemistryReproducibility of ResultsGeneral MedicineSolid-phase microextractionBiochemistrySensitivity and SpecificityAnalytical Chemistrychemistry.chemical_compoundchemistryHumic acidOrganic matterSample preparationSolid phase extractionGas chromatographyWater Pollutants ChemicalJournal of chromatography. A
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Determination of Plasma Lipid Hydroperoxides by an NADPH/NADP + Coupled Enzyme Reaction System. Evaluation of a Method

1998

Summary: Several techniques based on different principles have been proposed to measure lipid hydroperoxides. Enzymatic methods are sensitive and can be quite specific but they are subject to interference by inhibitors and not all are stoichiometric. The present work proposes some modifications of the Heath & Tappel (Anal Biochem 1976; 7:184—91) enzymatic method of determination of lipid hydroperoxides in order to standardize and automate it and to meet the analytical criteria required for a biological assay. The proposed new protocol and the automated assay give acceptable within-run and between-run precisions, with coefficients of variation of 3.34% and 5.80%, respectively, at the usual p…

chemistry.chemical_classificationGlutathione PeroxidaseLipid PeroxidesChromatographyChemistryBiochemistry (medical)Clinical BiochemistryReproducibility of ResultsSystem evaluationGeneral MedicineBiological fluidAutomationKineticsGlutathione ReductaseInvestigation methodsEnzymeBiochemistrySpectrophotometryNadph nadpPlasma lipidsHumansQuantitative analysis (chemistry)NADPcclm
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Determination of major carotenoids in vegetables by capillary electrochromatography.

2006

A simple and rapid method for the isocratic separation and determination of carotenoids (carotenes and xanthophylls) in vegetables by CEC is described. The capillary column (100 microm ID, 25 cm effective length) was packed with 3 microm Hypersil ODS particles. The optimized mobile phase contained 60% ACN, 35% THF and 5% of a 5 mM Tris aqueous buffer of pH 8. beta-Carotene, lycopene and lutein were separated with efficiencies of 66 000-128 000 plates/m within a short time (less than 12 min for the last peak eluted, 13/13'-cis-beta-carotene). An excellent resolution of the three carotenoids, as well as partial resolution of their geometrical isomers, was achieved. Application to the determin…

chemistry.chemical_classificationLuteinCapillary electrochromatographyChromatographyResolution (mass spectrometry)Molecular StructureElutionReproducibility of ResultsFiltration and SeparationStereoisomerismCarotenoidsLycopeneAnalytical Chemistrychemistry.chemical_compoundElectrochromatographychemistryXanthophyllVegetablesCarotenoidChromatography Micellar Electrokinetic CapillaryJournal of separation science
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Effect of traditional, microwave and industrial cooking on inositol phosphate content in beans, chickpeas and lentils

2003

An high-performance liquid chromatography method for determining inositol phosphate fractions was adapted to legumes. The validity of the method was assessed by estimating the following analytical parameters: linearity (linear response between 125 and 5000 microg inositol hexaphosphate (IP(6))/ml); instrumental precision and method precision (relative standard deviation, %) were 1.9% (IP(6)) for instrumental, and 2.5% (IP(6)) and 8.2% (IP(5)) for method precision. An accuracy was estimated by percentage recovery (72 +/- 3%). The application of this method to raw, conventional, microwave-cooked and ready-to-eat beans, chickpeas and lentils gave IP(6) contents ranging from 0.63 g/100 g dry ma…

chemistry.chemical_classificationPhytic AcidFood HandlingInositol PhosphatesRelative standard deviationReproducibility of ResultsFabaceaeCicerBioavailabilityInositol pentaphosphatechemistryBotanyLens PlantDry matterInositol hexaphosphateFood scienceMicrowavesInositol phosphateChromatography High Pressure LiquidLegumeFood ScienceInternational Journal of Food Sciences and Nutrition
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